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A Switchable Molecular Rotator: Neutron Spectroscopy Study on a Polymeric Spin-Crossover Compound

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A Switchable Molecular Rotator: Neutron Spectroscopy Study on a Polymeric Spin-Crossover Compound

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Rodriguez-Velamazan, J.; Gonzalez, M.; Real, J.; Castro, M.; Muñoz Roca, MDC.; Gaspar, A.; Ohtani, R.... (2012). A Switchable Molecular Rotator: Neutron Spectroscopy Study on a Polymeric Spin-Crossover Compound. Journal of the American Chemical Society. 134(11):5083-5098. doi:10.1021/ja206228n

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Title: A Switchable Molecular Rotator: Neutron Spectroscopy Study on a Polymeric Spin-Crossover Compound
Author: Rodriguez-Velamazan, J.A. Gonzalez, M.A. Real, J.A. Castro, M. Muñoz Roca, María del Carmen Gaspar, A.B. Ohtani, R. Ohba, M. Yoneda, K. Hijikata, Y. Yanai, N. Mizuno, M. Ando, H. Kitagawa, S.
UPV Unit: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Issued date:
Abstract:
A quasielastic neutron scattering and solid-state H-2 NMR spectroscopy study of the polymeric spin-crossover compound {Fe(pyrazine)[Pt(CN)(4)]} shows that the switching of the rotation of a molecular fragment- the pyrazine ...[+]
Subjects: Porous Coordination Polymers , Room-Temperature , Dynamics , State , Crystals , Transition , Framework , Machines , Rotors
Copyrigths: Cerrado
Source:
Journal of the American Chemical Society. (issn: 0002-7863 )
DOI: 10.1021/ja206228n
Publisher:
American Chemical Society
Publisher version: http://dx.doi.org/10.1021/ja206228n
Thanks:
This work was supported by the Spanish MICINN and FEDER, projects MAT2007-61621, CSD2007-00010, MAT2011-27233-C02-02, and CTQ2010-18414, and by a CREST JST program and Grant-In-Aid for Scientific Research (No. 23245014 and ...[+]
Type: Artículo

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