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Some ozone advanced oxidation processes to improve the biological removal of selected pharmaceutical contaminants from urban wastewater

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Some ozone advanced oxidation processes to improve the biological removal of selected pharmaceutical contaminants from urban wastewater

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dc.contributor.author Espejo, Azahara es_ES
dc.contributor.author Aguinaco, Almudena es_ES
dc.contributor.author Amat Payá, Ana María es_ES
dc.contributor.author Beltrán, Fernando J. es_ES
dc.date.accessioned 2015-05-08T09:25:37Z
dc.date.available 2015-05-08T09:25:37Z
dc.date.issued 2014-03-21
dc.identifier.issn 1093-4529
dc.identifier.uri http://hdl.handle.net/10251/49923
dc.description.abstract Removal of nine pharmaceutical compounds¿acetaminophen (AAF), antipyrine (ANT), caffeine (CAF), carbamazepine (CRB), diclofenac (DCF), hydrochlorothiazide (HCT), ketorolac (KET), metoprolol (MET) and sulfamethoxazole (SMX)¿spiked in a primary sedimentation effluent of a municipal wastewater has been studied with sequential aerobic biological and ozone advanced oxidation systems. Combinations of ozone, UVA black light and Fe(III) or Fe3O4 constituted the chemical systems. During the biological treatment (hydraulic residence time, HRT = 24 h), only AAF and CAF were completely eliminated,MET, SMX and HCT reached partial removal rates and the rest of compounds were completely refractory. With any ozone advanced oxidation process applied, the remaining pharmaceuticals disappear in less than 10 min. Fe3O4 or Fe(III) photocatalytic ozonation leads to 35% mineralization compared to 13% reached during ozonation alone after about 30-min reaction. Also, biodegradability of the treated wastewater increased 50% in the biological process plus another 150% after the ozonation processes. Both untreated and treated wastewater was non-toxic for Daphnia magna (D. magna) except when Fe(III) was used in photocatalytic ozonation. In this case, toxicity was likely due to the ferryoxalate formed in the process. Kinetic information on ozone processes reveals that pharmaceuticals at concentrations they have in urban wastewater are mainly removed through free radical oxidation. es_ES
dc.description.sponsorship The authors thank the Spanish CICYT and Feder funds for the economic support through project CTQ2009/13459/C05/05. Also, Chemical Engineer A. Espejo thanks Gobierno de Extremadura for providing her a FPI grant. en_EN
dc.language Inglés es_ES
dc.publisher Taylor & Francis: STM, Behavioural Science and Public Health Titles es_ES
dc.relation.ispartof Journal of Environmental Science and Health Part A-Toxic/Hazardous Substances&Environmental Engineering es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Aerobic processes es_ES
dc.subject Biodegradation es_ES
dc.subject Emerging contaminants es_ES
dc.subject Environmental preservation es_ES
dc.subject Ozone advanced oxidation processes es_ES
dc.subject Waste water treatment es_ES
dc.subject.classification QUIMICA FISICA es_ES
dc.title Some ozone advanced oxidation processes to improve the biological removal of selected pharmaceutical contaminants from urban wastewater es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1080/10934529.2014.854652
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2009-13459-C05-05/ES/Integración de procesos de fotocatálisis solar en la depuración biológica de aguas residuales para la eliminación de contaminantes emergentes/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera es_ES
dc.description.bibliographicCitation Espejo, A.; Aguinaco, A.; Amat Payá, AM.; Beltrán, FJ. (2014). Some ozone advanced oxidation processes to improve the biological removal of selected pharmaceutical contaminants from urban wastewater. Journal of Environmental Science and Health Part A-Toxic/Hazardous Substances&Environmental Engineering. 49(4):410-421. https://doi.org/10.1080/10934529.2014.854652 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1080/10934529.2014.854652 es_ES
dc.description.upvformatpinicio 410 es_ES
dc.description.upvformatpfin 421 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 49 es_ES
dc.description.issue 4 es_ES
dc.relation.senia 265938
dc.identifier.eissn 1532-4117
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Junta de Extremadura es_ES
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