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Cu mixed oxides based on hydrotalcite-like compounds for the oxidation of trichloroethylene

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Cu mixed oxides based on hydrotalcite-like compounds for the oxidation of trichloroethylene

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dc.contributor.author Blanch Raga, Neus es_ES
dc.contributor.author Palomares Gimeno, Antonio Eduardo es_ES
dc.contributor.author Martínez Triguero, Luis Joaquín es_ES
dc.contributor.author Fetter, Geolar es_ES
dc.contributor.author Bosch, P. es_ES
dc.date.accessioned 2014-09-24T11:04:11Z
dc.date.issued 2013-11-13
dc.identifier.issn 0888-5885
dc.identifier.uri http://hdl.handle.net/10251/39962
dc.description Consolider Ingenio Multicat MAT-2012-3856-C02-01 es_ES
dc.description.abstract [EN] Different Cu/(Mg or Ni)/Al mixed oxides based on hydrotalcite-like compounds have been studied for the catalytic oxidation of trichloroethylene. The catalysts have been synthesized and characterized by different techniques such as N-2-adsorption, inductively coupled plasma (ICP), X-ray diffraction, and temperature-programmed reduction (TPR). It has been shown that the activity for the catalytic abatement of trichloroethylene depends on the presence of metals with redox properties in the catalyst composition. The best results have been obtained with containing copper mixed oxides, although there is no direct correspondence between the copper content and the catalyst activity. These catalysts are highly active and selective, CO2 and HCl being the main reaction products. A mechanism for the reaction has been proposed. es_ES
dc.description.sponsorship The authors wish to thank CONACYT (project 154060), the Spanish Ministry of Economy and Competitiveness through the Severo Ochoa program (SEV-2012-0267), as well as operating grants Consolider Ingenio Multicat (CSD-2009-00050) and MAT-2012-3856-C02-01 for the financial support. N.B.R. acknowledges Catedra Cemex Sostenibilidad (UPV) for a fellowship. The technical work of Adriana Tejeda in X-ray diffraction is also gratefully recognized.
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof Industrial and Engineering Chemistry Research es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Temperature-Programmed Reduction es_ES
dc.subject Volatile Organic-Compounds es_ES
dc.subject Catalytic-Oxidation es_ES
dc.subject Chlorinated Hydrocarbons es_ES
dc.subject Nickel-Catalysts es_ES
dc.subject Destruction es_ES
dc.subject Copper es_ES
dc.subject Decomposition es_ES
dc.subject Precursors es_ES
dc.subject Vocs es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Cu mixed oxides based on hydrotalcite-like compounds for the oxidation of trichloroethylene es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1021/ie4024935
dc.relation.projectID info:eu-repo/grantAgreement/CONACyT//154060/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ / es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Blanch Raga, N.; Palomares Gimeno, AE.; Martínez Triguero, LJ.; Fetter, G.; Bosch, P. (2013). Cu mixed oxides based on hydrotalcite-like compounds for the oxidation of trichloroethylene. Industrial and Engineering Chemistry Research. 52(45):15772-15779. https://doi.org/10.1021/ie4024935 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1021/ie4024935 es_ES
dc.description.upvformatpinicio 15772 es_ES
dc.description.upvformatpfin 15779 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 52 es_ES
dc.description.issue 45 es_ES
dc.relation.senia 260384
dc.contributor.funder Ministerio de Economía y Competitividad
dc.contributor.funder Consejo Nacional de Ciencia y Tecnología, México
dc.contributor.funder Universitat Politècnica de València
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES


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