- -

A conducting nanocomposite via intercalative polymerisation of 2-metylaniline with aniline in montmorillonite cation-exchanged

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

A conducting nanocomposite via intercalative polymerisation of 2-metylaniline with aniline in montmorillonite cation-exchanged

Mostrar el registro sencillo del ítem

Ficheros en el ítem

[Cerrado]
Nombre: F. Chouli;ABDELGHANI ...
Tamaño: 378.9Kb
Formato: PDF
Descripción: Versión editorial
Solicitar una copia al autor
dc.contributor.author Chouli, Faiza es_ES
dc.contributor.author Benyoucef, Abdelghani es_ES
dc.contributor.author Yahiaoui, A. es_ES
dc.contributor.author Quijada Tomás, Cesar es_ES
dc.contributor.author Morallón, E. es_ES
dc.date.accessioned 2015-05-15T11:53:35Z
dc.date.available 2015-05-15T11:53:35Z
dc.date.issued 2012-11
dc.identifier.issn 1022-9760
dc.identifier.uri http://hdl.handle.net/10251/50295
dc.description.abstract Polymer/montmorillonite nanocomposites were prepared. Intercalation of 2-methylaniline with aniline monomers into montmorillonite modified by cation was followed by subsequent oxidative polymerization of the monomers in the interlayer spacing. The clay was prepared by cation exchange process between sodium cation in (M-Na) and copper cation (M-Cu). We prepared a series of polymer/clay nanocomposite materials that consisted of an emeraldine base of poly(2-MA), poly(2-MA-co-ANI) and PANI by layered copper montmorillonite. All organic monomers used were first intercalated into the interlayer regions of clay hosts followed by a one-step in situ oxidative polymerization. The unique properties of the as-synthesized nanocomposites materials are investigated by electronic conductivity measurements, X-ray diffraction, FTIR spectroscopy, UV-vis spectroscopy, thermogravimetric analysis and SEM, were also studied by cyclic voltammetry which indicates the electroactive effect of nanocomposite gradually increased with aniline in the polymer chain. es_ES
dc.description.sponsorship This work was supported by the National Agency for the Development of University Research (ANDRU), the Directorate General of Scientific Research and Technological Development (DGRSDT) of Algeria "The location of the manufacturer of samples is University of Mascara-Algeria" and the Departamento de Quimica Fisica e Instituto Universitario de Materiales, Universidad de Alicante (Spain) "Samples characterization are in University of Alicante-Spain". en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation.ispartof Journal of Polymer Research es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Nanocomposite es_ES
dc.subject Cation exchanged es_ES
dc.subject Conducting polymers es_ES
dc.subject Montmorillonite es_ES
dc.subject.classification QUIMICA FISICA es_ES
dc.title A conducting nanocomposite via intercalative polymerisation of 2-metylaniline with aniline in montmorillonite cation-exchanged es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10965-012-0003-6
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera es_ES
dc.description.bibliographicCitation Chouli, F.; Benyoucef, A.; Yahiaoui, A.; Quijada Tomás, C.; Morallón, E. (2012). A conducting nanocomposite via intercalative polymerisation of 2-metylaniline with aniline in montmorillonite cation-exchanged. Journal of Polymer Research. 19(3):1-10. doi:10.1007/s10965-012-0003-6 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s10965-012-0003-6 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 10 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 19 es_ES
dc.description.issue 3 es_ES
dc.relation.senia 231024
dc.contributor.funder Agence Nationale pour le Développement de la Recherche Universitaire, Argelia
dc.contributor.funder Direction Générale de la Recherche Scientifique et du Développement Technologique, Argelia
dc.contributor.funder Universitat d'Alacant
dc.description.references Wang Z, Yang X, Wei J, Xu M, Tong L, Zhao R, Liu X (2011) Morphological, electrical, thermal and mechanical properties of phthalocyanine/multi-wall carbon nanotubes nanocomposites prepared by masterbatch dilution. J Polym Res 19:9969 es_ES
dc.description.references Wang Z, Pinnavaia TJ (1998) Hybrid organic-inorganic nanocomposites: exfoliation of magadiite nanolayers in an elastomeric epoxy polymer. Chem Mater 10:3769–3771 es_ES
