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Polymer-supported chiral -amino amides for the asymmetricaddition of diethylzinc to aldehydes: Transforming an inactivehomogeneous system into an efficient catalyst

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Polymer-supported chiral -amino amides for the asymmetricaddition of diethylzinc to aldehydes: Transforming an inactivehomogeneous system into an efficient catalyst

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Nombre: Escorihuela;Laura ...
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dc.contributor.author Escorihuela Fuentes, Jorge es_ES
dc.contributor.author Gonzalez Mendoza, Laura es_ES
dc.contributor.author Altava Benito, Belén es_ES
dc.contributor.author Burguete Azcarate, Mª Isabel es_ES
dc.contributor.author Luis Lafuente, Santiago es_ES
dc.date.accessioned 2015-06-16T10:45:24Z
dc.date.issued 2013-07-10
dc.identifier.issn 0926-860X
dc.identifier.uri http://hdl.handle.net/10251/51770
dc.description.abstract [EN] A series of polymer-supported -amino amides derived from natural amino acids have been easily syn-thesized and fully characterized. Their chiral Zn (II) complexes catalyzed the enantioselective additionof diethylzinc to aldehydes to form chiral secondary alcohols in high yields and enantioselectivities upto 95% were obtained. The results showed that the immobilization of this chiral ligand onto a polymericmatrix transforms the inactive homogeneous system into an efficient catalyst. Moreover, the supportedcatalyst could be re-used at least five times without any significant loss of catalytic activity. es_ES
dc.description.sponsorship Financial support from Ministerio de Ciencia e Innovacion (CTQ2011-28903-C02-01), and Generalitat Valenciana PROMETEO 2012/020 is gratefully acknowledged.
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Applied Catalysis A: General es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Asymmetric catalysis es_ES
dc.subject Polymer-supported catalysts es_ES
dc.subject Diethylzinc es_ES
dc.subject N-containing ligands es_ES
dc.subject Enantioselective addition es_ES
dc.title Polymer-supported chiral -amino amides for the asymmetricaddition of diethylzinc to aldehydes: Transforming an inactivehomogeneous system into an efficient catalyst es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1016/j.apcata.2013.04.030
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2011-28903-C02-01/ES/DISOLVENTES NEOTERICOS PARA EL DESARROLLO DE PROCESOS QUIMICOS CATALITICOS Y BIOCATALITICOS AVANZADOS Y SOSTENIBLES/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic es_ES
dc.description.bibliographicCitation Escorihuela Fuentes, J.; Gonzalez Mendoza, L.; Altava Benito, B.; Burguete Azcarate, MI.; Luis Lafuente, S. (2013). Polymer-supported chiral -amino amides for the asymmetricaddition of diethylzinc to aldehydes: Transforming an inactivehomogeneous system into an efficient catalyst. Applied Catalysis A: General. 462-463:23-30. https://doi.org/10.1016/j.apcata.2013.04.030 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1016/j.apcata.2013.04.030 es_ES
dc.description.upvformatpinicio 23 es_ES
dc.description.upvformatpfin 30 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 462-463 es_ES
dc.relation.senia 254335
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.contributor.funder Generalitat Valenciana


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