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Passivation of a CoCrMo PVD Alloy with Biomedical Composition under Simulated Physiological Conditions Studied by EQCM and XPS

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Passivation of a CoCrMo PVD Alloy with Biomedical Composition under Simulated Physiological Conditions Studied by EQCM and XPS

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dc.contributor.author Valero Vidal, Carlos es_ES
dc.contributor.author Igual Muñoz, Anna Neus es_ES
dc.contributor.author Olsson, C.O.A. es_ES
dc.contributor.author Mischler, Stefano es_ES
dc.date.accessioned 2013-09-11T07:25:23Z
dc.date.available 2013-09-11T07:25:23Z
dc.date.issued 2012
dc.identifier.issn 0013-4651
dc.identifier.uri http://hdl.handle.net/10251/31971
dc.description.abstract Kinetics of passive film growth on a CoCrMo biomedical alloy have been studied using the Electrochemical Quartz Crystal Microbalance technique (EQCM) in phosphate buffer solution at room temperature and 37◦C. CoCrMo layers were deposited on the quartz crystals by physical vapor deposition (PVD) reaching a dense and compact deposition film with fine-grain structure. EQCM measurements were performed under potentiodynamic and potentiostatic conditions (at applied passive and transpassive potentials). Furthermore, ex-situ X-ray Photoelectron Spectroscopy (XPS) analysis of the each tested sample was performed at the end of the electrochemical test. The use ofEQCMallows distinguishing between electrochemical oxidation, passive and transpassive dissolution and passive film growth. In the passive domain the passive film thickness stabilizes within 200 to 400 s after an initial fast growth. The increase in current at the onset of the transpassive domain does not affect the passive dissolution rate. Only at higher potential dissolution rate increases due to the dissolution of Cr(VI), Co(III) and Mo(VI) species. The observed constant mass loss rate at transpassive potentials indicates that the passive film at these potentials is cracked or porous. Increasing temperature accelerates themass loss through the oxide/electrolyte interface enhancing the passive and transpassive dissolution and increasing the thickness of the oxide film es_ES
dc.description.sponsorship We wish to express our gratitude to the Spanish Government, "Ministerio de Educacion" for the economic support and the post-graduate grant (Ref.AP2007-01243) and "Ministerio de Ciencia e Innovacion" for the financial support (Ref.MAT2011-22481), the assistance of N. Xanthopoulos with the XPS measurements and P. Mettraux with the PVD deposits and assistance with the scanning electron micrographs. en_EN
dc.language Inglés es_ES
dc.publisher Electrochemical Society es_ES
dc.relation.ispartof Journal of The Electrochemical Society es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Electrochemical quartz crystal microbalance es_ES
dc.subject CoCrMo biomedical alloys es_ES
dc.subject proteins es_ES
dc.subject adsorption es_ES
dc.subject passivation es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Passivation of a CoCrMo PVD Alloy with Biomedical Composition under Simulated Physiological Conditions Studied by EQCM and XPS es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1149/2.090205jes
dc.relation.projectID info:eu-repo/grantAgreement/MEC//AP2007-01243/ES/AP2007-01243/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2011-22481/ES/ESTUDIO DE PROPIEDADES FISICO-QUIMICAS DE INTERFASE BIOMATERIAL/SUERO FISIOLOGICO PARA DETERMINAR MECANISMOS DE DEGRADACION TRIBO-ELECTROQUIMICOS DE ALEACIONES BIOMEDICAS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Valero Vidal, C.; Igual Muñoz, AN.; Olsson, C.; Mischler, S. (2012). Passivation of a CoCrMo PVD Alloy with Biomedical Composition under Simulated Physiological Conditions Studied by EQCM and XPS. Journal of The Electrochemical Society. 159(5):233-243. https://doi.org/10.1149/2.090205jes es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1149/2.090205jes es_ES
dc.description.upvformatpinicio 233 es_ES
dc.description.upvformatpfin 243 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 159 es_ES
dc.description.issue 5 es_ES
dc.relation.senia 235348
dc.contributor.funder Ministerio de Educación y Ciencia es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
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