dc.description.references Biswas M, Ray SS (2001) Recent progress in synthesis and evaluation of polymer- montmorillonite nanocomposites. Adv Polym Sci 155:167–221 es_ES
dc.description.references Lan T, Kaviratna PD, Pinnavaia T (1994) On the nature of polyimide-clay hybrid composites. J Chem Mater 6:573–575 es_ES
dc.description.references Gilman JW, Jackson CL, Morgan AB, Hayyis RJ, Manias E, Giannelis EP, Wuthenow M, Hilton D, Phillips SH (2000) Flammability properties of polymer-layered-silicate nanocomposites. Polypropylene and polystyrene nanocomposites. Chem Mater 12:1866 es_ES
dc.description.references Yeh JM, Liou SJ, Lai CY, Wu PC, Tsai TY (2001) Enhancement of corrosion protection effect in polyaniline via the formation of polyaniline-clay nanocomposite materials. Chem Mater 13:1131–1136 es_ES
dc.description.references Yeh JM, Liou SJ, Lin CY, Cheng CY, Cheng YW, Lee KR (2002) Anticorrosively enhanced PMMA-clay nanocomposite materials with qualemary alkylphosphonium salt as an intercalating agent. Chem Mater 14:154–161 es_ES
dc.description.references Yeh JM, Chen CL, Chen YC, Ma CY, Lee KR, Wei Y, Li S (2002) Enhancement of corrosion protection effect of poly (o-ethoxyaniline) via the formation of poly (o-elhoxyani-line)-clay nanocomposite materials. Polymer 43:2729–2736 es_ES
dc.description.references Focke WW, Wnek GE, Wei Y (1987) Influence of oxidation state, pH and counterion on the conductivity of polyaniline. J Phys Chem 91:5813 es_ES
dc.description.references Kingsborough RP, Swager TM (1998) Electroactivity enhancement by redox matching in cobalt salen-based conducting polymers. Adv Mater 14:1100–1004 es_ES
dc.description.references Riede A, Helmstedt J, Riede V, Zemek J, Stejskal J (2000) In situ polymerized polyaniline films. 2. Dispersion polymerization of aniline in the presence of colloidal silica. Langmuir 16:6240–6244 es_ES
dc.description.references Goller MI, Barthet C, McCarthy GP, Corradi R, Newby BP, Wilson SA, Armes SP, Luk SY (1998) Synthesis and characterization of surface-aminated polypyrrole-silica nanocomposites. Colloid Polym Sci 276:1010–1018 es_ES
dc.description.references Bekri I, Srasra AE (2011) Solid state polymerization and intercalation of aniline in Fe rich montmorillonite. J Polym Res 18:691–699 es_ES
dc.description.references Kong J, Franklin NR, Zhou C, Chapline MG, Peng S, Cho K, Dai H (2000) Nanotubes molecular wires as chemical sensors. Science 287:622–625 es_ES
dc.description.references Chen KH, Yang SM (2003) Polyaniline-montmorillonite composite synthesized. By electrochemical method. Synth Met 151:135–136 es_ES
dc.description.references Wu Q, Xue Z, Qi Z, Wang F (2000) Synthesis and characterization of PAn/clay nanocomposite with extended chain conformation of polyaniline. Polymer 41:2029–2032 es_ES
dc.description.references Çelik M, Önal M (2007) Intercalated polyaniline/Na-montmorillonite nanocomposites via oxidative polymerization. J Polym Res 14:313–317 es_ES
dc.description.references Orata D, Segor F (2000) Electrodeposition of polyaniline on acidified clay montmorillonite modified electrode. J React Funct Polymer 43:305–314 es_ES
dc.description.references Lim YT, Park JH, Park OOJ (2002) Improved electrorheological effect in polyaniline nanocomposite suspensions. Colloid Interface Sci J 245:198–203 es_ES
dc.description.references Kim BH, Jung JH, Kim JW, Choi HJ, Joo J (2001) Physical characterization of polyaniline-Na + -montmorillonite nanocomposite intercalated by emulsion polymerization. Synth Met 117:115–118 es_ES
dc.description.references Binitha NN, Sugunan S (2008) Polyaniline/pillared montmorillonite clay composite nanofibers. J Appl Polym Sci 107:3367–3372 es_ES
dc.description.references DoNascimento GM, Constantino VRL, Landers R, Temperini MLA (2004) Aniline polymerization into montmorillonite clay: a spectroscopic investigation of the intercalated conducting polymer. Macromolecules 37:9373–9385 es_ES
dc.description.references DoNascimento GM, Constantino VRL, Temperini MLA (2002) Spectroscopic characterization of a new type of conducting polymer-clay nanocomposite. Macromolecules 35:7535–7537 es_ES
dc.description.references Bae WJ, Kim KH, Jo WH (2004) Exfoliated nanocomposite from polyaniline graft copolymer/clay. Macromolecules 37:9850–9854 es_ES
dc.description.references Lee D, Char K, Lee SW, Park YW (2003) Structural changes of polyaniline / montmorillonite nanocomposites and their effects on physical properties. J Mater Chem 13:2942–2947 es_ES
