- -

Spin chemistry investigation of peculiarities of photoinduced electron transfer in donor-acceptor linked system

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

Spin chemistry investigation of peculiarities of photoinduced electron transfer in donor-acceptor linked system

Mostrar el registro sencillo del ítem

Ficheros en el ítem

Thumbnail
Nombre: Magin, I. M., ...
Tamaño: 265.5Kb
Formato: PDF
Descripción: Versión del Autor.
Abrir
[Cerrado]
Nombre: Miranda;N.E. ...
Tamaño: 639.6Kb
Formato: PDF
Descripción: Versión editorial
Solicitar una copia al autor
dc.contributor.author Magin, I.M. es_ES
dc.contributor.author Polyakov, N.E. es_ES
dc.contributor.author Khramtsova, E.A. es_ES
dc.contributor.author Kruppa, A.I. es_ES
dc.contributor.author Stepanov, A. es_ES
dc.contributor.author Purtov, P.A. es_ES
dc.contributor.author Leshina, T.V. es_ES
dc.contributor.author Tsentalovich, Yu.T. es_ES
dc.contributor.author Miranda Alonso, Miguel Ángel es_ES
dc.contributor.author Nuin Plá, Neus Edurne es_ES
dc.contributor.author Marín García, Mª Luisa es_ES
dc.date.accessioned 2015-02-24T11:17:43Z
dc.date.available 2015-02-24T11:17:43Z
dc.date.issued 2011-12
dc.identifier.issn 0937-9347
dc.identifier.uri http://hdl.handle.net/10251/47423
dc.description.abstract Photoinduced intramolecular electron transfer in linked systems, (R,S)- and (S,S)-naproxen-N-methylpyrrolidine dyads, has been studied by means of spin chemistry methods [magnetic field effect and chemically induced dynamic nuclear polarization (CIDNP)]. The relative yield of the triplet state of the dyads in different magnetic field has been measured, and dependences of the high-field CIDNP of the N-methylpyrrolidine fragment on solvent polarity have been investigated. However, both (S,S)- and (R,S)-enantiomers demonstrate almost identical CIDNP effects for the entire range of polarity. It has been demonstrated that the main peculiarities of photoprocesses in this linked system are connected with the participation of singlet exciplex alongside with photoinduced intramolecular electron transfer in chromophore excited state quenching. es_ES
dc.description.sponsorship This work was supported by the grants 08-03-00372 and 11-03-01104 of the Russian Foundation for Basic Research, and the grant of Priority Programs of the Russian Academy of Sciences, nr. 5.1.5. en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation.ispartof Applied Magnetic Resonance es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Radical-ion-pairs es_ES
dc.subject External magnetic-field es_ES
dc.subject Laser Flash-Photolysis es_ES
dc.subject Time-resolved cidnp es_ES
dc.subject Naphthalene-amine dyads es_ES
dc.subject Geminate recombination es_ES
dc.subject Polar-solvents es_ES
dc.subject NMR detection es_ES
dc.subject Fluorescence es_ES
dc.subject Photochemistry es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Spin chemistry investigation of peculiarities of photoinduced electron transfer in donor-acceptor linked system es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s00723-011-0288-3
dc.relation.projectID info:eu-repo/grantAgreement/RFBR//11-03-01104/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/RFBR//08-03-00372/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/RAS//nr. 5.1.5./ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Magin, I.; Polyakov, N.; Khramtsova, E.; Kruppa, A.; Stepanov, A.; Purtov, P.; Leshina, T.... (2011). Spin chemistry investigation of peculiarities of photoinduced electron transfer in donor-acceptor linked system. Applied Magnetic Resonance. 41(2-4):205-220. https://doi.org/10.1007/s00723-011-0288-3 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s00723-011-0288-3 es_ES
dc.description.upvformatpinicio 205 es_ES
dc.description.upvformatpfin 220 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 41 es_ES
dc.description.issue 2-4 es_ES
dc.relation.senia 211096
dc.identifier.eissn 1613-7507
dc.contributor.funder Russian Foundation for Basic Research es_ES
dc.contributor.funder Russian Academy of Sciences es_ES
dc.description.references J.S. Park, E. Karnas, K. Ohkubo, P. Chen, K.M. Kadish, S. Fukuzumi, C.W. Bielawski, T.W. Hudnall, V.M. Lynch, J.L. Sessler, Science 329, 1324–1327 (2010) es_ES
dc.description.references S.Y. Reece, D.G. Nocera, Annu. Rev. Biochem. 78, 673–699 (2009) es_ES
dc.description.references M.S. Afanasyeva, M.B. Taraban, P.A. Purtov, T.V. Leshina, C.B. Grissom, J. Am. Chem. Soc. 128, 8651–8658 (2006) es_ES
dc.description.references M.A. Fox, M. Chanon, in Photoinduced Electron Transfer. C: Photoinduced Electron Transfer Reactions: Organic Substrates (Elsevier, New York, 1988), p. 754 es_ES
dc.description.references P.J. Hayball, R.L. Nation, F. Bochner, Chirality 4, 484–487 (1992) es_ES
dc.description.references N. Suesa, M.F. Fernandez, M. Gutierrez, M.J. Rufat, E. Rotllan, L. Calvo, D. Mauleon, G. Carganico, Chirality 5, 589–595 (1993) es_ES
dc.description.references A.M. Evans, J. Clin. Pharmacol. 36, 7–15 (1996) es_ES
dc.description.references Y. Inoue, T. Wada, S. Asaoka, H. Sato, J.-P. Pete, Chem Commun. 4, 251–259 (2000) es_ES
dc.description.references T. Yorozu, K. Hayashi, M. Irie, J. Am. Chem. Soc. 103, 5480–5548 (1981) es_ES
dc.description.references N.J. Turro, in Modern Molecular Photochemistry (Benjamin/Cummings, San Francisco, 1978) es_ES
dc.description.references K.M. Salikhov, Y.N. Molin, R.Z. Sagdeev, A.L. Buchachenko, in Spin Polarization and Magnetic Field Effects in Radical Reactions (Akademiai Kiado, Budapest, 1984), p. 419 es_ES
dc.description.references E.A. Weiss, M.A. Ratner, M.R. Wasielewski, J. Phys. Chem. A 107, 3639–3647 (2003) es_ES
dc.description.references A.S. Lukas, P.J. Bushard, E.A. Weiss, M.R. Wasielewski, J. Am. Chem. Soc. 125, 3921–3930 (2003) es_ES
dc.description.references R. Nakagaki, K. Mutai, M. Hiramatsu, H. Tukada, S. Nakakura, Can. J. Chem. 66, 1989–1996 (1988) es_ES
dc.description.references M.C. Jim′enez, U. Pischel, M.A. Miranda, J. Photochem. Photobiol. C Photochem. Rev. 8, 128–142 (2007) es_ES
dc.description.references S. Abad, U. Pischel, M.A. Miranda, Photochem. Photobiol. Sci. 4, 69–74 (2005) es_ES
dc.description.references U. Pischel, S. Abad, L.R. Domingo, F. Bosca, M.A. Miranda, Angew. Chem. Int. Ed. 42, 2531–2534 (2003) es_ES
dc.description.references G.L. Closs, R.J. Miller, J. Am. Chem. Soc. 101, 1639–1641 (1979) es_ES
dc.description.references G.L. Closs, R.J. Miller, J. Am. Chem. Soc. 103, 3586–3588 (1981) es_ES
dc.description.references M. Goez, Chem. Phys. Lett. 188, 451–456 (1992) es_ES
dc.description.references I.F. Molokov, Y.P. Tsentalovich, A.V. Yurkovskaya, R.Z. Sagdeev, J. Photochem. Photobiol. A 110, 159–165 (1997) es_ES
dc.description.references U. Pischel, S. Abad, M.A. Miranda, Chem. Commun. 9, 1088–1089 (2003) es_ES
dc.description.references H. Hayashi, S. Nagakura, Bull. Chem. Soc. Jpn. 57, 322–328 (1984) es_ES
dc.description.references Y. Sakaguchi, H. Hayashi, S. Nagakura, Bull. Chem. Soc. Jpn. 53, 39–42 (1980) es_ES
dc.description.references H. Yonemura, H. Nakamura, T. Matsuo, Chem. Phys. Lett. 155, 157–161 (1989) es_ES
dc.description.references N. Hata, M. Hokawa, Chem. Lett. 10, 507–510 (1981) es_ES
dc.description.references M. Shiotani, L. Sjoeqvist, A. Lund, S. Lunell, L. Eriksson, M.B. Huang, J. Phys. Chem. 94, 8081–8090 (1990) es_ES
dc.description.references E. Schaffner, H. Fischer, J. Phys. Chem. 100, 1657–1665 (1996) es_ES
dc.description.references Y. Mori, Y. Sakaguchi, H. Hayashi, Chem. Phys. Lett. 286, 446–451 (1998) es_ES
dc.description.references I.M. Magin, A.I. Kruppa, P.A. Purtov, Chem. Phys. 365, 80–84 (2009) es_ES
dc.description.references K.K. Barnes, Electrochemical Reactions in Nonaqueous Systems (M. Dekker, New York, 1970), p. 560 es_ES
dc.description.references J. Bargon, J. Am. Chem. Soc. 99, 8350–8351 (1977) es_ES
dc.description.references M. Goez, I. Frisch, J. Phys. Chem. A 106, 8079–8084 (2002) es_ES
dc.description.references A.K. Chibisov, Russ. Chem. Rev. 50, 615–629 (1981) es_ES
dc.description.references J. Goodman, K. Peters, J. Am. Chem. Soc. 107, 1441–1442 (1985) es_ES
dc.description.references H. Cao, Y. Fujiwara, T. Haino, Y. Fukazawa, C.-H. Tung, Y. Tanimoto, Bull. Chem. Soc. Jpn. 69, 2801–2813 (1996) es_ES
dc.description.references P.A. Purtov, A.B. Doktorov, Chem. Phys. 178, 47–65 (1993) es_ES
dc.description.references A.I. Kruppa, O.I. Mikhailovskaya, T.V. Leshina, Chem. Phys. Lett. 147, 65–71 (1988) es_ES
dc.description.references M.E. Michel-Beyerle, R. Haberkorn, W. Bube, E. Steffens, H. Schröder, H.J. Neusser, E.W. Schlag, H. Seidlitz, Chem. Phys. 17, 139–145 (1976) es_ES
dc.description.references K. Schulten, H. Staerk, A. Weller, H.-J. Werner, B. Nickel, Z. Phys. Chem. 101, 371–390 (1976) es_ES
dc.description.references K. Gnadig, K.B. Eisenthal, Chem. Phys. Lett. 46, 339–342 (1977) es_ES
dc.description.references T. Nishimura, N. Nakashima, N. Mataga, Chem. Phys. Lett. 46, 334–338 (1977) es_ES
dc.description.references M.G. Kuzmin, I.V. Soboleva, E.V. Dolotova, D.N. Dogadkin, High Eng. Chem. 39, 86–96 (2005) es_ES


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem