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Orthogonal C N Plus C C Tandem Reaction of Iodoanilines Leading to Styrylguanidines Catalyzed by Supported Palladium Nanoparticles

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Orthogonal C N Plus C C Tandem Reaction of Iodoanilines Leading to Styrylguanidines Catalyzed by Supported Palladium Nanoparticles

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dc.contributor.author Grirrane, Abdessamad es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author Álvarez, Eleuterio es_ES
dc.date.accessioned 2013-11-15T09:07:26Z
dc.date.issued 2012-11-19
dc.identifier.issn 0947-6539
dc.identifier.uri http://hdl.handle.net/10251/33619
dc.description.abstract Two birds, one nanoparticle: A highly efficient and selective tandem reaction comprising C[BOND]N and C[BOND]C cross-coupling of iodoanilines to form styrylguanidines by using a recyclable, heterogeneous, supported palladium nanoparticle catalyst is reported (see scheme). A mechanistic proposal based on coordination of palladium nanoparticles to the basic N atoms of aniline and guanidine is supported by isolation of palladium complexes with aniline or guanidine. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Science and Innovation (Consolider MULTICAT and CTQ 2012-32315) is gratefully acknowledged. The Generalidad Valenciana is also thanked for partial financial support (Prometeo Grant). en_EN
dc.format.extent 5 es_ES
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Domino reactions es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Nanoparticles es_ES
dc.subject Palladium es_ES
dc.subject Coordination chemistry es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Orthogonal C N Plus C C Tandem Reaction of Iodoanilines Leading to Styrylguanidines Catalyzed by Supported Palladium Nanoparticles es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/chem.201202823
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Grirrane, A.; García Gómez, H.; Corma Canós, A.; Álvarez, E. (2012). Orthogonal C N Plus C C Tandem Reaction of Iodoanilines Leading to Styrylguanidines Catalyzed by Supported Palladium Nanoparticles. Chemistry - A European Journal. 18:14934-14938. https://doi.org/10.1002/chem.201202823 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/chem.201202823 es_ES
dc.description.upvformatpinicio 14934 es_ES
dc.description.upvformatpfin 14938 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 18 es_ES
dc.relation.senia 229659
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.contributor.funder Generalitat Valenciana
dc.contributor.funder Ministerio de Economía y Competitividad es_ES


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