dc.description.references Lu J, Zhao X (2002) Electrorheological behaviors of polyaniline-montmorillonite clay nanocomposite. Int J Mod Phys B 16:2521–2527 es_ES
dc.description.references Salahuddin N, Ayad MM, Ali M (2008) Synthesis and characterization of polyaniline-organoclay nanocomposites. J Appl Polymer Sci 107:1981–1989 es_ES
dc.description.references Samrana K, Shahzada A, Jiri P, Josef P, Yogesh MJ (2012) Polyaniline/sodium montmorillonite clay nanocomposites: effect of clay concentration on thermal, structural, and electrical properties. J Mater Sci 47:420–428 es_ES
dc.description.references Carrado KA, Xu L (1998) In situ synthesis of polymer-clay nanocomposites from silicate gels. Chem Mater 10:1440–1445 es_ES
dc.description.references Kim BH, Jung JH, Kim JW, Choi HJ, Joo J (2001) Physical characterization of polyaniline/Na+-montmorillonite nanocompósito intercalated by emulsion polymerization. Synth Met 1:115–118 es_ES
dc.description.references Boutaleb N, Benyoucef A, Salavagione HJ, Belbachir M, Morallón E (2006) Electrochemical behaviour of conducting polymers obtained into clay-catalyst layers. An in situ Raman spectroscopy study. Eur Polymer J 42:733–739 es_ES
dc.description.references Salavagione HJ, Amorós DC, Tidjane S, Belbachir M, Benyoucef A, Morallón E (2008) Effect of the intercalated cation on the properties of poly(o-methylaniline)/maghnite clay nanocomposites. Eur Polymer J 44:1275–1284 es_ES
dc.description.references Lee D, Lee SH, Char K, Kim J (2000) Expansion distribution of basal spacing of the silicate layers in polyaniline/Na+-montmorillonite nanocomposites monitored with X-ray diffraction. Macromol Rapid Comm 21:1136–1139 es_ES
dc.description.references Cole KC (2008) Use of infrared spectroscopy to characterize clay intercalation and exfoliation in. Polymer nanocomposites. Macromolecules 41:834–843 es_ES
dc.description.references Niu Z, Yang Z, Hu Z, Lu Y, Han CC (2003) Polyaniline/silica composite capsules and hollow spheres. Adv Funct Mater 13:949 es_ES
dc.description.references Han MG, Im SS (2000) X-ray photoelectron spectroscopy study of electrically conducting polyaniline/polyimide blends. Polymer 41:3253–3262 es_ES
dc.description.references Rajagopalan R, Iroh JO (2003) Characterization of polyaniline-polypyrrole composite coatings on low carbon steel: a XPS and infrared spectroscopy study. Appl Surf Sci 218:58–69 es_ES
dc.description.references Benoit R, Durand Y, Narjoux B, Quintana G (2011) X-ray photoelectron spectroscopy database, La Surface, CNRS and Thermo Fisher Scientific, Thermo Electron France, available from: http://www.lasurface.com/database/elementxps.php (last accessed 11.30.11) es_ES
dc.description.references Monkman AP, Stevens GC, Bloor D (1991) X-ray photoelectron spectroscopic investigations of the chain structure and doping mechanisms in polyaniline. J Phys D Appl Phys 24:738–749 es_ES
dc.description.references Lapkowski M, Berrada K, Quillard S, Louran G, Lefrant S, Pron A (1995) Electrochemical oxidation of polyaniline in nonaqueous electrolytes: “in situ” Raman spectroscopic studies. Macromolecules 28:1233–1238 es_ES
dc.description.references Huang W, Humphrey BD, MacDiarmid AG (1986) Polyaniline, a novel conducting polymer. Morphology and chemistry of its oxidation and reduction in aqueous electrolytes. J Chem Soc Faraday Trans 1:2385–2400 es_ES
dc.description.references Shreepathi S, Holze R (2005) Spectroelectrochemical investigations of soluble polyaniline synthesized via New inverse emulsion pathway. Chem Mater 17:4078–4085 es_ES
dc.description.references Yang G, Hou W, Feng X, Xu L, Liu Y, Wang G, Ding W (2007) Nanocomposites of polyaniline and a layered inorganic acid host: polymerization of aniline in the layers, conformation, and electrochemical studies. Adv Funct Mater 17:401–412 es_ES
dc.description.references Narayanan BN, Koodathil R, Gangadharan T, Yaakob Z, Saidu FK, Chandralayam S (2010) Preparation and characterization of exfoliated polyaniline/montmorillonite nanocomposites. Mater Sci Eng B 168:242–244 es_ES
dc.description.references Marjanovic GC, Dondur V, Milojevic M, Mojovic M, Mentus S, Radulovic A, Vukovic Z, Stejskal J (2009) Synthesis and characterization of conducting self-assembled polyaniline nanotubes/zeolite nanocomposite. Langmuir 25:3122–3131 es_ES


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem