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Isolation and X-ray characterization of palladium N complexes in the guanylation ofaromatic amines. Mechanistic implications

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Isolation and X-ray characterization of palladium N complexes in the guanylation ofaromatic amines. Mechanistic implications

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Nombre: Grirrane;García;E ...
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dc.contributor.author Grirrane, Abdessamad es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Álvarez, Eleuterio es_ES
dc.date.accessioned 2014-12-22T10:56:59Z
dc.date.available 2014-12-22T10:56:59Z
dc.date.issued 2013-07-22
dc.identifier.issn 1860-5397
dc.identifier.uri http://hdl.handle.net/10251/45654
dc.description.abstract In the context of palladium-catalyzed guanylation of anilines herein, we have been able to characterize and isolate bis(anilino) and bis(guanidino)Pd(II) complexes using reaction conditions under which stoichiometric amounts of palladium salts are used. Characterization of these palladium complexes strongly supports a mechanistic proposal for the catalytic guanylation of anilines using PdCl2(NCCH3)2 as catalyst that involves the intermediacy of these Pd(II) complexes. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Economy and competitiveness (Severo Ochoa and CTQ2012-36351) and Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged. en_EN
dc.language Inglés es_ES
dc.publisher Beilstein-Institut es_ES
dc.relation.ispartof Beilstein Journal of Organic Chemistry es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Coordination chemistry es_ES
dc.subject Guanylation reaction es_ES
dc.subject Homogeneous catalysis es_ES
dc.subject Palladium complexes es_ES
dc.subject Reactive intermediates es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Isolation and X-ray characterization of palladium N complexes in the guanylation ofaromatic amines. Mechanistic implications es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3762/bjoc.9.165
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F014/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Grirrane, A.; García Gómez, H.; Álvarez, E. (2013). Isolation and X-ray characterization of palladium N complexes in the guanylation ofaromatic amines. Mechanistic implications. Beilstein Journal of Organic Chemistry. 9:1455-1462. https://doi.org/10.3762/bjoc.9.165 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.3762/bjoc.9.165 es_ES
dc.description.upvformatpinicio 1455 es_ES
dc.description.upvformatpfin 1462 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 9 es_ES
dc.relation.senia 256265
dc.identifier.pmid 23946843 en_EN
dc.identifier.pmcid PMC3740567 en_EN
dc.contributor.funder Generalitat Valenciana es_ES
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