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Unprecedented multi-stable spin crossover molecular material with two thermal memory channels

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Unprecedented multi-stable spin crossover molecular material with two thermal memory channels

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Seredyuk, M.; Muñoz Roca, MDC.; Castro, M.; Romero-Morcillo, T.; Gaspar, AB.; Real, JA. (2013). Unprecedented multi-stable spin crossover molecular material with two thermal memory channels. Chemistry - A European Journal. 19(21):6591-6596. https://doi.org/10.1002/chem.201300394

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Title: Unprecedented multi-stable spin crossover molecular material with two thermal memory channels
Author: Seredyuk, Maksym Muñoz Roca, María del Carmen Castro, Miguel Romero-Morcillo, Tania Gaspar, Ana B. Real, José Antonio
UPV Unit: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Issued date:
Abstract:
Two in one: A new iron(II) complex with short alkyl substituents exhibits an unprecedented bimodal behavior governed by the coexistence of three phases: two structurally different low-spin phases and one high-spin phase. ...[+]
Subjects: Intermolecular interactions , Iron , LIESST effect , Molecular materials , Phase transitions
Copyrigths: Cerrado
Source:
Chemistry - A European Journal. (issn: 0947-6539 )
DOI: 10.1002/chem.201300394
Publisher:
Wiley-VCH Verlag
Publisher version: http://onlinelibrary.wiley.com/doi/10.1002/chem.201300394/pdf
Project ID:
info:eu-repo/grantAgreement/MEC//MAT2007-61621/ES/MATERIALES MULTIFUNCIONALES MAGNETICOS: MATERIALES MOLECULARES Y NUEVAS APLICACIONES DE COMPUESTOS MAGNETICOS./ /
...[+]
info:eu-repo/grantAgreement/MEC//MAT2007-61621/ES/MATERIALES MULTIFUNCIONALES MAGNETICOS: MATERIALES MOLECULARES Y NUEVAS APLICACIONES DE COMPUESTOS MAGNETICOS./ /
info:eu-repo/grantAgreement/GVA//ACOMP%2F2012%2F233/
info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F049/
info:eu-repo/grantAgreement/EC/FP7/253254/EU/Tailoring crossover properties by electric field in nano-structural and liquid crystalline molecular based magnetic materials/ELECTROSCO/
info:eu-repo/grantAgreement/MICINN//MAT2011-24284/ES/ENSAMBLAJES MOLECULARES Y EXTENDIDOS DE COMPLEJOS MAGNETICOS PARA FOTO-CONMUTACION, PUERTAS LOGICAS CUANTICAS Y ORGANIZACION DE NANO-IMANES EN SUPERFICIES/
info:eu-repo/grantAgreement/MICINN//CTQ2010-18414/ES/MATERIALES MULTIPROPIEDAD BASADOS EN EL FENOMENO "SPIN CROSSOVER": MEMORIAS Y SENSORES MOLECULARES/
info:eu-repo/grantAgreement/MEC//CSD2007-00010/ES/NANOCIENCIA MOLECULAR/ /
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Thanks:
This work was supported by the Spanish Ministerio de Ciencia e Innovacion (MICINN) (presently Ministerio de Economia y Competitividad (MINECO)) and FEDER funds (CTQ2010-18414, MAT2007-61621, MAT2011-24284, Consolider Ingenio ...[+]
Type: Artículo

References

Real, J. A., Gaspar, A. B., & Muñoz, M. C. (2005). Thermal, pressure and light switchable spin-crossover materials. Dalton Transactions, (12), 2062. doi:10.1039/b501491c

Halcrow, M. A. (2007). The spin-states and spin-transitions of mononuclear iron(II) complexes of nitrogen-donor ligands. Polyhedron, 26(14), 3523-3576. doi:10.1016/j.poly.2007.03.033

NIHEI, M., SHIGA, T., MAEDA, Y., & OSHIO, H. (2007). Spin crossover iron(III) complexes. Coordination Chemistry Reviews, 251(21-24), 2606-2621. doi:10.1016/j.ccr.2007.08.007 [+]
Real, J. A., Gaspar, A. B., & Muñoz, M. C. (2005). Thermal, pressure and light switchable spin-crossover materials. Dalton Transactions, (12), 2062. doi:10.1039/b501491c

