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Synthesis, characterization and conducting properties of nanocomposites of intercalated 2-aminophenol with aniline in codium-montmorillonite

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Synthesis, characterization and conducting properties of nanocomposites of intercalated 2-aminophenol with aniline in codium-montmorillonite

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Nombre: M. Khaldi;ABDELGHANI ...
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dc.contributor.author Khaldi, Mohamed es_ES
dc.contributor.author Benyoucef, Abdelghani es_ES
dc.contributor.author Quijada Tomás, Cesar es_ES
dc.contributor.author Yahiaoui, Ahmed es_ES
dc.contributor.author Morallón, Emilia es_ES
dc.date.accessioned 2015-06-26T08:49:43Z
dc.date.available 2015-06-26T08:49:43Z
dc.date.issued 2014-03
dc.identifier.issn 1574-1443
dc.identifier.uri http://hdl.handle.net/10251/52331
dc.description The final publication is available at Springer via http://dx.doi.org/10.1007/s10904-013-9998-3 es_ES
dc.description.abstract A simple method was used to synthesize poly(2-aminophenol), poly(2-aminophenol-co-Aniline) and polyaniline nanocomposites with sodium-montmorillonite (Na-M) using in situ intercalative oxidative polymerization. Morphology and thermal properties of the synthesized nanocomposites were examined by transmission electron microscopy (TEM) and thermogravimetric analysis. The thermal analysis shows an improved thermal stability of the nanocomposites in comparison with the pure poly(2-aminophenol). The intercalation of polymers into the clay layers was confirmed by X-ray diffraction studies, TEM images and FTIR spectroscopy. In addition, the room temperature conductivity values of these nanocomposites varied between 8.21 x 10(-5) and 6.76 x 10(-4) S cm(-1). The electrochemical behavior of the polymers extracted from the nanocomposites, has been analyzed by cyclic voltammetry. Good electrochemical response has been observed for polymer films; the observed redox processes indicate that the polymerization into Na-M produces electroactive polymers. es_ES
dc.description.sponsorship This work was supported by the National Agency for the Development of University Research (CRSTRA and ANDRU), the Directorate General of Scientific Research and Technological Development (DGRSDT) of Algeria. Ministerio de Economia y Competitividad, FEDER and Generalitat Valenciana are also acknowledged (MAT2010-15273; PROMETEO2013/038). en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation.ispartof Journal of Inorganic and Organometallic Polymers and Materials es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Chemical synthesis es_ES
dc.subject Nanocomposite es_ES
dc.subject Conducting polymer es_ES
dc.subject Montmorillonite es_ES
dc.subject.classification QUIMICA FISICA es_ES
dc.title Synthesis, characterization and conducting properties of nanocomposites of intercalated 2-aminophenol with aniline in codium-montmorillonite es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10904-013-9998-3
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2010-15273/ES/ELECTRODOS NANOESTRUCTURADOS PARA APLICACIONES EN SENSORES ELECTROQUIMICOS Y SUPERCONDENSADORES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO2013%2F038/
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera es_ES
dc.description.bibliographicCitation Khaldi, M.; Benyoucef, A.; Quijada Tomás, C.; Yahiaoui, A.; Morallón, E. (2014). Synthesis, characterization and conducting properties of nanocomposites of intercalated 2-aminophenol with aniline in codium-montmorillonite. Journal of Inorganic and Organometallic Polymers and Materials. 24(2):267-274. https://doi.org/10.1007/s10904-013-9998-3 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s10904-013-9998-3 es_ES
dc.description.upvformatpinicio 267 es_ES
dc.description.upvformatpfin 274 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 24 es_ES
dc.description.issue 2 es_ES
dc.relation.senia 274787
dc.identifier.eissn 1574-1451
dc.contributor.funder Ministerio de Economía y Competitividad
dc.contributor.funder Generalitat Valenciana
dc.contributor.funder Agence Nationale pour le Développement de la Recherche Universitaire, Argelia
dc.contributor.funder Direction Générale de la Recherche Scientifique et du Développement Technologique, Argelia
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