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Layered zeolitic materials: an approach to designing versatile functional solids

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Layered zeolitic materials: an approach to designing versatile functional solids

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Díaz Morales, UM.; Corma Canós, A. (2014). Layered zeolitic materials: an approach to designing versatile functional solids. Dalton Transactions. 43(27):10292-10316. https://doi.org/10.1039/c3dt53181c

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Título: Layered zeolitic materials: an approach to designing versatile functional solids
Autor: Díaz Morales, Urbano Manuel Corma Canós, Avelino
Entidad UPV: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Fecha difusión:
Resumen:
Relevant layered zeolites have been considered in this perspective article from the point of view of the synthesis methodologies, materials characterization and catalytic implications, considering the unique physico-chemical ...[+]
Palabras clave: Delaminated itq-2 zeolite , Organic-inorganic aluminosilicate , Piperazine silicate eu-19 , Pillared molecular-sieve , Diphenyl methane dadpm , Alkali-metal cations , Unit-cell thickness , Mww-type zeolites , Pure polymorph-c , Catalytic-activity
Derechos de uso: Reserva de todos los derechos
Fuente:
Dalton Transactions. (issn: 1477-9226 ) (eissn: 1477-9234 )
DOI: 10.1039/c3dt53181c
Editorial:
Royal Society of Chemistry
Versión del editor: http://dx.doi.org/10.1039/c3dt53181c
Código del Proyecto:
info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/
info:eu-repo/grantAgreement/MICINN//MAT2011-29020-C02-01/ES/CATALIZADORES HIBRIDOS MULTIFUNCIONALES BASADOS EN UNIDADES ESTRUCTURALES ORGANICAS-INORGANICAS UTILIZADOS EN REACCIONES CASCADA/
info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/
Agradecimientos:
The authors thank financial support to Spanish Government by Consolider-Ingenio MULTICAT CSD2009-00050, MAT2011-29020-C02-01 and Severo Ochoa Excellence Program SEV-2012-0267.
Tipo: Artículo

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Zhu, J., Cui, Y., Wang, Y., & Wei, F. (2009). Direct synthesis of hierarchical zeolite from a natural layered material. Chemical Communications, (22), 3282. doi:10.1039/b902661d

Wang, Y. J., Tang, Y., Wang, X. D., Dong, A. G., Shan, W., & Gao, Z. (2001). Fabrication of Hierarchically Structured Zeolites through Layer-by-Layer Assembly of Zeolite Nanocrystals on Diatom Templates. Chemistry Letters, 30(11), 1118-1119. doi:10.1246/cl.2001.1118

Rhodes, K. H., Davis, S. A., Caruso, F., Zhang, B., & Mann, S. (2000). Hierarchical Assembly of Zeolite Nanoparticles into Ordered Macroporous Monoliths Using Core−Shell Building Blocks. Chemistry of Materials, 12(10), 2832-2834. doi:10.1021/cm000438y

Corma, A., Díaz, U., García, T., Sastre, G., & Velty, A. (2010). Multifunctional Hybrid Organic−Inorganic Catalytic Materials with a Hierarchical System of Well-Defined Micro- and Mesopores. Journal of the American Chemical Society, 132(42), 15011-15021. doi:10.1021/ja106272z

Inagaki, S., & Tatsumi, T. (2009). Vapor-phase silylation for the construction of monomeric silica puncheons in the interlayer micropores of Al-MWW layered precursor. Chemical Communications, (18), 2583. doi:10.1039/b823524d

Wu, P., Ruan, J., Wang, L., Wu, L., Wang, Y., Liu, Y., … Tatsumi, T. (2008). Methodology for Synthesizing Crystalline Metallosilicates with Expanded Pore Windows Through Molecular Alkoxysilylation of Zeolitic Lamellar Precursors. Journal of the American Chemical Society, 130(26), 8178-8187. doi:10.1021/ja0758739

Wang, L., Wang, Y., Liu, Y., Wu, H., Li, X., He, M., & Wu, P. (2009). Alkoxysilylation of Ti-MWW lamellar precursors into interlayer pore-expanded titanosilicates. Journal of Materials Chemistry, 19(45), 8594. doi:10.1039/b910886f

