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An electronic tongue designed to detect ammonium nitrate in aqueous solution

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An electronic tongue designed to detect ammonium nitrate in aqueous solution

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dc.contributor.author Campos Sánchez, Inmaculada es_ES
dc.contributor.author Pascual Vidal, Lluís es_ES
dc.contributor.author Soto Camino, Juan es_ES
dc.contributor.author Gil Sánchez, Luís es_ES
dc.contributor.author Martínez Mañez, Ramón es_ES
dc.date.accessioned 2014-03-28T11:51:43Z
dc.date.available 2014-03-28T11:51:43Z
dc.date.issued 2013-10-18
dc.identifier.issn 1424-8220
dc.identifier.uri http://hdl.handle.net/10251/36708
dc.description.abstract An electronic tongue has been developed to monitor the presence of ammonium nitrate in water. It is based on pulse voltammetry and consists of an array of eight working electrodes (Au; Pt; Rh; Ir; Cu; Co; Ag and Ni) encapsulated in a stainless steel cylinder. In a first step the electrochemical response of the different electrodes was studied in the presence of ammonium nitrate in water in order to further design the wave form used in the voltammetric tongue. The response of the electronic tongue was then tested in the presence of a set of 15 common inorganic salts; i.e.; NH4NO3; MgSO4; NH4Cl; NaCl; Na2CO3; (NH4)2SO4; MgCl2; Na3PO4; K2SO4; K2CO3; CaCl2; NaH2PO4; KCl; NaNO3; K2HPO4. A PCA plot showed a fairly good discrimination between ammonium nitrate and the remaining salts studied. In addition Fuzzy Art map analyses determined that the best classification was obtained using the Pt; Co; Cu and Ni electrodes. Moreover; PLS regression allowed the creation of a model to correlate the voltammetric response of the electrodes with concentrations of ammonium nitrate in the presence of potential interferents such as ammonium chloride and sodium nitrate. es_ES
dc.language Inglés es_ES
dc.publisher MDPI es_ES
dc.relation.ispartof Sensors es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Ammonium nitrate es_ES
dc.subject Electronic tongue es_ES
dc.subject PCA es_ES
dc.subject Fuzzy ARTMAP es_ES
dc.subject PLS es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.subject.classification TECNOLOGIA ELECTRONICA es_ES
dc.title An electronic tongue designed to detect ammonium nitrate in aqueous solution es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/s131014064
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Electrónica - Departament d'Enginyeria Electrònica es_ES
dc.description.bibliographicCitation Campos Sánchez, I.; Pascual Vidal, L.; Soto Camino, J.; Gil Sánchez, L.; Martínez Mañez, R. (2013). An electronic tongue designed to detect ammonium nitrate in aqueous solution. Sensors. 13(10):14064-14078. doi:10.3390/s131014064 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.3390/s131014064 es_ES
dc.description.upvformatpinicio 14064 es_ES
dc.description.upvformatpfin 14078 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 13 es_ES
dc.description.issue 10 es_ES
dc.relation.senia 259357
dc.identifier.pmid 24145916 en_EN
dc.identifier.pmcid PMC3859109 en_EN
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