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Enhanced photochemical [6pi] electrocyclization within the lipophilic protein binding site

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Enhanced photochemical [6pi] electrocyclization within the lipophilic protein binding site

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Marín Melchor, M.; Lhiaubet, VL.; Miranda Alonso, MÁ. (2012). Enhanced photochemical [6pi] electrocyclization within the lipophilic protein binding site. Organic letters. 14(7):1788-1791. https://doi.org/10.1021/ol3003805

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/33011

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Title: Enhanced photochemical [6pi] electrocyclization within the lipophilic protein binding site
Author: Marín Melchor, Mireia Lhiaubet, Virginie Lyria Miranda Alonso, Miguel Ángel
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
Photocyclization of N-methyldiphenylamine to N-methylcarbazole is achieved within the microenvironment provided by site I of serum albumins. Quantum yield determinations, combined with transient absorption spectroscopic ...[+]
Subjects: Human-serum-albumin , N methyldiphenylamine , Drug , Photoconversion , State , Stereodifferentiation , Photocyclization , Methylcarbazole , Diphenylamines , Switches
Copyrigths: Cerrado
Source:
Organic letters. (issn: 1523-7060 )
DOI: 10.1021/ol3003805
Publisher:
American Chemical Society
Publisher version: http://pubs.acs.org/doi/pdf/10.1021/ol3003805
Project ID:
info:eu-repo/grantAgreement/MICINN//CTQ2009-13699/ES/CTQ2009-13699/
info:eu-repo/grantAgreement/GVA//PROMETEO08%2F2008%2F090/ES/Especies fotoactivas como sondas para proteínas/
info:eu-repo/grantAgreement/MEC//RYC-2007-00476/ES/RYC-2007-00476/
Thanks:
This work was funded by the Spanish Government (Project CTQ2009-13699, Ramon y Cajal contract RyC-2007-00476 to V.L.-V. and JAE-predoc contract to M.M.) and the Generalitat Valenciana (Prometeo/2008/090).
Type: Artículo

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