Halcrow, M. A. (2007). The spin-states and spin-transitions of mononuclear iron(II) complexes of nitrogen-donor ligands. Polyhedron, 26(14), 3523-3576. doi:10.1016/j.poly.2007.03.033

NIHEI, M., SHIGA, T., MAEDA, Y., & OSHIO, H. (2007). Spin crossover iron(III) complexes. Coordination Chemistry Reviews, 251(21-24), 2606-2621. doi:10.1016/j.ccr.2007.08.007

Gamez, P., Costa, J. S., Quesada, M., & Aromí, G. (2009). Iron Spin-Crossover compounds: from fundamental studies to practical applications. Dalton Transactions, (38), 7845. doi:10.1039/b908208e

Olguín, J., & Brooker, S. (2011). Spin crossover active iron(II) complexes of selected pyrazole-pyridine/pyrazine ligands. Coordination Chemistry Reviews, 255(1-2), 203-240. doi:10.1016/j.ccr.2010.08.002

Bousseksou, A., Molnár, G., Salmon, L., & Nicolazzi, W. (2011). Molecular spin crossover phenomenon: recent achievements and prospects. Chemical Society Reviews, 40(6), 3313. doi:10.1039/c1cs15042a

Koenig, E., Ritter, G., Kulshreshtha, S. K., & Nelson, S. M. (1982). The high-spin (5T2) .dblharw. low-spin (1A1) transition in solid tris(2,2’-bi-2-imidazoline)iron(II) diperchlorate. Hysteresis effects, simultaneous change of spin and lattice characteristics, and order-disorder phenomena of the perchlorate anion. Inorganic Chemistry, 21(8), 3022-3029. doi:10.1021/ic00138a020

Holland, J. M., Kilner, C. A., Thornton-Pett, M., Halcrow, M. A., McAllister, J. A., & Lu, Z. (2001). An unusual abrupt thermal spin-state transition in [FeL2][BF4]2 [L = 2,6-di(pyrazol-1-yl)pyridine]. Chemical Communications, (6), 577-578. doi:10.1039/b100995h

Matouzenko, G. S., Bousseksou, A., Borshch, S. A., Perrin, M., Zein, S., Salmon, L., … Lecocq, S. (2004). Cooperative Spin Crossover and Order−Disorder Phenomena in a Mononuclear Compound [Fe(DAPP)(abpt)](ClO4)2[DAPP = [Bis(3-aminopropyl)(2-pyridylmethyl)amine], abpt = 4-Amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole]. Inorganic Chemistry, 43(1), 227-236. doi:10.1021/ic034450e

Money, V. A., Elhaïk, J., Radosavljevic Evans, I., Halcrow, M. A., & Howard, J. A. K. (2004). A study of the thermal and light induced spin transition in [FeL2](BF4)2and [FeL2](ClO4)2L = 2,6-di(3-methylpyrazol-1-yl)pyrazine. Dalton Trans., (1), 65-69. doi:10.1039/b311262b

Craig, G. A., Sánchez Costa, J., Roubeau, O., Teat, S. J., & Aromí, G. (2011). Coupled Crystallographic Order–Disorder and Spin State in a Bistable Molecule: Multiple Transition Dynamics. Chemistry – A European Journal, 17(11), 3120-3127. doi:10.1002/chem.201003197

Mikami, M., Konno, M., & Saito, Y. (1979). The structure changes and the spin phase transition mechanism of a spin crossover complex, [Fe(2-pic)3]Cl2·EtOH. Chemical Physics Letters, 63(3), 566-569. doi:10.1016/0009-2614(79)80715-0

Chernyshov, D., Hostettler, M., Törnroos, K. W., & Bürgi, H.-B. (2003). Ordnungsphänomene und Phasenübergänge in einer Spin-Crossover-Verbindung:[Fe(2-pic)3]Cl2⋅EtOH durchläuft eine geordnete Zwischenphase. Angewandte Chemie, 115(32), 3955-3960. doi:10.1002/ange.200351834

Chernyshov, D., Hostettler, M., Törnroos, K. W., & Bürgi, H.-B. (2003). Ordering Phenomena and Phase Transitions in a Spin-Crossover Compound—Uncovering the Nature of the Intermediate Phase of[Fe(2-pic)3]Cl2⋅EtOH. Angewandte Chemie International Edition, 42(32), 3825-3830. doi:10.1002/anie.200351834

