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The potential of flavonoids as natural antioxidants and UV light stabilizers for polypropylene

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The potential of flavonoids as natural antioxidants and UV light stabilizers for polypropylene

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dc.contributor.author Samper Madrigal, María Dolores es_ES
dc.contributor.author Fages, E. es_ES
dc.contributor.author Fenollar Gimeno, Octavio Ángel es_ES
dc.contributor.author Boronat Vitoria, Teodomiro es_ES
dc.contributor.author Balart Gimeno, Rafael Antonio es_ES
dc.date.accessioned 2014-06-14T10:22:09Z
dc.date.issued 2013-08-15
dc.identifier.issn 0021-8995
dc.identifier.uri http://hdl.handle.net/10251/38145
dc.description.abstract This article presents a study on the stabilization of polypropylene against thermo-oxidation and UV radiation by using natural phenolic compounds derived from the structures of flavonoids: a flavone (chrysin), a flavanol (quercetin), two flavanone glycosides (hesperidin and naringin), and flavanoligand (silibinin). Thermal stabilization has been assessed in an oxidizing atmosphere by means of differential scanning calorimetry both in isothermal and in dynamic conditions. In addition, the effectiveness of these phenolic compounds as thermal stabilizers at high temperature has been quantified with the use of thermogravimetric analysis. Stabilization against UV radiation has been estimated by studying the morphology changes of the exposed surfaces by scanning electron microscope (SEM); also, surface chemical changes have been followed by infrared spectroscopy. Global results show that flavonoid compounds of type flavonols (quercetin and silibinin) provide the best results in stabilizing both against oxidation and against the action of UV radiation. (c) 2012 Wiley Periodicals, Inc. es_ES
dc.description.sponsorship This study is part of the project IPT-310000-2010-037, "ECOTEX-COMP: Research and development of textile structures useful as reinforcement of composite materials with marked ecological character" funded by the "Ministerio de Ciencia e Innovacion," with an aid of 189540.20 euros, within the "Plan Nacional de Investigacion Cientifica, Desarrollo e Innovacion Tecnologica 2008-2011" and funded by the European Union through FEDER funds, "Technology Fund 2007-2013, Operational Programme on R+D+i for and on behalf of the companies." Also, Generalitat Valenciana Ref: ACOMP/2012/087 is acknowledged for financial support. en_EN
dc.language Inglés es_ES
dc.publisher Wiley es_ES
dc.relation.ispartof Journal of Applied Polymer Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Ageing es_ES
dc.subject Crystallization es_ES
dc.subject Degradation es_ES
dc.subject Properties and characterization es_ES
dc.subject Glass transition es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.subject.classification INGENIERIA DE LOS PROCESOS DE FABRICACION es_ES
dc.title The potential of flavonoids as natural antioxidants and UV light stabilizers for polypropylene es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/app.38871
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//IPT-310000-2010-037/ES/ECOTEXCOMP: Investigación y desarrollo de estructuras textiles aplicables como refuerzo de materiales compuestos de marcado carácter ecológico./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//ACOMP%2F2012%2F087/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation Samper Madrigal, MD.; Fages, E.; Fenollar Gimeno, OÁ.; Boronat Vitoria, T.; Balart Gimeno, RA. (2013). The potential of flavonoids as natural antioxidants and UV light stabilizers for polypropylene. Journal of Applied Polymer Science. 129(4):1707-1716. https://doi.org/10.1002/app.38871 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://onlinelibrary.wiley.com/doi/10.1002/app.38871/abstract;jsessionid=047063166288351AD8E60AEF2279538E.f01t01 es_ES
dc.description.upvformatpinicio 1707 es_ES
dc.description.upvformatpfin 1716 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 129 es_ES
dc.description.issue 4 es_ES
dc.relation.senia 255862
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Generalitat Valenciana es_ES
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