- -

Bromate catalytic reduction in continuous mode using metal catalysts supported on monoliths coated with carbon nonofibers

RiuNet: Institutional repository of the Polithecnic University of Valencia

Share/Send to

Cited by

Statistics

Bromate catalytic reduction in continuous mode using metal catalysts supported on monoliths coated with carbon nonofibers

Show simple item record

Files in this item

dc.contributor.author Marco, Yanila es_ES
dc.contributor.author García-Bordejé, Enrique es_ES
dc.contributor.author Franch Martí, Cristina es_ES
dc.contributor.author Palomares Gimeno, Antonio Eduardo es_ES
dc.contributor.author Yuranova, Tatiana es_ES
dc.contributor.author Kiwi-Minsker, Liouba es_ES
dc.date.accessioned 2014-06-24T13:47:55Z
dc.date.issued 2013-08-15
dc.identifier.issn 1385-8947
dc.identifier.uri http://hdl.handle.net/10251/38334
dc.description.abstract [EN] Nitrogen-doped and un-doped carbon nanofibers layers, denoted as N-CNFs and CNFs respectively, coating the walls of cordierite monoliths have been used as support for Pd and Ru catalyst. They have been tested in bromate reduction in batch and continuous operation employing different reactor configurations. The CNF/monolith catalysts were benchmarked with Pd catalyst on CNF coated on another structured support, namely sintered metal fibers. CNF/monolith is a robust, active and stable catalyst for bromate reduction. The catalyst shows stable performance when operating in monolithic reactor and the CNFs showed excellent attachment to the monolith. The comparison of intrinsic activity of catalysts in batch experiments (free of diffusional limitations) revealed that Pd supported on CNF/monolith exhibited higher intrinsic activity than Pd on CNF/SMFs. Pd metal showed significantly higher specific activity than Ru. The doping of CNF with nitrogen, although contribute to decrease reoxidation propensity of metal does not supplies higher activity in bromate reduction. es_ES
dc.description.sponsorship The authors thank the European Union (European Community’s Seventh Framework Programme FP7/2007-2013 under Grant Agreement No. 226347 Project) for financial support. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Chemical Engineering Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Monoliths es_ES
dc.subject Carbon nanofibers es_ES
dc.subject Nitrogen-doping es_ES
dc.subject Catalytic structured reactor es_ES
dc.subject Bromate reduction es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Bromate catalytic reduction in continuous mode using metal catalysts supported on monoliths coated with carbon nonofibers es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1016/j.cej.2013.06.040
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/226347/EU es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Marco, Y.; García-Bordejé, E.; Franch Martí, C.; Palomares Gimeno, AE.; Yuranova, T.; Kiwi-Minsker, L. (2013). Bromate catalytic reduction in continuous mode using metal catalysts supported on monoliths coated with carbon nonofibers. Chemical Engineering Journal. 230:605-611. https://doi.org/10.1016/j.cej.2013.06.040 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1016/j.cej.2013.06.040 es_ES
dc.description.upvformatpinicio 605 es_ES
dc.description.upvformatpfin 611 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 230 es_ES
dc.relation.senia 262614
dc.contributor.funder European Commission


This item appears in the following Collection(s)

Show simple item record