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Sensitive determination of Fenamiphos in water samples by flow injection photoinduced chemiluminescence

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Sensitive determination of Fenamiphos in water samples by flow injection photoinduced chemiluminescence

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dc.contributor.author Gómez Benito, Carmen es_ES
dc.contributor.author Meseguer Lloret, Susana es_ES
dc.contributor.author Torres Cartas, Sagrario es_ES
dc.date.accessioned 2014-04-24T14:39:37Z
dc.date.issued 2013-02-01
dc.identifier.issn 0306-7319
dc.identifier.uri http://hdl.handle.net/10251/37135
dc.description.abstract In this work, a sensitive flow injection chemiluminescence (FI-CL) method for the determination of nematicide Fenamiphos in a rapid and simple way is proposed. Fenamiphos is first photodegraded in basic medium. These photofragments react with Ce(IV) providing the chemiluminescence signal. To the authors' knowledge, no chemiluminescence method has been described in the literature for the determination of the nematicide Fenamiphos. All physical and chemical parameters in the flow injection chemiluminescence system were optimized in order to obtain the best sensitivity, selectivity and sample throughput. Before the injection of the sample in the FI-CL system, a preconcentration step with solid phase extraction C18 cartridges was performed. By applying solid phase extraction (SPE) to 250 mL of standard (final volume 10 mL), the linear dynamic range was between 3.4 and 60 µg L-1, and the detection limit was 1 µg L-1. When SPE was applied to 500 mL of standard (final volume 10 mL), the detection limit was 0.5 µg L-1. These detection limits are below the emission limit value established by the Spanish Regulations of the Hydraulic Public Domain for pesticides (50 µg L-1) and of the same order as the limit established for total pesticides (0.5 µg L-1) at European Directive on the quality of water for human consumption. The sample throughput was 126 hour-1. Intraday and interday coefficients of variation were below 10% in all cases. No interference was registered in presence of usual concentrations of anions, cations and other organophosphorus pesticides. The method was successfully applied to the analysis of environmental water samples, obtaining recoveries between 96 and 107.5%. © 2013 Copyright Taylor and Francis Group, LLC. es_ES
dc.description.sponsorship The authors are grateful to The Spanish Ministry of Education and Science and FEDER funds for financial support: Project CTM2006-11991. en_EN
dc.format.extent 14 es_ES
dc.language Inglés es_ES
dc.publisher Taylor & Francis: STM, Behavioural Science and Public Health Titles es_ES
dc.relation.ispartof International Journal of Environmental Analytical Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Fenamiphos es_ES
dc.subject Chemiluminescence es_ES
dc.subject Flow injection analysis es_ES
dc.subject Solid phase extraction es_ES
dc.subject Water es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Sensitive determination of Fenamiphos in water samples by flow injection photoinduced chemiluminescence es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1080/03067319.2012.663755
dc.relation.projectID info:eu-repo/grantAgreement/MEC//CTM2006-11991/ES/DESARROLLO DE METODOS SENCILLOS EN FLUJO CONTINUO CON DETECCION QUIMIOLUMINISCENTE APLICADOS AL CONTROL DE PLAGUICIDAS EN LOS CULTIVOS DE CITRICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Investigación para la Gestión Integral de Zonas Costeras - Institut d'Investigació per a la Gestió Integral de Zones Costaneres es_ES
dc.description.bibliographicCitation Gómez Benito, C.; Meseguer Lloret, S.; Torres Cartas, S. (2013). Sensitive determination of Fenamiphos in water samples by flow injection photoinduced chemiluminescence. International Journal of Environmental Analytical Chemistry. 93(2):152-165. https://doi.org/10.1080/03067319.2012.663755 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1080/03067319.2012.663755 es_ES
dc.description.upvformatpinicio 152 es_ES
dc.description.upvformatpfin 165 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 93 es_ES
dc.description.issue 2 es_ES
dc.relation.senia 239840
dc.contributor.funder Ministerio de Educación y Ciencia es_ES
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