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Bypassing the energy barrier of homolytic photodehalogenation in chloroaromatics through self-quenching

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Bypassing the energy barrier of homolytic photodehalogenation in chloroaromatics through self-quenching

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Limones Herrero, D.; Pérez Ruiz, R.; Jiménez Molero, MC.; Miranda Alonso, MÁ. (2013). Bypassing the energy barrier of homolytic photodehalogenation in chloroaromatics through self-quenching. Organic Letters. 15(6):1314-1317. https://doi.org/10.1021/ol400251s

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/33146

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Title: Bypassing the energy barrier of homolytic photodehalogenation in chloroaromatics through self-quenching
Author: Limones Herrero, Daniel Pérez Ruiz, Raul Jiménez Molero, María Consuelo Miranda Alonso, Miguel Ángel
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
Reductive photodehalogenation of chloroaromatics is assumed to proceed from the triplet excited state, although its energy is often insufficient to promote a clean homolytic C¿Cl cleavage. A clear-cut experimental proof ...[+]
Subjects: Carprofen dyads , Photodehalogenation
Copyrigths: Cerrado
Source:
Organic Letters. (issn: 1523-7060 ) (eissn: 1523-7052 )
DOI: 10.1021/ol400251s
Publisher:
American Chemical Society
Publisher version: http://pubs.acs.org/doi/pdf/10.1021/ol400251s
Project ID:
info:eu-repo/grantAgreement/MICINN//CTQ2010-14882/ES/DIADAS FOTOACTIVAS COMO SONDAS PARA LA GENERACION DE ESPECIES TRANSITORIAS EN SISTEMAS MICROHETEROGENEOS DE TIPO BIOMIMETICO/ /
info:eu-repo/grantAgreement/GVA//GV%2F2012%2F041/
info:eu-repo/grantAgreement/GVA//PROMETEO08%2F2008%2F090/ES/Especies fotoactivas como sondas para proteínas/
info:eu-repo/grantAgreement/MICINN//BES-2011-043706/ES/BES-2011-043706/
info:eu-repo/grantAgreement/MICINN//JCI-2010-06204/ES/JCI-2010-06204/
Thanks:
Financial support from the Spanish Government (CTQ2010-14882, BES-2011-043706, JCI-2010-06204) and from the Generalitat Valenciana (Prometeo 2008/090 and GV/2012/041) is gratefully acknowledged.
Type: Artículo

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