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Aryl carbinols as nerve agent probes. Influence of the conjugation on the sensing properties

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Aryl carbinols as nerve agent probes. Influence of the conjugation on the sensing properties

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dc.contributor.author Royo Calvo, Santiago es_ES
dc.contributor.author Gotor Candel, Raul Jesús es_ES
dc.contributor.author Costero Nieto, Ana María es_ES
dc.contributor.author Parra Álvarez, Margarita es_ES
dc.contributor.author Gil Grau, Salvador es_ES
dc.contributor.author Martínez Mañez, Ramón es_ES
dc.contributor.author Sancenón Galarza, Félix es_ES
dc.date.accessioned 2014-05-09T13:54:27Z
dc.date.issued 2012-04-13
dc.identifier.issn 1144-0546
dc.identifier.uri http://hdl.handle.net/10251/37360
dc.description.abstract Two new aryl carbinols (1 and 3) have been synthesised and characterised and their ability as OFF-ON probes for the chromogenic detection of the nerve agent simulant in acetonitrile has been tested. In addition compound 2 has been also studied. The carbinols suffered a phosphorylation reaction followed by an elimination process giving rise to the corresponding carbocations. This transformation of the carbinol into the carbocation is responsible for a significant color change. © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2012. es_ES
dc.description.sponsorship Financial support from the Spanish Government (project MAT2009-14564-C04-01) and the Generalitat Valencia (project PROMETEO/2009/016) is gratefully acknowledged. R. G. is grateful to the Spanish Ministry of Education and S. R. to Generalitat Valencia for their grants. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof New Journal of Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Acetonitrile es_ES
dc.subject Chemical warfare agent es_ES
dc.subject Methanol derivative es_ES
dc.subject Chemical reaction es_ES
dc.subject Elimination reaction es_ES
dc.subject Molecular probe es_ES
dc.subject Phosphorylation es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Aryl carbinols as nerve agent probes. Influence of the conjugation on the sensing properties es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1039/c2nj40104e
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2009-14564-C04-01/ES/Nanomateriales Hibridos Para El Desarrollo De "Puertas Moleculares" De Aplicacion En Procesos De Reconocimiento Y Terapeutica Y Para La Deteccion De Explosivos./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Generalitat Valenciana//PROMETEO09%2F2009%2F016/ES/Ayuda prometeo 2009 para el grupo de diseño y desarrollo de sensores/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Royo Calvo, S.; Gotor Candel, RJ.; Costero Nieto, AM.; Parra Álvarez, M.; Gil Grau, S.; Martínez Mañez, R.; Sancenón Galarza, F. (2012). Aryl carbinols as nerve agent probes. Influence of the conjugation on the sensing properties. New Journal of Chemistry. 36(12):1485-1489. https://doi.org/10.1039/c2nj40104e es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c2nj40104e es_ES
dc.description.upvformatpinicio 1485 es_ES
dc.description.upvformatpfin 1489 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 36 es_ES
dc.description.issue 12 es_ES
dc.relation.senia 230309
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Ministerio de Educación es_ES
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