Ruan, J., Wu, P., Slater, B., & Terasaki, O. (2005). Structure Elucidation of the Highly Active Titanosilicate Catalyst Ti-YNU-1. Angewandte Chemie International Edition, 44(41), 6719-6723. doi:10.1002/anie.200501939

Moliner, M., & Corma, A. (2012). Synthesis of Expanded Titanosilicate MWW-Related Materials from a Pure Silica Precursor. Chemistry of Materials, 24(22), 4371-4375. doi:10.1021/cm302509m

Corma, A., Fornes, V., Pergher, S. B., Maesen, T. L. M., & Buglass, J. G. (1998). Delaminated zeolite precursors as selective acidic catalysts. Nature, 396(6709), 353-356. doi:10.1038/24592

Corma, A., Fornés, V., Guil, J. ., Pergher, S., Maesen, T. L. ., & Buglass, J. . (2000). Preparation, characterisation and catalytic activity of ITQ-2, a delaminated zeolite. Microporous and Mesoporous Materials, 38(2-3), 301-309. doi:10.1016/s1387-1811(00)00149-9

Corma, A., Diaz, U., Fornés, V., Guil, J. M., Martínez-Triguero, J., & Creyghton, E. J. (2000). Characterization and Catalytic Activity of MCM-22 and MCM-56 Compared with ITQ-2. Journal of Catalysis, 191(1), 218-224. doi:10.1006/jcat.1999.2774

Sastre, G., Catlow, C. R. A., Chica, A., & Corma, A. (2000). Molecular Dynamics of C7 Hydrocarbon Diffusion in ITQ-2. The Benefit of Zeolite Structures Containing Accessible Pockets. The Journal of Physical Chemistry B, 104(3), 416-422. doi:10.1021/jp9913970

Ogino, I., Nigra, M. M., Hwang, S.-J., Ha, J.-M., Rea, T., Zones, S. I., & Katz, A. (2011). Delamination of Layered Zeolite Precursors under Mild Conditions: Synthesis of UCB-1 via Fluoride/Chloride Anion-Promoted Exfoliation. Journal of the American Chemical Society, 133(10), 3288-3291. doi:10.1021/ja111147z

Wu, P., Nuntasri, D., Ruan, J., Liu, Y., He, M., Fan, W., … Tatsumi, T. (2004). Delamination of Ti-MWW and High Efficiency in Epoxidation of Alkenes with Various Molecular Sizes. The Journal of Physical Chemistry B, 108(50), 19126-19131. doi:10.1021/jp037459a

Corma, A., Díaz, U., Fornés, V., Jordá, J. L., Domine, M., & Rey, F. (1999). Ti/ITQ-2, a new material highly active and selective for the epoxidation of olefins with organic hydroperoxides. Chemical Communications, (9), 779-780. doi:10.1039/a900763f

Adam, W., Corma, A., García, H., & Weichold, O. (2000). Titanium-Catalyzed Heterogeneous Oxidations of Silanes, Chiral Allylic Alcohols, 3-Alkylcyclohexanes, and Thianthrene 5-Oxide: A Comparison of the Reactivities and Selectivities for the Large-Pore Zeolite Ti-β, the Mesoporous Ti-MCM-41, and the Layered Alumosilicate Ti-ITQ-2. Journal of Catalysis, 196(2), 339-344. doi:10.1006/jcat.2000.3043

SERNA, P., BAUMES, L., MOLINER, M., & CORMA, A. (2008). Combining high-throughput experimentation, advanced data modeling and fundamental knowledge to develop catalysts for the epoxidation of large olefins and fatty esters. Journal of Catalysis, 258(1), 25-34. doi:10.1016/j.jcat.2008.05.033

Baumes, L. A., Serna, P., & Corma, A. (2010). Merging traditional and high-throughput approaches results in efficient design, synthesis and screening of catalysts for an industrial process. Applied Catalysis A: General, 381(1-2), 197-208. doi:10.1016/j.apcata.2010.04.012

