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dc.contributor.author | Dhakshinamoorthy, Amarajothi![]() |
es_ES |
dc.contributor.author | Alvaro Rodríguez, Maria Mercedes![]() |
es_ES |
dc.contributor.author | García Gómez, Hermenegildo![]() |
es_ES |
dc.date.accessioned | 2013-11-19T12:23:05Z | |
dc.date.issued | 2011-04-14 | |
dc.identifier.issn | 0947-6539 | |
dc.identifier.uri | http://hdl.handle.net/10251/33736 | |
dc.description.abstract | [EN] Aerobic oxidation of cyclooctane to its corresponding ol/one mixture at atmospheric pressure and in the liquid phase is efficiently promoted by an Fe(BTC) (BTC=1,3,5-benzenetricarboxylate) metal-organic framework, incorporating N-hydroxyphthalimide and in several cases reaches a selectivity over 90% at 28% conversion. This catalytic system is further extended to other hydrocarbons, such as ethylbenzene and 1,2,3,4-tetrahydronaphthalene (tetralin), with high selectivity (>85%). This high selectivity in the product distribution arises from a radical reaction mechanism that occurs inside a hydrophobic cavity that preferentially adsorbs hydrocarbons over their corresponding alcohols. The system can be reused although there is a gradual decrease in turnover frequency, caused by minor changes in the crystal structure due to the formation of iron oxide nanoparticles. Given the sustainable nature of the oxidant and the mild conditions used, this discovery could serve to develop a new catalyst generation for the oxyfunctionalisation of hydrocarbon feedstocks with the real possibility of finding industrial application. | es_ES |
dc.description.sponsorship | Financial support from the Spanish DGI (CTQ2009-11587, CTQ2007-67805 and Consolider MULTICAT) is gratefully acknowledged. Partial funding from the European Community's Seventh Framework Programme ([FP7/2007-2013] under grant agreement number 228862) is also gratefully acknowledged. Alejandro Vidal is thanked for recording the ESR spectra. | en_EN |
dc.format.extent | 7 | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | Wiley-VCH Verlag | es_ES |
dc.relation.ispartof | Chemistry - A European Journal | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Alkanes | es_ES |
dc.subject | Aerobic oxidation | es_ES |
dc.subject | Green chemistry | es_ES |
dc.subject | Metal-organic frameworks | es_ES |
dc.subject | Organocatalysis | es_ES |
dc.subject | Oxidation | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Atmospheric-pressure, liquid-phase, selective aerobic oxidation of alkanes catalysed by metal-organic frameworks | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1002/chem.201002664 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CTQ2009-11587/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/228862/EU/MOFs as Catalysts and Adsorbents: Discovery and Engineering of Materials for Industrial Applications/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/MEC//CTQ2007-67805/ES/APLICACION DE NUEVOS DERIVADOS DEL PPV ENCAPSULADOS EN MATRICES DE SILICE EN LA PREPARACION DE TRANSISTORES DE CAMPO ELECTRICO Y RECTIFICADORES A ESCALA MICROMETRICA/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Dhakshinamoorthy, A.; Alvaro Rodríguez, MM.; García Gómez, H. (2011). Atmospheric-pressure, liquid-phase, selective aerobic oxidation of alkanes catalysed by metal-organic frameworks. Chemistry - A European Journal. 17(22):6256-6262. https://doi.org/10.1002/chem.201002664 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://onlinelibrary.wiley.com/doi/10.1002/chem.201002664/pdf | es_ES |
dc.description.upvformatpinicio | 6256 | es_ES |
dc.description.upvformatpfin | 6262 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 17 | es_ES |
dc.description.issue | 22 | es_ES |
dc.relation.senia | 215905 | |
dc.identifier.pmid | 21495095 | |
dc.contributor.funder | European Commission | |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |
dc.contributor.funder | Ministerio de Educación y Ciencia | es_ES |