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Electrochemical and In Situ FTIR Study of o-Cresol on Platinum Electrode in Acid Medium

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Electrochemical and In Situ FTIR Study of o-Cresol on Platinum Electrode in Acid Medium

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dc.contributor.author Taleb, Z. es_ES
dc.contributor.author Montilla, F. es_ES
dc.contributor.author Quijada Tomás, Cesar es_ES
dc.contributor.author Morallón, E. es_ES
dc.contributor.author Taleb, S. es_ES
dc.date.accessioned 2015-06-22T08:28:01Z
dc.date.available 2015-06-22T08:28:01Z
dc.date.issued 2014-04
dc.identifier.issn 1868-2529
dc.identifier.uri http://hdl.handle.net/10251/52083
dc.description “The final publication is available at Springer via http://dx.doi.org/10.1007/s12678-013-0182-x” es_ES
dc.description.abstract The electrochemical behaviour of o-cresol in acidic medium on platinum electrode has been studied by cyclic voltammetry and in situ Fourier transform infrared spectroscopy. The o-cresol suffers hydrolysis during oxidation giving rise to the formation of methyl-p-benzoquinone. In situ FTIR spectroscopic studies also reveal the presence of CO2, formed as a consequence of the rupture of the aromatic ring. Moreover, the oxidation of o-cresol in acidic medium produces a polymeric film on the platinum surface that precludes further oxidation of o-cresol. The reduction of o-cresol at potentials below 0 V produces in the first step the partial reduction of the aromatic ring and when the potential goes to values below 0 V, methyl-cyclohexanone. es_ES
dc.description.sponsorship Financial support by the Ministerio de Economia y Competitividad and FEDER (MAT2010-15273) and Generalitat Valenciana (PROMETEO/2013/038) projects is gratefully acknowledged. The authors thank Prof. J.M. Sansano from Organic Chemistry Department of Alicante University for his fruitful discussion. en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation.ispartof Electrocatalysis es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject o-Cresol es_ES
dc.subject Platinum electrode es_ES
dc.subject Oxidation es_ES
dc.subject Reduction es_ES
dc.subject Cyclic voltammetry es_ES
dc.subject FTIR spectroscopy es_ES
dc.subject.classification QUIMICA FISICA es_ES
dc.title Electrochemical and In Situ FTIR Study of o-Cresol on Platinum Electrode in Acid Medium es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s12678-013-0182-x
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2010-15273/ES/ELECTRODOS NANOESTRUCTURADOS PARA APLICACIONES EN SENSORES ELECTROQUIMICOS Y SUPERCONDENSADORES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2013%2F038/ES/Desarrollo de nuevos electrodos y procesos químicos sostenibles para la detección de analitos obtenidos por microextracción líquido-líquido/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera es_ES
dc.description.bibliographicCitation Taleb, Z.; Montilla, F.; Quijada Tomás, C.; Morallón, E.; Taleb, S. (2014). Electrochemical and In Situ FTIR Study of o-Cresol on Platinum Electrode in Acid Medium. Electrocatalysis. 5(2):186-192. https://doi.org/10.1007/s12678-013-0182-x es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s12678-013-0182-x es_ES
dc.description.upvformatpinicio 186 es_ES
dc.description.upvformatpfin 192 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 5 es_ES
dc.description.issue 2 es_ES
dc.relation.senia 274759
dc.identifier.eissn 1868-5994
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.description.references M.D. Obradovic, J. Lessard, G. Jerkiewicz, J Electroanal Chem 649, 248–256 (2010) es_ES
dc.description.references A.A. Isse, A. De Giusti, A. Gennaro, L. Falciola, P.R. Mussini, Electrochim Acta 51, 4956–4964 (2006) es_ES
dc.description.references A.T. Hubbard, Langmuir 6, 97–105 (1990) es_ES
dc.description.references T. Hartung, H. Baltruschat, Langmuir 6, 953–957 (1990) es_ES
