Mostrar el registro sencillo del ítem
dc.contributor.author | Fernández Domene, Ramón Manuel | es_ES |
dc.contributor.author | Blasco Tamarit, María Encarnación | es_ES |
dc.contributor.author | García García, Dionisio Miguel | es_ES |
dc.contributor.author | García Antón, José | es_ES |
dc.date.accessioned | 2015-05-04T11:26:16Z | |
dc.date.available | 2015-05-04T11:26:16Z | |
dc.date.issued | 2013-04-15 | |
dc.identifier.issn | 0013-4686 | |
dc.identifier.uri | http://hdl.handle.net/10251/49609 | |
dc.description.abstract | The passive and transpassive behaviour of Alloy 31, a highly alloyed austenitic stainless steel (UNS N08031), has been investigated in a LiBr heavy brine solution (400 g/l) at 25 °C using potentiostatic polarisation combined with electrochemical impedance spectroscopy and Mott–Schottky analysis. The passive film formed on Alloy 31 has been found to be p-type and/or n-type in electronic character, depending on the film formation potential. The thickness of the film formed at potentials within the passive region increases linearly with applied potential. The film formed at transpassive potentials is thinner and more conductive than the film formed within the passive region. These observations are consistent with the predictions of the Point Defect Model for passive and transpassive films on metals and alloys | es_ES |
dc.description.sponsorship | We wish express our gratitude to the Ministerio de Ciencia e Innovacion (project CTQ2009-07518), for the economical support of this research, to Thyssen Krupp for supplying the materials, and to Dr. M. Asuncion Jaime for her translation assistance. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | Electrochimica Acta | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Stainless steel | es_ES |
dc.subject | Passive film | es_ES |
dc.subject | Transpassivity | es_ES |
dc.subject | EIS | es_ES |
dc.subject | Mott–Schottky | es_ES |
dc.subject.classification | INGENIERIA QUIMICA | es_ES |
dc.title | Passive and transpassive behaviour of Alloy 31 in a heavy brine LiBr solution | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.electacta.2013.02.024 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CTQ2009-07518/ES/ESTUDIO DE LA CORROSION TERMOGALVANICA EN LAS MAQUINAS DE ABSORCION DE LIBR DE DOBLE EFECTO MEDIANTE TECNICAS ELECTROQUIMICAS Y DE IMAGEN/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto de Seguridad Industrial, Radiofísica y Medioambiental - Institut de Seguretat Industrial, Radiofísica i Mediambiental | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear | es_ES |
dc.description.bibliographicCitation | Fernández Domene, RM.; Blasco Tamarit, ME.; García García, DM.; García Antón, J. (2013). Passive and transpassive behaviour of Alloy 31 in a heavy brine LiBr solution. Electrochimica Acta. 95:1-11. https://doi.org/10.1016/j.electacta.2013.02.024 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.electacta.2013.02.024 | es_ES |
dc.description.upvformatpinicio | 1 | es_ES |
dc.description.upvformatpfin | 11 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 95 | es_ES |
dc.relation.senia | 252321 | |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |