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Supramolecular Transcription of Guanosine Monophosphate into Mesostructured Silica

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Supramolecular Transcription of Guanosine Monophosphate into Mesostructured Silica

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dc.contributor.author Bueno Alejo, Carlos Javier es_ES
dc.contributor.author Villaescusa Alonso, Luis Angel es_ES
dc.contributor.author García Bennet, Alfonso E. es_ES
dc.date.accessioned 2015-02-17T11:50:24Z
dc.date.issued 2014-11-03
dc.identifier.issn 1433-7851
dc.identifier.issn 1521-3773
dc.identifier.uri http://hdl.handle.net/10251/47190
dc.description.abstract There is large interest in replicating biological supramolecular structures in inorganic materials that are capable of mimicking biological properties. The use of 5- guanosine monophosphate in the presence of Na+ and K+ ions as a supramolecular template for the synthesis of well-ordered mesostructured materials is reported here. Mesostructured particles with the confined template exhibit high structural order at both meso- and atomic scales, with a lower structural symmetry in the columnar mesophase. Although a chiral space group can not be deduced from X-ray diffraction, analysis by electron microscopy and circular dichroism confirms a chiral stacking arrangement along the c-axis. Guanosine monophosphate based mesophases thus illustrate the possibility for specific molecular imprinting of mesoporous materials by genetic material and the potential for higher definition in molecular recognition. es_ES
dc.description.sponsorship This work was supported by the Swedish Research Council (A.E.G.B.), and L.A.V. thanks the Spanish Government for financial support (project MAT2012-38429-C04) and D.E.L.I for help with the ICP/MS analysis. We are grateful to Prof. Sven Hovmoller (Stockholm University) for advice and helpful discussions regarding electron crystallography and CRISP. We are indebted to Dr. Isabel Correia (Technical University of Lisbon) for her help with circular dichroism measurements. en_EN
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Chirality es_ES
dc.subject Electron microscopy es_ES
dc.subject Hybrid material es_ES
dc.subject Mesoporous materials es_ES
dc.subject Self-assembly es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.title Supramolecular Transcription of Guanosine Monophosphate into Mesostructured Silica es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/anie.201407005
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2012-38429-C04/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Bueno Alejo, CJ.; Villaescusa Alonso, LA.; García Bennet, AE. (2014). Supramolecular Transcription of Guanosine Monophosphate into Mesostructured Silica. Angewandte Chemie International Edition. 53(45):12106-12110. https://doi.org/10.1002/anie.201407005 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/anie.201407005 es_ES
dc.description.upvformatpinicio 12106 es_ES
dc.description.upvformatpfin 12110 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 53 es_ES
dc.description.issue 45 es_ES
dc.relation.senia 276641
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Swedish Research Council es_ES
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