dc.description.references M. DeBloisa, J. Lessarda, G. Jerkiewicz, Electrochim Acta 50, 3517–3523 (2005) es_ES
dc.description.references G. Liu, B. Ren, D. Wu, S. Duan, J. Li, J. Yao, R. Gu, Z. Tian, J Phys Chem B 110, 17498–17506 (2006) es_ES
dc.description.references H. Baltruschat, U. Schmiemann, Ber Bunsenges Phys 97, 452–460 (1993) es_ES
dc.description.references F. Montilla, E. Morallón, J.L. Vázquez, Electrochim Acta 47, 4399 (2002) es_ES
dc.description.references G. Jerkiewicz, M. DeBlois, Z. Radovic-Hrapovic, J.P. Tessier, F. Perreault, J. Lessard, Langmuir 21, 3511–3520 (2005) es_ES
dc.description.references F. Montilla, E. Morallón, J.L. Vázquez. Electrochemical behaviour of aromatic compounds on platinum electrodes in different aqueous media in «Trends in electrochemistry and corrosion at the beginning of the 21st century» Ed. Universitat de Barcelona (2004) es_ES
dc.description.references F. Montilla, F. Huerta, E. Morallón, J.L. Vázquez, Electrochim Acta 45, 4271 (2000) es_ES
dc.description.references F. Montilla, E. Morallón, J.L. Vázquez, Langmuir 19, 10241 (2003) es_ES
dc.description.references D. Ren, A.T. Hubbard, J Colloid Interf Sci 209, 435–441 (1999) es_ES
dc.description.references K.H. Kim, S.K. Ihm, J Hazard Mater 186, 16 (2011) es_ES
dc.description.references H.B. Senturk, D. Ozdes, A. Gundogdu, C. Duran, M. Soylak, J Hazard Mater 172, 353 (2009) es_ES
dc.description.references I.D. Santos, J.C. Afonso, A.J.B. Dutra, Sep Purif Technol 76, 151 (2010) es_ES
dc.description.references C. Flox, C. Arias, E. Brillas, A. Savall, K. Groenen-Serrano, Chemosphere 74, 1340 (2009) es_ES
dc.description.references F. Montilla, E. Morallón, J.L. Vázquez, J Electrochem Soc 152, B421 (2005) es_ES
dc.description.references R. Menini, Y.M. Henuset, F. Fournier, J Appl Electrochem 35, 625 (2005) es_ES
dc.description.references J.L. Nava, F. Núñez, I. González, Electrochim Acta 52, 3229 (2007) es_ES
dc.description.references M. Gattrell, D.W. Kirk, J Electrochem Soc 140, 903 (1993) es_ES
dc.description.references M. Gattrell, D.W. Kirk, J Electrochem Soc 140, 1534 (1993) es_ES
dc.description.references H.J. Salavagione, J. Arias, P. Garcés, E. Morallón, C. Barbero, J.L. Vázquez, J Electroanal Chem 565, 375 (2004) es_ES
dc.description.references M. Ferreira, H. Varela, R.M. Torresi, G. Tremiliosi-Filho, Electrochim Acta 52, 434 (2006) es_ES
dc.description.references S. Andreescu, D. Andreescu, O.A. Sadik, Electrochem Comm 5, 681 (2003) es_ES
dc.description.references R. Lapuente, F. Cases, P. Garcés, E. Morallón, J.L. Vázquez, J Electroanal Chem 451, 163 (1998) es_ES
dc.description.references R. Lapuente, C. Quijada, F. Huerta, F. Cases, J.L. Vázquez, Polym J 35, 911 (2003) es_ES
dc.description.references N.B. Colthup, L.H. Daly, S.E. Wiberley, Introduction to Infrared and Raman spectroscopy, 3rd edn. (Academic, San Diego, 1990) es_ES
dc.description.references G. Socrates, Infrared and Raman Characteristic Group Frequencies, 3rd edn. (Wiley, New York, 2001) es_ES
dc.description.references NIST Chemistry WebBook; National Institute of Standards and Technology; 2011, http://webbook.nist.gov/cgi/cbook.cgi?Name=methyl-benzoquinone&Units=SI&cIR = es_ES
dc.description.references M.P. Soriaga, P.H. Wilson, A.T. Hubbard, C.S. Benton, J Electroanal Chem 142, 317 (1982) es_ES
dc.description.references A.R. Almeida, J.A. Moulijn, G. Mul, J Phys Chem C 112, 1552 (2008) es_ES
dc.description.references E.-J. Shin, M.A. Keane, J Catal 173, 450 (1998) es_ES
dc.description.references S. Sciré, C. Crisafulli, R. Maggiore, S. Minicò, S. Galvagno, Appl Surf Sci 93, 309 (1996) es_ES
dc.description.references S. Sciré, S. Minicò, C. Crisafulli, Appl Catal A 235, 21 (2002) es_ES
dc.description.references L.L. Miller, L. Christensen, J Org Chem 43, 2059 (1978) es_ES
dc.description.references H. Ilikti, N. Rekik, M. Thomalla, J Appl Electrochem 34, 127 (2004) es_ES


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