Gotor Candel, RJ.; Costero Nieto, AM.; Gil Grau, S.; Parra Alvarez, M.; Martínez Mañez, R.; Sancenón Galarza, F. (2011). A Molecular Probe for the Highly Selective Chromogenic Detection of DFP, a Mimic of Sarin and Soman Nerve Agents. Chemistry - A European Journal. 17:11994-11997. doi:10.1002/chem.201102241
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/33411
Title:
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A Molecular Probe for the Highly Selective Chromogenic Detection of DFP, a Mimic of Sarin and Soman Nerve Agents
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Author:
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Gotor Candel, Raul Jesús
Costero Nieto, Ana María
Gil Grau, Salvador
Parra Álvarez, Margarita
Martínez Mañez, Ramón
Sancenón Galarza, Félix
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UPV Unit:
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Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic
Universitat Politècnica de València. Departamento de Química - Departament de Química
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Issued date:
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Abstract:
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Lethal-weapon visualization: A novel triarylmethanol derivative, which is able to colorimetrically distinguish diisopropylfluorophosphate (DFP; a mimic of Sarin and Soman) from other nerve-agent simulants, is reported (see ...[+]
Lethal-weapon visualization: A novel triarylmethanol derivative, which is able to colorimetrically distinguish diisopropylfluorophosphate (DFP; a mimic of Sarin and Soman) from other nerve-agent simulants, is reported (see picture). This probe was designed to contain two reactive sites: an OH group that provides a suitable reactive group for nerve agents and a tert-butyldimethylsilylether moiety that is able to react with fluoride, which is a specific byproduct of the phosphorylation of OH by DFP.
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Subjects:
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Chemosensors
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Chromogenic detection
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DFP recognition
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Nerve-agent simulants
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Organophosphonates
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Copyrigths:
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Cerrado |
Source:
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Chemistry - A European Journal. (issn:
0947-6539
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DOI:
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10.1002/chem.201102241
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Publisher:
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Wiley-VCH Verlag
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Publisher version:
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http://dx.doi.org/10.1002/chem.201102241
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Project ID:
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Spanish Government [MAT2009-14564-C04]
Regional Valencian Government (Generalitat Valencia) [PROMETEO/2009/016, ACOMP07/080]
Generalitat Valenciana
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Thanks:
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We thank the Spanish Government (project MAT2009-14564-C04) and the Regional Valencian Government (Generalitat Valencia; project PROMETEO/2009/016 and ACOMP07/080) for support. S.R. is grateful to the Generalitat Valenciana ...[+]
We thank the Spanish Government (project MAT2009-14564-C04) and the Regional Valencian Government (Generalitat Valencia; project PROMETEO/2009/016 and ACOMP07/080) for support. S.R. is grateful to the Generalitat Valenciana for the fellowship awarded. SCSIE (Universidad de Valencia) is gratefully acknowledged for all the equipment employed.
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Type:
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Artículo
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