Hostettler, M., Törnroos, K. W., Chernyshov, D., Vangdal, B., & Bürgi, H.-B. (2004). Engineering von Spin-Crossover-Verbindungen? Strukturen und magnetische Eigenschaften von sechs Alkoholsolvaten des Tris(2-picolylamin)eisen(II)-dichlorids. Angewandte Chemie, 116(35), 4689-4695. doi:10.1002/ange.200460736

Hostettler, M., Törnroos, K. W., Chernyshov, D., Vangdal, B., & Bürgi, H.-B. (2004). Challenges in Engineering Spin Crossover: Structures and Magnetic Properties of Six Alcohol Solvates of Iron(II) Tris(2-picolylamine) Dichloride. Angewandte Chemie International Edition, 43(35), 4589-4594. doi:10.1002/anie.200460736

Törnroos, K. W., Hostettler, M., Chernyshov, D., Vangdal, B., & Bürgi, H.-B. (2006). Interplay of Spin Conversion and Structural Phase Transformations: Re-Entrant Phase Transitions in the 2-Propanol Solvate of Tris(2-picolylamine)iron(II) Dichloride. Chemistry - A European Journal, 12(24), 6207-6215. doi:10.1002/chem.200600547

Chernyshov, D., Klinduhov, N., Törnroos, K. W., Hostettler, M., Vangdal, B., & Bürgi, H.-B. (2007). Coupling between spin conversion and solvent disorder in spin crossover solids. Physical Review B, 76(1). doi:10.1103/physrevb.76.014406

Chernyshov, D., Vangdal, B., Törnroos, K. W., & Bürgi, H.-B. (2009). Chemical disorder and spin crossover in a mixed ethanol–2-propanol solvate of FeII tris(2-picolylamine) dichloride. New Journal of Chemistry, 33(6), 1277. doi:10.1039/b823514g

Matouzenko, G. S., Luneau, D., Molnár, G., Ould-Moussa, N., Zein, S., Borshch, S. A., … Averseng, F. (2006). A Two-Step Spin Transition and Order–Disorder Phenomena in the Mononuclear Compound [Fe(Hpy-DAPP)](BF4)2. European Journal of Inorganic Chemistry, 2006(13), 2671-2682. doi:10.1002/ejic.200600068

Lakhloufi, S., Guionneau, P., Lemée-Cailleau, M. H., Rosa, P., & Létard, J.-F. (2010). Structural phase transition in the spin-crossover complex[Fe(ptz)6](BF4)2studied by x-ray diffraction. Physical Review B, 82(13). doi:10.1103/physrevb.82.132104

Ross, T. M., Moubaraki, B., Wallwork, K. S., Batten, S. R., & Murray, K. S. (2011). A temperature-dependent order-disorder and crystallographic phase transition in a 0D Feii spin crossover compound and its non-spin crossover Coii isomorph. Dalton Transactions, 40(39), 10147. doi:10.1039/c1dt10961h

Boinnard, D., Bousseksou, A., Dworkin, A., Savariault, J. M., Varret, F., & Tuchagues, J. P. (1994). Two-step spin conversion of [FeII(5-NO2-sal-N(1,4,7,10))]: 292, 153, and 103 K x-ray crystal and molecular structure, infrared, magnetic, Moessbauer, calorimetric, and theoretical studies. Inorganic Chemistry, 33(2), 271-281. doi:10.1021/ic00080a015

Létard, J.-F., Guionneau, P., Codjovi, E., Lavastre, O., Bravic, G., Chasseau, D., & Kahn, O. (1997). Wide Thermal Hysteresis for the Mononuclear Spin-Crossover Compoundcis-Bis(thiocyanato)bis[N-(2‘-pyridylmethylene)-4-(phenylethynyl)anilino]iron(II). Journal of the American Chemical Society, 119(44), 10861-10862. doi:10.1021/ja972441x

Thompson, A. L., Goeta, A. E., Real, J. A., Galet, A., & Carmen Muñoz, M. (2004). Thermal and light induced polymorphism in iron(ii) spin crossover compounds. Chem. Commun., (12), 1390-1391. doi:10.1039/b403179b

