Mostrar el registro sencillo del ítem
dc.contributor.author | Fenollar Gimeno, Octavio Ángel | es_ES |
dc.contributor.author | García Sanoguera, David | es_ES |
dc.contributor.author | Sánchez Nacher, Lourdes | es_ES |
dc.contributor.author | López Martínez, Juan | es_ES |
dc.contributor.author | Balart Gimeno, Rafael Antonio | es_ES |
dc.date.accessioned | 2015-03-24T18:18:01Z | |
dc.date.available | 2015-03-24T18:18:01Z | |
dc.date.issued | 2012-05-05 | |
dc.identifier.issn | 0021-8995 | |
dc.identifier.uri | http://hdl.handle.net/10251/48247 | |
dc.description.abstract | In this work, we have evaluated the curing process of a natural-based plasticizer, epoxidized linseed oil, as a possible alternative to phthalate substitution for polyvinyl chloride. Several curing times ranging from 6 to 14 min at different isothermal curing temperatures in the 140-220°C range have been selected. The effects of the curing process (in terms of time and temperature) have been determined by mechanical tests, color measurements, and microstructure characterization. The obtained results show that optimum overall properties are obtained for curing times of 10-12 min at 200°C or 8 min at 220°C, which are typical values of industrial processing of vinyl plastisols. © 2011 Wiley Periodicals, Inc. | es_ES |
dc.description.sponsorship | Contract grant sponsor: Ministerio de Ciencia y Tecnologia; contract grant number: DPI2007-66849-C02-02 | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Wiley-Blackwell | es_ES |
dc.relation.ispartof | Journal of Applied Polymer Science | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Additives | es_ES |
dc.subject | Curing of polymers | es_ES |
dc.subject | Degradation | es_ES |
dc.subject | Mechanical properties | es_ES |
dc.subject | Poly(vinyl chloride) | es_ES |
dc.subject | Color measurements | es_ES |
dc.subject | Curing process | es_ES |
dc.subject | Curing temperature | es_ES |
dc.subject | Epoxidized linseed oil | es_ES |
dc.subject | Industrial processing | es_ES |
dc.subject | Mechanical tests | es_ES |
dc.subject | Microstructure characterization | es_ES |
dc.subject | Overall properties | es_ES |
dc.subject | Phthalates | es_ES |
dc.subject | Typical values | es_ES |
dc.subject | Chlorine compounds | es_ES |
dc.subject | Diamond cutting tools | es_ES |
dc.subject | Drying oils | es_ES |
dc.subject | Elastomers | es_ES |
dc.subject | Plasticizers | es_ES |
dc.subject | Plastisols | es_ES |
dc.subject | Polyvinyl chlorides | es_ES |
dc.subject | Reinforced plastics | es_ES |
dc.subject | Curing | es_ES |
dc.subject.classification | CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA | es_ES |
dc.title | Characterization of the curing process of vinyl plastisols with epoxidized linseed oil as a natural-based plasticizer | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/app.34645 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MEC//DPI2007-66849-C02-02/ES/INVESTIGACION DE LOS MECANISMOS DE ACTUACION DE TRATAMIENTOS SUPERFICIALES, PARA LA CUANTIFICACION DE LA HIDROFILIDAD Y DURABILIDAD, APLICADOS SOBRE MATERIALES TEXTILES/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials | es_ES |
dc.description.bibliographicCitation | Fenollar Gimeno, OÁ.; García Sanoguera, D.; Sánchez Nacher, L.; López Martínez, J.; Balart Gimeno, RA. (2012). Characterization of the curing process of vinyl plastisols with epoxidized linseed oil as a natural-based plasticizer. Journal of Applied Polymer Science. 124(3):2550-2557. https://doi.org/10.1002/app.34645 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1002/app.34645 | es_ES |
dc.description.upvformatpinicio | 2550 | es_ES |
dc.description.upvformatpfin | 2557 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 124 | es_ES |
dc.description.issue | 3 | es_ES |
dc.relation.senia | 212501 | |
dc.identifier.eissn | 1097-4628 | |
dc.contributor.funder | Ministerio de Educación y Ciencia | es_ES |
dc.description.references | Braun, D. (2001). PVC ? origin, growth, and future. Journal of Vinyl and Additive Technology, 7(4), 168-176. doi:10.1002/vnl.10288 | es_ES |
dc.description.references | Jimenez, A., Lopez, J., Iannoni, A., & Kenny, J. M. (2001). Formulation and mechanical characterization of PVC plastisols based on low-toxicity additives. Journal of Applied Polymer Science, 81(8), 1881-1890. doi:10.1002/app.1621 | es_ES |
dc.description.references | Marcilla, A., Garcia, S., & Garcia-Quesada, J. C. (2008). Migrability of PVC plasticizers. Polymer Testing, 27(2), 221-233. doi:10.1016/j.polymertesting.2007.10.007 | es_ES |
dc.description.references | Wang, Q., & Storm, B. K. (2005). Separation and analysis of low molecular weight plasticizers in poly(vinyl chloride) tubes. Polymer Testing, 24(3), 290-300. doi:10.1016/j.polymertesting.2004.12.002 | es_ES |
dc.description.references | Pedersen, G. A., Jensen, L. K., Fankhauser, A., Biedermann, S., Petersen, J. H., & Fabech, B. (2008). Migration of epoxidized soybean oil (ESBO) and phthalates from twist closures into food and enforcement of the overall migration limit. Food Additives & Contaminants: Part A, 25(4), 503-510. doi:10.1080/02652030701519088 | es_ES |
dc.description.references | Kim, S.-W., Kim, J.-G., Choi, J.-I., Jeon, I.-R., & Seo, K.-H. (2005). Synthesis of glycidylethylhexylphthalate and its effects on poly(vinyl chloride) films as a novel plasticizer. Journal of Applied Polymer Science, 96(4), 1347-1356. doi:10.1002/app.21553 | es_ES |
dc.description.references | Guoquan, W., & Yiaoting, C. (1991). Test methods for gelation of PVC plastisol. Polymer Testing, 10(4), 315-324. doi:10.1016/0142-9418(91)90025-s | es_ES |
dc.description.references | Crespo, J. E., Balart, R., Sanchez, L., & López, J. (2007). Substitution of di(2-ethylhexyl) phthalate by di(isononyl) cyclohexane-1,2-dicarboxylate as a plasticizer for industrial vinyl plastisol formulations. Journal of Applied Polymer Science, 104(2), 1215-1220. doi:10.1002/app.25760 | es_ES |
dc.description.references | Shea, K. M. (2003). Pediatric Exposure and Potential Toxicity of Phthalate Plasticizers. PEDIATRICS, 111(6), 1467-1474. doi:10.1542/peds.111.6.1467 | es_ES |
dc.description.references | Audic, J.-L., Reyx, D., & Brosse, J.-C. (2003). Migration of additives from food grade polyvinyl chloride (PVC) films: Effect of plasticization by polymeric modifiers instead of conventional plasticizers. Journal of Applied Polymer Science, 89(5), 1291-1299. doi:10.1002/app.12240 | es_ES |
dc.description.references | Fankhauser-Noti, A., & Grob, K. (2006). Migration of plasticizers from PVC gaskets of lids for glass jars into oily foods: Amount of gasket material in food contact, proportion of plasticizer migrating into food and compliance testing by simulation. Trends in Food Science & Technology, 17(3), 105-112. doi:10.1016/j.tifs.2005.10.013 | es_ES |
dc.description.references | Hakkarainen, M. (s. f.). Migration of Monomeric and Polymeric PVC Plasticizers. Advances in Polymer Science, 159-185. doi:10.1007/12_2008_140 | es_ES |
dc.description.references | Benaniba, M. ., Belhaneche-Bensemra, N., & Gelbard, G. (2001). Stabilizing effect of epoxidized sunflower oil on the thermal degradation of poly(vinyl chloride). Polymer Degradation and Stability, 74(3), 501-505. doi:10.1016/s0141-3910(01)00170-7 | es_ES |
