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Development of a Flow Injection Manifold for Napropamide Determination by Photo-Induced Chemiluminescence

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Development of a Flow Injection Manifold for Napropamide Determination by Photo-Induced Chemiluminescence

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dc.contributor.author Catalá Icardo, Mónica es_ES
dc.contributor.author López Paz, José Luis es_ES
dc.contributor.author Asensio Martín, Víctor es_ES
dc.date.accessioned 2013-11-19T11:46:20Z
dc.date.issued 2012
dc.identifier.issn 0003-2719
dc.identifier.uri http://hdl.handle.net/10251/33730
dc.description.abstract A new, rapid, and simple method is proposed for the determination of the pesticide napropamide by photo-induced chemiluminescence detection coupled with a flow injection analysis (FIA) system. The emission was obtained by oxidation with periodate in basic medium, of the photoproducts generated on-line by UV irradiation (254 nm) of napropamide in acidic SDS (sodium dodecyl sulfate) medium. The flow method, in combination with the solid phase extraction (SPE) performed off-line with C-18 cartridges, allowed the determination of this pesticide over the 0.8-14.0 mu g L-1 range, with a limit of detection of 0.3 mu g L-1. The relative standard deviation (n = 9) at 2.5 mu g L-1 level was 4.3% for the combined FIA-SPE system. After testing the influence of several potential interfering compounds, including ions and other pesticides, the method was successfully applied to the determination of napropamide in spiked water samples with recoveries between 96-103%. es_ES
dc.description.sponsorship This work was supported by the Ministry of Education and Science of Spain (Project CTM2006-11991) and FEDER funds. en_EN
dc.language Inglés es_ES
dc.publisher Taylor & Francis Group es_ES
dc.relation Ministry of Education and Science of Spain CTM2006-11991 es_ES
dc.relation FEDER es_ES
dc.relation.ispartof Analytical Letters es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Chemiliminescence es_ES
dc.subject Flow injection: Napropamide es_ES
dc.subject Pesticides es_ES
dc.subject Photoreaction es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Development of a Flow Injection Manifold for Napropamide Determination by Photo-Induced Chemiluminescence es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1080/00032719.2012.655679
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Investigación para la Gestión Integral de Zonas Costeras - Institut d'Investigació per a la Gestió Integral de Zones Costaneres es_ES
dc.description.bibliographicCitation Catalá Icardo, M.; López Paz, JL.; Asensio Martín, V. (2012). Development of a Flow Injection Manifold for Napropamide Determination by Photo-Induced Chemiluminescence. Analytical Letters. 45:872-882. doi:10.1080/00032719.2012.655679 es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://www.tandfonline.com/doi/pdf/10.1080/00032719.2012.655679 es_ES
dc.description.upvformatpinicio 872 es_ES
dc.description.upvformatpfin 882 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 45 es_ES
dc.relation.senia 246303


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