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Oxetane ring enlargement through nucleophilic trapping of radical cations by acetonitrile

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Oxetane ring enlargement through nucleophilic trapping of radical cations by acetonitrile

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dc.contributor.author Pérez Ruiz, Raul es_ES
dc.contributor.author Sáez Cases, José Antonio es_ES
dc.contributor.author Domingo, Luis R. es_ES
dc.contributor.author Jiménez Molero, María Consuelo es_ES
dc.contributor.author Miranda Alonso, Miguel Ángel
dc.date.accessioned 2013-10-22T15:53:14Z
dc.date.issued 2012
dc.identifier.issn 1523-7060
dc.identifier.uri http://hdl.handle.net/10251/33013
dc.description.abstract Oxidative electron transfer cycloreversion of trans,trans-2-cyclopropyl-4-methyl-3-phenyloxetane, using triphenylthiapyrylium perchlorate as a photosensitizer, leads to distonic 1,4-radical cations; subsequent cleavage gives rise to fragmentation products (pathway a), whereas nucleophilic trapping by acetonitrile affords a ring expanded oxazine (pathway b). es_ES
dc.description.sponsorship Financial support by the MICINN (Grants CTQ-2010-14882, CTQ-2009-13699 and JCI-2010-06204), from CSIC (JAEDOC 101-2011) and from Generalitat Valenciana (Grant No.GV/2012/041-20120205) is gratefully acknowledged. en_EN
dc.format.extent 4 es_ES
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof Organic letters es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Oxetane ring enlargement through nucleophilic trapping of radical cations by acetonitrile es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1021/ol302717s
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//JCI-2010-06204/ES/JCI-2010-06204/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2010-14882/ES/DIADAS FOTOACTIVAS COMO SONDAS PARA LA GENERACION DE ESPECIES TRANSITORIAS EN SISTEMAS MICROHETEROGENEOS DE TIPO BIOMIMETICO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CSIC//JAEDOC 101-2011/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2009-13699/ES/MECANISMOS FOTOQUIMICOS DEL DAÑO AL ADN Y SU REPARACION. FOTOSENSIBILIZACION FRENTE A FOTOPROTECCION/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//GV%2F2012%2F041/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Pérez Ruiz, R.; Sáez Cases, JA.; Domingo, LR.; Jiménez Molero, MC.; Miranda Alonso, MÁ. (2012). Oxetane ring enlargement through nucleophilic trapping of radical cations by acetonitrile. Organic letters. 14(22):5700-5703. https://doi.org/10.1021/ol302717s es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://pubs.acs.org/doi/pdf/10.1021/ol302717s es_ES
dc.description.upvformatpinicio 5700 es_ES
dc.description.upvformatpfin 5703 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 14 es_ES
dc.description.issue 22 es_ES
dc.relation.senia 237614
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Consejo Superior de Investigaciones Científicas es_ES


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