dc.description.references | KANNO, S., KAWAMURA, Y., MUTSUGA, M., & TANAMOTO, K. (2006). Determination of Epoxidized Soybean Oil and Linseed Oil in Wrapping Film and Cap Sealing. Journal of the Food Hygienic Society of Japan (Shokuhin Eiseigaku Zasshi), 47(3), 89-94. doi:10.3358/shokueishi.47.89 | es_ES |
dc.description.references | KAWAMURA, Y., KANNO, S., MUTSUGA, M., & TANAMOTO, K. (2006). Determination of Epoxidized Soybean Oil in Bottled Foods. Journal of the Food Hygienic Society of Japan (Shokuhin Eiseigaku Zasshi), 47(6), 243-248. doi:10.3358/shokueishi.47.243 | es_ES |
dc.description.references | Starnes, W. H., Du, B., Kim, S., Zaikov, V. G., Ge, X., & Culyba, E. K. (2006). Thermal stabilization and plasticization of poly(vinyl chloride) by ester thiols: Update and current status. Thermochimica Acta, 442(1-2), 78-80. doi:10.1016/j.tca.2006.01.018 | es_ES |
dc.description.references | Taghizadeh, M. T., Nalbandi, N., & Bahadori, A. (2008). Stabilizing effect of epoxidized sunflower oil as a secondary stabilizer for Ca/Hg stabilized PVC. Express Polymer Letters, 2(1), 65-76. doi:10.3144/expresspolymlett.2008.9 | es_ES |
dc.description.references | Fenollar, O., Garcia-Sanoguera, D., Sanchez-Nacher, L., Lopez, J., & Balart, R. (2010). Effect of the epoxidized linseed oil concentration as natural plasticizer in vinyl plastisols. Journal of Materials Science, 45(16), 4406-4413. doi:10.1007/s10853-010-4520-6 | es_ES |
dc.description.references | Boudhani, H., Lainé, C., Fulchiron, R., & Cassagnau, P. (2007). Rheology and gelation kinetics of PVC plastisols. Rheologica Acta, 46(6), 825-838. doi:10.1007/s00397-006-0157-4 | es_ES |
dc.description.references | Fenollar, O., García, D., Sánchez, L., López, J., & Balart, R. (2009). Optimization of the curing conditions of PVC plastisols based on the use of an epoxidized fatty acid ester plasticizer. European Polymer Journal, 45(9), 2674-2684. doi:10.1016/j.eurpolymj.2009.05.029 | es_ES |
dc.description.references | Garcia, J. C., & Marcilla, A. (1998). Rheological study of the influence of the plasticizer concentration in the gelation and fusion processes of PVC plastisols. Polymer, 39(15), 3507-3514. doi:10.1016/s0032-3861(97)10033-7 | es_ES |
dc.description.references | Marcilla, A., & Garcı́a, J. . (1998). Qualitative model for viscoelastic measurement during gelation and fusion of PVC plastisols. European Polymer Journal, 34(9), 1341-1348. doi:10.1016/s0014-3057(97)00256-5 | es_ES |
dc.description.references | Kwak, S.-Y. (1995). In situ, quantitative characterization of gelation and fusion mechanism in poly(vinyl chloride) plastisols by small angle light scattering (SALS). Polymer Engineering and Science, 35(13), 1106-1112. doi:10.1002/pen.760351306 | es_ES |
dc.description.references | Fenollar, O., Sanchez-Nacher, L., Garcia-Sanoguera, D., López, J., & Balart, R. (2009). The effect of the curing time and temperature on final properties of flexible PVC with an epoxidized fatty acid ester as natural-based plasticizer. Journal of Materials Science, 44(14), 3702-3711. doi:10.1007/s10853-009-3495-7 | es_ES |
dc.description.references | Sharma, V., & Kundu, P. P. (2006). Addition polymers from natural oils—A review. Progress in Polymer Science, 31(11), 983-1008. doi:10.1016/j.progpolymsci.2006.09.003 | es_ES |
dc.description.references | Sharma, V., & Kundu, P. P. (2008). Condensation polymers from natural oils. Progress in Polymer Science, 33(12), 1199-1215. doi:10.1016/j.progpolymsci.2008.07.004 | es_ES |