Toumi, I.; Benyoucef, A.; Yahiaoui, A.; Quijada Tomás, C.; Morallón, E. (2013). Effect of the intercalated cation-exchanged on the properties of nanocomposites prepared by 2-aminobenzene sulfonic acid with aniline and montmorillonite. Journal of Alloys and Compounds. 551:212-218. doi:10.1016/j.jallcom.2012.10.057
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/50373
Title:
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Effect of the intercalated cation-exchanged on the properties of nanocomposites prepared by 2-aminobenzene sulfonic acid with aniline and montmorillonite
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Author:
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Toumi, I.
Benyoucef, A.
Yahiaoui, A.
Quijada Tomás, Cesar
Morallón, E.
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UPV Unit:
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Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera
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Issued date:
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Abstract:
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[EN] Polymer/montmorillonite nanocomposites were prepared. Intercalation of 2-aminobenzene sulfonic acid with aniline monomers into montmorillonite modified by cation was followed by subsequent oxidative polymerization of ...[+]
[EN] Polymer/montmorillonite nanocomposites were prepared. Intercalation of 2-aminobenzene sulfonic acid with aniline monomers into montmorillonite modified by cation was followed by subsequent oxidative polymerization of monomers in the interlayer spacing. The clay was prepared by cation exchange process between sodium cation in (M-Na) and copper cation (M-Cu). XRD analyses show the manifestation of a basal spacing (d-spacing) for M-Cu changes depending on the inorganic cation and the polymer intercalated in the M-Cu structure. TGA analyses reveal that polymer/M-Cu composites is less stable than M-Cu. The conductivity of the composites is found to be 10(3) times higher than that for M-Cu. The microscopic examinations including TEM picture of the nanocomposite demonstrated an entirely different and more compatible morphology. Remarkable differences in the properties of the polymers have also been observed by UV-Vis and FTIR, suggesting that the polymer produced with presence of aniline has a higher degree of branching. The electrochemical behavior of the polymers extracted from the nanocomposites has been studied by cyclic voltammetry which indicates the electroactive effect of nanocomposite gradually increased with aniline in the polymer chain. (C) 2012 Elsevier B. V. All rights reserved.
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Subjects:
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Nanocomposite
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Conducting polymers
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Cation exchanged
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Montmorillonite
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Copyrigths:
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Cerrado |
Source:
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Journal of Alloys and Compounds. (issn:
0925-8388
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DOI:
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10.1016/j.jallcom.2012.10.057
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Publisher:
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Elsevier
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Publisher version:
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http://dx.doi.org/10.1016/j.jallcom.2012.10.057
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Thanks:
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This work was supported by the National Agency for the Development of University Research (ANDRU), the Directorate General of Scientific Research and Technological Development (DGRSDT) of Algeria and the Departamento de ...[+]
This work was supported by the National Agency for the Development of University Research (ANDRU), the Directorate General of Scientific Research and Technological Development (DGRSDT) of Algeria and the Departamento de Quimica Fisica e Instituto Universitario de Materiales, Universidad de Alicante (Spain).
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Type:
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Artículo
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