- -

Mechanical and Thermal Properties of Polyvinyl Chloride Plasticized with Natural Fatty Acid Esters

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

Mechanical and Thermal Properties of Polyvinyl Chloride Plasticized with Natural Fatty Acid Esters

Mostrar el registro sencillo del ítem

Ficheros en el ítem

dc.contributor.author Fenollar Gimeno, Octavio Ángel es_ES
dc.contributor.author García Sanoguera, David es_ES
dc.contributor.author Sánchez Nacher, Lourdes es_ES
dc.contributor.author Boronat Vitoria, Teodomiro es_ES
dc.contributor.author López Martínez, Juan es_ES
dc.contributor.author Balart Gimeno, Rafael Antonio es_ES
dc.date.accessioned 2014-10-23T11:36:31Z
dc.date.available 2014-10-23T11:36:31Z
dc.date.issued 2013-06-21
dc.identifier.issn 0360-2559
dc.identifier.uri http://hdl.handle.net/10251/43557
dc.description.abstract From an industrial point of view, the use of new nontoxic and biodegradable plasticizers coming from natural resources is an interesting alternative to traditional plasticizers based on phthalates. In this study, two types of epoxidized fatty acids esters (EFAE) with different molecular weights have been used in order to produce flexible PVC with low toxicity. Different amounts of EFAE 201 and 401 have been considered in this study. Mechanical and thermal properties have been determined and morphology of fracture surface has been studied by scanning electron microscopy. es_ES
dc.description.sponsorship This work was supported by the "Ministerio de Ciencia e Innovacion" [Grant number IPT-310000-2010-37] and the "Universitat Politecnica de Valencia" [Grant number PAID 06-10 Ref: 003-300]. en_EN
dc.language Inglés es_ES
dc.publisher Taylor & Francis: STM, Behavioural Science and Public Health Titles es_ES
dc.relation.ispartof Polymer-Plastics Technology and Engineering es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Mechanical properties es_ES
dc.subject Natural plasticizer es_ES
dc.subject Polyvinyl chloride es_ES
dc.subject Thermal properties es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.subject.classification INGENIERIA DE LOS PROCESOS DE FABRICACION es_ES
dc.title Mechanical and Thermal Properties of Polyvinyl Chloride Plasticized with Natural Fatty Acid Esters es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1080/03602559.2013.763352
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//IPT-310000-2010-037/ES/ECOTEXCOMP: Investigación y desarrollo de estructuras textiles aplicables como refuerzo de materiales compuestos de marcado carácter ecológico/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UPV//PAID-06-10-003-300/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.description.bibliographicCitation Fenollar Gimeno, OÁ.; García Sanoguera, D.; Sánchez Nacher, L.; Boronat Vitoria, T.; López Martínez, J.; Balart Gimeno, RA. (2013). Mechanical and Thermal Properties of Polyvinyl Chloride Plasticized with Natural Fatty Acid Esters. Polymer-Plastics Technology and Engineering. 52(8):761-767. https://doi.org/10.1080/03602559.2013.763352 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1080/03602559.2013.763352 es_ES
dc.description.upvformatpinicio 761 es_ES
dc.description.upvformatpfin 767 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 52 es_ES
dc.description.issue 8 es_ES
dc.relation.senia 256168
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.description.references Zhao, R., Neighbour, G., Deutz, P., & McGuire, M. (2012). Materials selection for cleaner production: An environmental evaluation approach. Materials & Design, 37, 429-434. doi:10.1016/j.matdes.2012.01.014 es_ES
dc.description.references Biedermann-Brem, S., Biedermann, M., Fiselier, K., & Grob, K. (2005). Compositional GC-FID analysis of the additives to PVC, focusing on the gaskets of lids for glass jars. Food Additives and Contaminants, 22(12), 1274-1284. doi:10.1080/02652030500309426 es_ES
