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Cationic Gold Catalyzes Omega-Bromination of Terminal Alkynes and Subsequent Hydroaddition Reactions

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Cationic Gold Catalyzes Omega-Bromination of Terminal Alkynes and Subsequent Hydroaddition Reactions

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Leyva Perez, A.; Rubio Marqués, P.; Al-Dejab, SS.; Al-Resayes, SI.; Corma Canós, A. (2011). Cationic Gold Catalyzes Omega-Bromination of Terminal Alkynes and Subsequent Hydroaddition Reactions. ACS Catalysis. 1(6):601-606. doi:10.1021/cs200168p

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/33517

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Title: Cationic Gold Catalyzes Omega-Bromination of Terminal Alkynes and Subsequent Hydroaddition Reactions
Author:
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] Orthogonal sigma,pi-bisfunctionalization of terminal alkynes can be achieved with a cationic gold complex in catalytic amounts. First, the terminal C-H bond is transformed to the corresponding bromoalkyne which is ...[+]
Subjects: Gold catalysis , Aurophilic interactions , Terminal alkynes , ¿,¿-bisfunctionalization , Bromoalkynes
Copyrigths: Cerrado
Source:
ACS Catalysis. (issn: 2155-5435 )
DOI: 10.1021/cs200168p
Publisher:
American Chemical Society
Publisher version: http://dx.doi.org/10.1021/cs200168p
Thanks:
A.L.-P. thanks CSIC for a contract under JAE-doctors program. P.R-M. thanks UPV and ITQ for the concession of a FPI predoctoral fellowship.
Type: Artículo

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