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Pulse and potentiostatic electrodeposition of CuInSe2 films on gold coated alumina substrates

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Pulse and potentiostatic electrodeposition of CuInSe2 films on gold coated alumina substrates

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dc.contributor.author Valdés, M. es_ES
dc.contributor.author Mollar García, Miguel Alfonso es_ES
dc.contributor.author Vazquéz, M. es_ES
dc.contributor.author Marí Soucase, Bernabé es_ES
dc.date.accessioned 2015-02-26T10:59:55Z
dc.date.available 2015-02-26T10:59:55Z
dc.date.issued 2013-06
dc.identifier.issn 0021-891X
dc.identifier.uri http://hdl.handle.net/10251/47502
dc.description.abstract [EN] CuInSe2 thin films were deposited on goldcoated alumina electrodes using constant and pulsed potential signals. In situ electrochemical measurements were recorded with an atomic force microscope to follow CuInSe2 electrodeposition. The electrodeposited films were characterized employing scanning electron microscopy, energy dispersive spectroscopy, grazing incidence X-ray diffraction, and Raman spectroscopy. The best stoichiometry is attained for films deposited at pulsed potentials of -0.7 V. These films are also the most compact, showing a homogeneous morphology. In contrast, potentiostatic films presented minor variations in their chemical composition with the deposition potential. The morphology presented porous coral-like structures. X-ray and Raman spectroscopy analysis of as-deposited films by either technique reveal the presence of secondary phases such as CuxSe and Se, especially at the most positive deposition potentials. After a thermal treatment at 500 "C in Se vapor, the crystallinity of the material is significantly enhanced and no secondary phases are present. es_ES
dc.description.sponsorship This study was partially supported by Spanish Government through MCINN grant MAT2009-14625-C03-03 and European Commission through NanoCIS project FP7-PEOPLE-2010IRSES (ref. 269279). Financial support from Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Agencia Nacional de Promocion Cientifica y Tecnologica and Universidad Nacional de Mar del Plata (UNMdP) from Argentina are greatly acknowledged. The authors wish to thank BSc. Mariela Desimone for her assistance with GXRD measurements. en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation.ispartof Journal of Applied Electrochemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject CuInSe2 es_ES
dc.subject Semiconductor es_ES
dc.subject Thin films es_ES
dc.subject Electrodeposition es_ES
dc.subject AFM es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Pulse and potentiostatic electrodeposition of CuInSe2 films on gold coated alumina substrates es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10800-013-0549-y
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2009-14625-C03-03/ES/Diseño, Sintesis Y Caracterizacion De Materiales Fotovoltaicos Avanzados De Alta Eficiencia/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/269279/EU/Development of a new generation of CIGS-based solar cells/
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Valdés, M.; Mollar García, MA.; Vazquéz, M.; Marí Soucase, B. (2013). Pulse and potentiostatic electrodeposition of CuInSe2 films on gold coated alumina substrates. Journal of Applied Electrochemistry. 43(6):619-628. https://doi.org/10.1007/s10800-013-0549-y es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s10800-013-0549-y es_ES
dc.description.upvformatpinicio 619 es_ES
dc.description.upvformatpfin 628 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 43 es_ES
dc.description.issue 6 es_ES
dc.relation.senia 263950
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.contributor.funder Consejo Nacional de Investigaciones Científicas y Técnicas, Argentina
dc.contributor.funder Agencia Nacional de Promoción Científica y Tecnológica, Argentina
dc.contributor.funder Universidad Nacional de Mar del Plata, Argentina
dc.contributor.funder European Commission
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