dc.description.references Braun, D. (2001). PVC ? origin, growth, and future. Journal of Vinyl and Additive Technology, 7(4), 168-176. doi:10.1002/vnl.10288 es_ES
dc.description.references Summers, J. W. (1997). A review of vinyl technology. Journal of Vinyl and Additive Technology, 3(2), 130-139. doi:10.1002/vnl.10179 es_ES
dc.description.references Islam, R., Islam, T., Nigar, F., Saha, S., Tapash, A., Sharmin, N., … Zaman, H. U. (2011). Fabrication and Mechanical Characterization of Jute Fabrics: Reinforced Polyvinyl Chloride/Polypropylene Hybrid Composites. International Journal of Polymeric Materials, 60(8), 576-590. doi:10.1080/00914037.2010.531822 es_ES
dc.description.references Khan, R. A., Sharmin, N., Khan, M. A., Das, A. K., Dey, K., Saha, S., … Saha, M. (2011). Comparative Studies of Mechanical and Interfacial Properties Between Jute Fiber/PVC and E-Glass Fiber/PVC Composites. Polymer-Plastics Technology and Engineering, 50(2), 153-159. doi:10.1080/03602559.2010.531422 es_ES
dc.description.references Hassan, A., Akbari, A., Hing, N. K., & Ratnam, C. T. (2012). Mechanical and Thermal Properties of ABS/PVC Composites: Effect of Particles Size and Surface Treatment of Ground Calcium Carbonate. Polymer-Plastics Technology and Engineering, 51(5), 473-479. doi:10.1080/03602559.2011.651242 es_ES
dc.description.references Zhu, G., Liu, Y., & Wang, F. (2012). Surface Morphology and Properties of Rigid Poly(γ-benzylL-glutamate) Membrane Modified by Flexible Poly(Vinyl Chloride). International Journal of Polymeric Materials, 61(10), 737-747. doi:10.1080/00914037.2011.610044 es_ES
dc.description.references KAWAMURA, Y., KANNO, S., MUTSUGA, M., & TANAMOTO, K. (2006). Determination of Epoxidized Soybean Oil in Bottled Foods. Journal of the Food Hygienic Society of Japan (Shokuhin Eiseigaku Zasshi), 47(6), 243-248. doi:10.3358/shokueishi.47.243 es_ES
dc.description.references Marcilla, A., Garcia, S., & Garcia-Quesada, J. C. (2008). Migrability of PVC plasticizers. Polymer Testing, 27(2), 221-233. doi:10.1016/j.polymertesting.2007.10.007 es_ES
dc.description.references Wang, Q., & Storm, B. K. (2005). Separation and analysis of low molecular weight plasticizers in poly(vinyl chloride) tubes. Polymer Testing, 24(3), 290-300. doi:10.1016/j.polymertesting.2004.12.002 es_ES
dc.description.references Llop, C., Manrique, A., Navarro, R., Mijangos, C., & Reinecke, H. (2011). Control of the migration behavior of slip agents in polyolefin-based films. Polymer Engineering & Science, 51(9), 1763-1769. doi:10.1002/pen.21963 es_ES
dc.description.references Pedersen, G. A., Jensen, L. K., Fankhauser, A., Biedermann, S., Petersen, J. H., & Fabech, B. (2008). Migration of epoxidized soybean oil (ESBO) and phthalates from twist closures into food and enforcement of the overall migration limit. Food Additives & Contaminants: Part A, 25(4), 503-510. doi:10.1080/02652030701519088 es_ES
dc.description.references Jimenez, A., Lopez, J., Iannoni, A., & Kenny, J. M. (2001). Formulation and mechanical characterization of PVC plastisols based on low-toxicity additives. Journal of Applied Polymer Science, 81(8), 1881-1890. doi:10.1002/app.1621 es_ES
dc.description.references Shea, K. M. (2003). Pediatric Exposure and Potential Toxicity of Phthalate Plasticizers. PEDIATRICS, 111(6), 1467-1474. doi:10.1542/peds.111.6.1467 es_ES
dc.description.references Boudhani, H., Lainé, C., Fulchiron, R., Bounor-Legaré, V., & Cassagnau, P. (2009). Viscoelasticity and mechanical properties of reactive PVC plastisols. Polymer Engineering & Science, 49(6), 1089-1098. doi:10.1002/pen.21356 es_ES
dc.description.references Wang, M. Y., Zhou, N. Q., & Wen, S. P. (2009). The Effect of Concentrations of Modifying Agent and Plasticizer on Cell Morphology of PVC Microcellular Foam. Polymer-Plastics Technology and Engineering, 48(3), 303-309. doi:10.1080/03602550802675678 es_ES
dc.description.references Yang, B., Bai, Y., & Cao, Y. (2010). Effects of inorganic nano-particles on plasticizers migration of flexible PVC. Journal of Applied Polymer Science, 115(4), 2178-2182. doi:10.1002/app.31310 es_ES