Bonnet, S., Siegler, M. A., Costa, J. S., Molnár, G., Bousseksou, A., Spek, A. L., … Reedijk, J. (2008). A two-step spin crossover mononuclear iron(ii) complex with a [HS–LS–LS] intermediate phase. Chemical Communications, (43), 5619. doi:10.1039/b811746b

Krivokapic, I., Enachescu, C., Bronisz, R., & Hauser, A. (2008). Spin transition and relaxation dynamics coupled to a crystallographic phase transition in a polymeric iron(II) spin-crossover system. Chemical Physics Letters, 455(4-6), 192-196. doi:10.1016/j.cplett.2008.02.088

Martínez, V., Gaspar, A. B., Muñoz, M. C., Bukin, G. V., Levchenko, G., & Real, J. A. (2009). Synthesis and Characterisation of a New Series of Bistable Iron(II) Spin-Crossover 2D Metal-Organic Frameworks. Chemistry - A European Journal, 15(41), 10960-10971. doi:10.1002/chem.200901391

Xia, Y., Xiong, Y., Lim, B., & Skrabalak, S. E. (2008). Titelbild: Formkontrolle bei der Synthese von Metallnanokristallen: einfache Chemie, komplexe Physik? (Angew. Chem. 1/2009). Angewandte Chemie, 121(1), 1-1. doi:10.1002/ange.200890324

Xia, Y., Xiong, Y., Lim, B., & Skrabalak, S. E. (2008). Cover Picture: Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics? (Angew. Chem. Int. Ed. 1/2009). Angewandte Chemie International Edition, 48(1), 1-1. doi:10.1002/anie.200890275

Kaiba, A., Shepherd, H. J., Fedaoui, D., Rosa, P., Goeta, A. E., Rebbani, N., … Guionneau, P. (2010). Crystallographic elucidation of purely structural, thermal and light-induced spin transitions in an iron(ii) binuclear complex. Dalton Transactions, 39(11), 2910. doi:10.1039/b914841h

Adams, C. J., Muñoz, M. C., Waddington, R. E., & Real, J. A. (2011). Cooperative Spin Transition in the Two-Dimensional Coordination Polymer [Fe(4,4′-bipyridine)2(NCX)2]·4CHCl3(X = S, Se). Inorganic Chemistry, 50(21), 10633-10642. doi:10.1021/ic200932w

Sciortino, N. F., Scherl-Gruenwald, K. R., Chastanet, G., Halder, G. J., Chapman, K. W., Létard, J.-F., & Kepert, C. J. (2012). Hysteretic Three-Step Spin Crossover in a Thermo- and Photochromic 3D Pillared Hofmann-type Metal-Organic Framework. Angewandte Chemie International Edition, 51(40), 10154-10158. doi:10.1002/anie.201204387

Bhar, K., Khan, S., Costa, J. S., Ribas, J., Roubeau, O., Mitra, P., & Ghosh, B. K. (2012). Crystallographic Evidence for Reversible Symmetry Breaking in a Spin-Crossover d7 Cobalt(II) Coordination Polymer. Angewandte Chemie International Edition, 51(9), 2142-2145. doi:10.1002/anie.201107116

Lin, J.-B., Xue, W., Wang, B.-Y., Tao, J., Zhang, W.-X., Zhang, J.-P., & Chen, X.-M. (2012). Chemical/Physical Pressure Tunable Spin-Transition Temperature and Hysteresis in a Two-Step Spin Crossover Porous Coordination Framework. Inorganic Chemistry, 51(17), 9423-9430. doi:10.1021/ic301237p

Tao, J., Wei, R.-J., Huang, R.-B., & Zheng, L.-S. (2012). Polymorphism in spin-crossover systems. Chem. Soc. Rev., 41(2), 703-737. doi:10.1039/c1cs15136c

Seredyuk, M., Gaspar, A. B., Ksenofontov, V., Reiman, S., Galyametdinov, Y., Haase, W., … Gütlich, P. (2006). Room Temperature Operational Thermochromic Liquid Crystals. Chemistry of Materials, 18(10), 2513-2519. doi:10.1021/cm052632w

Seredyuk, M., Gaspar, A. B., Ksenofontov, V., Galyametdinov, Y., Kusz, J., & Gütlich, P. (2008). Does the Solid−Liquid Crystal Phase Transition Provoke the Spin-State Change in Spin-Crossover Metallomesogens? Journal of the American Chemical Society, 130(4), 1431-1439. doi:10.1021/ja077265z

Seredyuk, M., Gaspar, A. B., Ksenofontov, V., Galyametdinov, Y., Kusz, J., & Gütlich, P. (2008). Iron(II) Metallomesogens Exhibiting Coupled Spin State and Liquid Crystal Phase Transitions near Room Temperature. Advanced Functional Materials, 18(14), 2089-2101. doi:10.1002/adfm.200800049

Seredyuk, M., Gaspar, A. B., Ksenofontov, V., Galyametdinov, Y., Verdaguer, M., Villain, F., & Gütlich, P. (2008). One-Dimensional Iron(II) Compounds Exhibiting Spin Crossover and Liquid Crystalline Properties in the Room Temperature Region. Inorganic Chemistry, 47(22), 10232-10245. doi:10.1021/ic8006266

Seredyuk, M., Gaspar, A. B., Ksenofontov, V., Galyametdinov, Y., Verdaguer, M., Villain, F., & Gütlich, P. (2010). Spin-Crossover and Liquid Crystal Properties in 2D Cyanide-Bridged FeII−MI/IIMetalorganic Frameworks. Inorganic Chemistry, 49(21), 10022-10031. doi:10.1021/ic101304v

Seredyuk, M. (2012). Iron(II) metallomesogens based on symmetrical tripod ligands. Inorganica Chimica Acta, 380, 65-71. doi:10.1016/j.ica.2011.08.014

Gaspar, A. B., Seredyuk, M., & Gütlich, P. (2009). Spin crossover in metallomesogens. Coordination Chemistry Reviews, 253(19-20), 2399-2413. doi:10.1016/j.ccr.2008.11.016

Schlamp, S., Weber, B., Naik, A. D., & Garcia, Y. (2011). Cooperative spin transition in a lipid layer like system. Chemical Communications, 47(25), 7152. doi:10.1039/c1cc12162f

Hayami, S., Komatsu, Y., Shimizu, T., Kamihata, H., & Lee, Y. H. (2011). Spin-crossover in cobalt(II) compounds containing terpyridine and its derivatives. Coordination Chemistry Reviews, 255(17-18), 1981-1990. doi:10.1016/j.ccr.2011.05.016

Hauser, A. (1995). Intersystem Crossing in Iron(II) Coordination Compounds: A Model Process Between Classical and Quantum Mechanical Behaviour. Comments on Inorganic Chemistry, 17(1), 17-40. doi:10.1080/02603599508035780

Létard, J.-F. (2006). Photomagnetism of iron(ii) spin crossover complexes—the T(LIESST) approach. J. Mater. Chem., 16(26), 2550-2559. doi:10.1039/b603473j

Sorai, M., Nakano, M., & Miyazaki, Y. (2006). Calorimetric Investigation of Phase Transitions Occurring in Molecule-Based Magnets†. Chemical Reviews, 106(3), 976-1031. doi:10.1021/cr960049g

Slichter, C. P., & Drickamer, H. G. (1972). Pressure‐Induced Electronic Changes in Compounds of Iron. The Journal of Chemical Physics, 56(5), 2142-2160. doi:10.1063/1.1677511

Chang, H. R., McCusker, J. K., Toftlund, H., Wilson, S. R., Trautwein, A. X., Winkler, H., & Hendrickson, D. N. (1990). [Tetrakis(2-pyridylmethyl)ethylenediamine]iron(II) perchlorate, the first rapidly interconverting ferrous spin-crossover complex. Journal of the American Chemical Society, 112(19), 6814-6827. doi:10.1021/ja00175a012

Purcell, K. F. (1979). Pseudorotational intersystem crossing in d6 complexes. Journal of the American Chemical Society, 101(18), 5147-5152. doi:10.1021/ja00512a005

Drew, M. G. B., Harding, C. J., McKee, V., Morgan, G. G., & Nelson, J. (1995). Geometric control of manganese redox state. Journal of the Chemical Society, Chemical Communications, (10), 1035. doi:10.1039/c39950001035

Bondi, A. (1964). van der Waals Volumes and Radii. The Journal of Physical Chemistry, 68(3), 441-451. doi:10.1021/j100785a001

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