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Chemical instability of Cu(3)(BTC)(2) by reaction with thiols

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Chemical instability of Cu(3)(BTC)(2) by reaction with thiols

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Dhakshinamoorthy, A.; Alvaro Rodríguez, MM.; Concepción Heydorn, P.; García Gómez, H. (2011). Chemical instability of Cu(3)(BTC)(2) by reaction with thiols. Catalysis Communications. 12(11):1018-1021. https://doi.org/10.1016/j.catcom.2011.03.018

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Title: Chemical instability of Cu(3)(BTC)(2) by reaction with thiols
Author: Dhakshinamoorthy, Amarajothi Alvaro Rodríguez, Maria Mercedes Concepción Heydorn, Patricia García Gómez, Hermenegildo
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
In contrast to Fe(BTC) (BTC: 1,3,5-benzenetricarboxylate), the crystal structure of Cu3(BTC)2, a commercial metal organic framework widely used as solid catalyst, collapses when contacted with thiols under mild reaction ...[+]
Subjects: Cu3(BTC)2 , Copper , Metal organic frameworks , Thiols , Metal nanoparticles
Copyrigths: Reserva de todos los derechos
Source:
Catalysis Communications. (issn: 1566-7367 )
DOI: 10.1016/j.catcom.2011.03.018
Publisher:
Elsevier
Publisher version: http://dx.doi.org/10.1016/j.catcom.2011.03.018
Project ID:
info:eu-repo/grantAgreement/MICINN//CTQ2010-18671/ES/APLICACION DE SOLIDOS RETICULARES METAL-ORGANICO MODIFICADOS COMO CATALIZADORES HETEROGENEOS EN PROCESOS DE OXIDACION AEROBICA Y EN REACCIONES PROMOVIDAS POR ACIDOS DE LEWIS/
Thanks:
Financial support by the Spanish DGI (CTQ2009-11587 and CTQ2010-18671) is gratefully acknowledged. Maykel de Miguel is thanked for helping to record TEM images.
Type: Artículo

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