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Determination of N-methylcarbamate pesticides using flow injection with photoinduced chemiluminescence detection

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Determination of N-methylcarbamate pesticides using flow injection with photoinduced chemiluminescence detection

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dc.contributor.author López Paz, José Luis es_ES
dc.contributor.author Catalá Icardo, Mónica es_ES
dc.contributor.author Langa Sánchez, Adrián es_ES
dc.date.accessioned 2015-06-04T11:52:20Z
dc.date.available 2015-06-04T11:52:20Z
dc.date.issued 2014-02-13
dc.identifier.issn 0306-7319
dc.identifier.uri http://hdl.handle.net/10251/51251
dc.description.abstract A sensitive, economic, rapid and simple method for the determination of four N-methylcarbamate pesticides: methomyl (2.0–80 μg L−1), aldicarb (5.0–50 μg L−1), butocarboxim (2.0–60 μg L−1) and oxamyl (2.0–60 μg L−1); is reported. It relies on the coupling of photoinduced chemiluminescence (PICL) detection with flow injection (FI) methodology. The automation of FI together with the use of light as a reagent decreased the environmental impact of the analysis. The proposed method was based on the oxidation of these pesticides, previously irradiated on-line with UV light, with cerium(IV), using quinine as a sensitiser. Limits of detection below the legal limits (100 ng L−1) established by the European Union for drinking waters were obtained without the need of preconcentration steps. A good inter-day reproducibility (1.6–6.4%, n = 5), repeatability (rsd = 2.7 %, n = 25) and high throughput (123 h−1) were achieved. The method was successfully applied to the determination of methomyl in natural waters with mean recoveries ranging from 90% to 98%. es_ES
dc.description.sponsorship The authors would like to thank Ministerio de Educacion y Ciencia from Spain and FEDER funds for financial support: Project CTM2006-11991. en_EN
dc.language Inglés es_ES
dc.publisher Taylor & Francis: STM, Behavioural Science and Public Health Titles es_ES
dc.relation.ispartof International Journal of Environmental Analytical Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Flow injection es_ES
dc.subject N-methylcarbamates es_ES
dc.subject Photoinduced chemiluminescence es_ES
dc.subject Pesticides es_ES
dc.subject Water es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Determination of N-methylcarbamate pesticides using flow injection with photoinduced chemiluminescence detection es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1080/03067319.2013.879295
dc.relation.projectID info:eu-repo/grantAgreement/MEC//CTM2006-11991/ES/DESARROLLO DE METODOS SENCILLOS EN FLUJO CONTINUO CON DETECCION QUIMIOLUMINISCENTE APLICADOS AL CONTROL DE PLAGUICIDAS EN LOS CULTIVOS DE CITRICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation López Paz, JL.; Catalá Icardo, M.; Langa Sánchez, A. (2014). Determination of N-methylcarbamate pesticides using flow injection with photoinduced chemiluminescence detection. International Journal of Environmental Analytical Chemistry. 94(6):606-617. https://doi.org/10.1080/03067319.2013.879295 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1080/03067319.2013.879295 es_ES
dc.description.upvformatpinicio 606 es_ES
dc.description.upvformatpfin 617 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 94 es_ES
dc.description.issue 6 es_ES
dc.relation.senia 269075
dc.identifier.eissn 1029-0397
dc.contributor.funder Ministerio de Educación y Ciencia es_ES
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