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dc.contributor.author | Moliner Marin, Manuel | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.date.accessioned | 2013-11-11T13:20:37Z | |
dc.date.issued | 2012-10-30 | |
dc.identifier.issn | 0897-4756 | |
dc.identifier.uri | http://hdl.handle.net/10251/33424 | |
dc.description.abstract | Titanosilicate forms of expanded MWW-related material are synthesized starting from a pure silica precursor, ITQ-1. This procedure improves the current synthetic route of the expanded titanosilicate MWW material (Ti-YNU-1), which requires the use of a borosilicate MWW as precursor and, consequently, several postsynthetic acid treatments for removing boron atoms from the framework. The expanded Ti-MWW-related materials presented here show better activity than regular Ti-MWW in the selective epoxidation reaction of cyclohexene using H2O2 as oxidant. | es_ES |
dc.description.sponsorship | Financial support by the Spanish MINECO (MAT2012-37160, and Consolider Ingenio 2010-Multicat), Generalitat Valenciana by the PROMETEO program, and UPV through PAID-06-11 (no. 1952) is acknowledged. M.M. also acknowledges "Subprograma Ramon y Cajal" for the contract RYC-2011-08972. | en_EN |
dc.format.extent | 5 | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | Chemistry of Materials | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Titanosilicate | es_ES |
dc.subject | MWW | es_ES |
dc.subject | Zeolite | es_ES |
dc.subject | Olefin epoxidation | es_ES |
dc.subject | Green chemistry | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Synthesis of expanded titanosilicate MWW-related materials from a pure silica precursor | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1021/cm302509m | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MAT2012-37160/ES/SINTESIS DE NUEVOS MATERIALES MICROPOROSOS BASADOS EN EL USO DE ?ESPONJAS DE PROTONES? COMO AGENTES DIRECTORES DE ESTRUCTURA (ADES)/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/UPV//PAID-06-11-1952/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//RYC-2011-08972/ES/RYC-2011-08972/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Moliner Marin, M.; Corma Canós, A. (2012). Synthesis of expanded titanosilicate MWW-related materials from a pure silica precursor. Chemistry of Materials. 24(22):4371-4375. https://doi.org/10.1021/cm302509m | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://pubs.acs.org/doi/abs/10.1021/cm302509m | es_ES |
dc.description.upvformatpinicio | 4371 | es_ES |
dc.description.upvformatpfin | 4375 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 24 | es_ES |
dc.description.issue | 22 | es_ES |
dc.relation.senia | 237734 | |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |
dc.contributor.funder | Universitat Politècnica de València | es_ES |
dc.contributor.funder | Generalitat Valenciana | es_ES |