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Si-C attachment points during sol-gel synthesis of organosilicas from 2,8 bis-silylated Troeger s base as building block precursor

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Si-C attachment points during sol-gel synthesis of organosilicas from 2,8 bis-silylated Troeger s base as building block precursor

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Poli, E.; Merino Marcos, E.; Díaz Morales, UM.; Brunel, D.; Corma Canós, A. (2011). Si-C attachment points during sol-gel synthesis of organosilicas from 2,8 bis-silylated Troeger s base as building block precursor. Journal of Materials Chemistry. 21(24):8524-8527. doi:10.1039/c1jm10426h

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Título: Si-C attachment points during sol-gel synthesis of organosilicas from 2,8 bis-silylated Troeger s base as building block precursor
Autor:
Entidad UPV: Universitat Politècnica de València. Departamento de Química - Departament de Química
Fecha difusión:
Resumen:
The porous organosilica framework containing Troger's base (TB) prepared by mild sol-gel synthesis from 2,8-bis-silylated TB precursor contains a mixture of two point attached TB and one point attached TB units, resulting ...[+]
Palabras clave: PERIODIC MESOPOROUS ORGANOSILICAS , HYBRID MATERIALS , NUCLEOPHILIC DISPLACEMENT , MECHANISTIC IMPLICATIONS , CATALYTIC-ACTIVITY , SELF-ORGANIZATION , ORGANIC GROUPS , CHANNEL WALLS , SILICA-GEL , CRYSTAL
Derechos de uso: Reserva de todos los derechos
Fuente:
Journal of Materials Chemistry. (issn: 0959-9428 )
DOI: 10.1039/c1jm10426h
Editorial:
Royal Society of Chemistry
Versión del editor: http://dx.doi.org/10.1039/c1jm10426h
Agradecimientos:
We are thankful for financial support by Consolider-Ingenio 2010 (MULTICAT project). E.M. thanks Ministerio de Ciencia y Innovacion by the support through Juan de la Cierva contract. The authors are indebted to Dr Alejandro ...[+]
Tipo: Artículo

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