dc.description.references Kilinç, S., İyim, T. B., Emik, S., & Özgümüş, S. (2005). Recycling of Waste PET: Usage as Secondary Plasticizer for PVC. Polymer-Plastics Technology and Engineering, 44(8-9), 1379-1388. doi:10.1080/03602550500208228 es_ES
dc.description.references Audic, J.-L., Reyx, D., & Brosse, J.-C. (2003). Migration of additives from food grade polyvinyl chloride (PVC) films: Effect of plasticization by polymeric modifiers instead of conventional plasticizers. Journal of Applied Polymer Science, 89(5), 1291-1299. doi:10.1002/app.12240 es_ES
dc.description.references Fankhauser-Noti, A., Biedermann-Brem, S., & Grob, K. (2006). PVC plasticizers/additives migrating from the gaskets of metal closures into oily food: Swiss market survey June 2005. European Food Research and Technology, 223(4), 447-453. doi:10.1007/s00217-005-0223-7 es_ES
dc.description.references Sharma, V., & Kundu, P. P. (2008). Condensation polymers from natural oils. Progress in Polymer Science, 33(12), 1199-1215. doi:10.1016/j.progpolymsci.2008.07.004 es_ES
dc.description.references Benaniba, M. ., Belhaneche-Bensemra, N., & Gelbard, G. (2001). Stabilizing effect of epoxidized sunflower oil on the thermal degradation of poly(vinyl chloride). Polymer Degradation and Stability, 74(3), 501-505. doi:10.1016/s0141-3910(01)00170-7 es_ES
dc.description.references Atek, D., Belhaneche-Bensemra, N., & Turki, M. (2010). Migration of Epoxidized Sunflower Oil and Dioctyl Phthalate from Rigid and Plasticized Poly(vinyl chloride). International Journal of Polymeric Materials, 59(5), 342-352. doi:10.1080/00914030903478909 es_ES
dc.description.references Ghiou, N., & Benaniba, M. T. (2010). The Effect of Epoxidized Sunflower Oil on the Miscibility of Plasticized PVC/NBR Blends. International Journal of Polymeric Materials, 59(7), 463-474. doi:10.1080/00914031003627007 es_ES
dc.description.references Taghizadeh, M. T., Nalbandi, N., & Bahadori, A. (2008). Stabilizing effect of epoxidized sunflower oil as a secondary stabilizer for Ca/Hg stabilized PVC. Express Polymer Letters, 2(1), 65-76. doi:10.3144/expresspolymlett.2008.9 es_ES
dc.description.references Fenollar, O., Garcia-Sanoguera, D., Sanchez-Nacher, L., Lopez, J., & Balart, R. (2010). Effect of the epoxidized linseed oil concentration as natural plasticizer in vinyl plastisols. Journal of Materials Science, 45(16), 4406-4413. doi:10.1007/s10853-010-4520-6 es_ES
dc.description.references Galià, M., de Espinosa, L. M., Ronda, J. C., Lligadas, G., & Cádiz, V. (2010). Vegetable oil-based thermosetting polymers. European Journal of Lipid Science and Technology, 112(1), 87-96. doi:10.1002/ejlt.200900096 es_ES
dc.description.references Nandanan, V., Joseph, R., & Francis, D. J. (1996). Linseed Oil as a Multipurpose Ingredient in NBR Vulcanizate. Journal of Elastomers & Plastics, 28(4), 326-334. doi:10.1177/009524439602800404 es_ES
dc.description.references Fenollar, O., García, D., Sánchez, L., López, J., & Balart, R. (2009). Optimization of the curing conditions of PVC plastisols based on the use of an epoxidized fatty acid ester plasticizer. European Polymer Journal, 45(9), 2674-2684. doi:10.1016/j.eurpolymj.2009.05.029 es_ES
dc.description.references Fenollar, O., Sanchez-Nacher, L., Garcia-Sanoguera, D., López, J., & Balart, R. (2009). The effect of the curing time and temperature on final properties of flexible PVC with an epoxidized fatty acid ester as natural-based plasticizer. Journal of Materials Science, 44(14), 3702-3711. doi:10.1007/s10853-009-3495-7 es_ES
dc.description.references Crespo, J. E., Balart, R., Sanchez, L., & López, J. (2007). Substitution of di(2-ethylhexyl) phthalate by di(isononyl) cyclohexane-1,2-dicarboxylate as a plasticizer for industrial vinyl plastisol formulations. Journal of Applied Polymer Science, 104(2), 1215-1220. doi:10.1002/app.25760 es_ES


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem