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Thiodiacetate-manganese chemistry with N-ligands: unique control of the supramolecular arrangement over the metal coordination mode

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Thiodiacetate-manganese chemistry with N-ligands: unique control of the supramolecular arrangement over the metal coordination mode

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dc.contributor.author Grirrane, Abdessamad es_ES
dc.contributor.author Pastor, Antonio es_ES
dc.contributor.author Galindo, Agustín es_ES
dc.contributor.author Álvarez, Eleuterio es_ES
dc.contributor.author Mealli, Carlo es_ES
dc.contributor.author Ienco, Andrea es_ES
dc.contributor.author Orlandini, Annabella es_ES
dc.contributor.author Rosa, Patrick es_ES
dc.contributor.author Caneschi, Andrea es_ES
dc.contributor.author Barra, Anne-Laure es_ES
dc.contributor.author Fernández Sanz, Javier es_ES
dc.date.accessioned 2013-11-20T10:46:27Z
dc.date.issued 2011-09-12
dc.identifier.issn 0947-6539
dc.identifier.uri http://hdl.handle.net/10251/33808
dc.description.abstract [EN] Compounds based on the Mn-tda unit (tda=S(CH2COO)2 2) and N co-ligands have been analyzed in terms of structural, spectroscopic, magnetic properties and DFT calculations. The precursors [Mn(tda)(H2O)]n (1) and [Mn(tda)(H2O)3] H2O (2) have been characterized by powder and X-ray diffraction, respectively. Their derivatives with bipyridyl-type ligands have formulas [Mn(tda)(bipy)]n (3), [{Mn(N-N)}2(u-H2O)(u-tda)2]n (N-N=4,4'-Me2bipy (4), 5,5'-Me2bipy, (5)) and [Mn(tda){(MeO)2bipy} 2 H2O]n (6). Depending on the presence/position of substituents at bipy, the supramolecular arrangement can affect the metal coordination type. While all the complexes consist of 1D coordination polymers, only 3 has a copper-acetate core with local trigonal prismatic metal coordination. es_ES
dc.description.sponsorship Financial support from the Spanish Ministerio de Ciencia e Innovacion (CTQ2007-61037 and CTQ2010-15515, FEDER supported) and the Junta de Andalucia (Proyecto de Excelencia, P07-FQM-2474) is gratefully acknowledged. This work was also supported by Ministero dell'Istruzione, dell'Universita e della Ricerca (MIUR) through "Progetti di Rilevante Interesse Nazionale" (PRIN) project 2008RFEB3X "Aspetti elettronici di legame chimico, proprieta chimico-fisiche e reattivita di nanocluster metallici". We are grateful to CICA for permitting the use of their computational resources. Other computations were also carried out at the CINECA center, and the authors (A. I., C. M.) acknowledge the ISCRA-CINECA HP grant HP10BNL89W.
dc.format.extent 18 es_ES
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation MICINN/CTQ2007-61037 es_ES
dc.relation Junta de Andalucía/P07-FQM-2474 es_ES
dc.relation MIUR/2008RFEB3X es_ES
dc.relation info:eu-repo/grantAgreement/MICINN//CTQ2010-15515/ES/NUEVOS SISTEMAS CATALITICOS EN QUIMICA SOSTENIBLE MEDIANTE EL EMPLEO DE DISOLVENTES ALTERNATIVOS/
dc.relation ISCRA/HP10BNL89W
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Manganese es_ES
dc.subject Noncovalent interactions es_ES
dc.subject Stacking interactions es_ES
dc.subject Thiodiac es_ES
dc.subject Metal-organic frameworks es_ES
dc.title Thiodiacetate-manganese chemistry with N-ligands: unique control of the supramolecular arrangement over the metal coordination mode es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/chem.201100988
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Grirrane, A.; Pastor, A.; Galindo, A.; Álvarez, E.; Mealli, C.; Ienco, A.; Orlandini, A.... (2011). Thiodiacetate-manganese chemistry with N-ligands: unique control of the supramolecular arrangement over the metal coordination mode. Chemistry - A European Journal. 17:10600-10617. https://doi.org/10.1002/chem.201100988 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/chem.201100988 es_ES
dc.description.upvformatpinicio 10600 es_ES
dc.description.upvformatpfin 10617 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 17 es_ES
dc.relation.senia 193901
dc.identifier.pmid 21834105
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.contributor.funder Junta de Andalucía
dc.contributor.funder Ministero dell'Istruzione dell'Università e della Ricerca, Italia
dc.contributor.funder Italian SuperComputing Resource Allocation


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