Juttu, G. G., & Lobo, R. F. (2000). Characterization and catalytic properties of MCM-56 and MCM-22 zeolites. Microporous and Mesoporous Materials, 40(1-3), 9-23. doi:10.1016/s1387-1811(00)00233-x

Yang, P. P., Yu, J. F., Wang, Z. L., Xu, M. P., Liu, Q. S., Yang, X. W., & Wu, T. H. (2005). Preparation, characterization of MCM-56 and catalytic activity in one-step synthesis of MIBK from acetone. Catalysis Communications, 6(2), 107-111. doi:10.1016/j.catcom.2004.11.008

CORMA, A., DIAZCABANAS, M., MOLINER, M., & MARTINEZ, C. (2006). Discovery of a new catalytically active and selective zeolite (ITQ-30) by high-throughput synthesis techniques. Journal of Catalysis, 241(2), 312-318. doi:10.1016/j.jcat.2006.04.036

Roth, W. J., Dorset, D. L., & Kennedy, G. J. (2011). Discovery of new MWW family zeolite EMM-10: Identification of EMM-10P as the missing MWW precursor with disordered layers. Microporous and Mesoporous Materials, 142(1), 168-177. doi:10.1016/j.micromeso.2010.10.052

Wang, J., Tu, X., Hua, W., Yue, Y., & Gao, Z. (2011). Role of the acidity and porosity of MWW-type zeolites in liquid-phase reaction. Microporous and Mesoporous Materials, 142(1), 82-90. doi:10.1016/j.micromeso.2010.11.021

JUNG, H., PARK, S., SHIN, C., PARK, Y., & HONG, S. (2007). Comparative catalytic studies on the conversion of 1-butene and n-butane to isobutene over MCM-22 and ITQ-2 zeolites. Journal of Catalysis, 245(1), 65-74. doi:10.1016/j.jcat.2006.09.015

Inagaki, S., Kamino, K., Kikuchi, E., & Matsukata, M. (2007). Shape selectivity of MWW-type aluminosilicate zeolites in the alkylation of toluene with methanol. Applied Catalysis A: General, 318, 22-27. doi:10.1016/j.apcata.2006.10.036

Corma, A. (1997). Organic reactions catalyzed over solid acids. Catalysis Today, 38(3), 257-308. doi:10.1016/s0920-5861(97)81500-1

Botella, P., Corma, A., Carr, R. H., & Mitchell, C. J. (2011). Towards an industrial synthesis of diamino diphenyl methane (DADPM) using novel delaminated materials: A breakthrough step in the production of isocyanates for polyurethanes. Applied Catalysis A: General, 398(1-2), 143-149. doi:10.1016/j.apcata.2011.03.026

Corma, A., Botella, P., & Mitchell, C. (2004). Replacing HCl by solid acids in industrial processes: synthesis of diamino diphenyl methane (DADPM) for producing polyurethanesElectronic supplementary information (ESI) available: detailed analytical procedures by GC and 1H-NMR techniques. See http://www.rsc.org/suppdata/cc/b4/b406303a/. Chemical Communications, (17), 2008. doi:10.1039/b406303a

Min, H.-K., Park, M. B., & Hong, S. B. (2010). Methanol-to-olefin conversion over H-MCM-22 and H-ITQ-2 zeolites. Journal of Catalysis, 271(2), 186-194. doi:10.1016/j.jcat.2010.01.012

Wang, J., Zhang, F., Hua, W., Yue, Y., & Gao, Z. (2012). Dehydrogenation of propane over MWW-type zeolites supported gallium oxide. Catalysis Communications, 18, 63-67. doi:10.1016/j.catcom.2011.11.023

Corma, A., González-Alfaro, V., & Orchillés, A. . (2001). Decalin and Tetralin as Probe Molecules for Cracking and Hydrotreating the Light Cycle Oil. Journal of Catalysis, 200(1), 34-44. doi:10.1006/jcat.2001.3181

Corma, A., Martı́nez, A., & Martı́nez-Soria, V. (2001). Catalytic Performance of the New Delaminated ITQ-2 Zeolite for Mild Hydrocracking and Aromatic Hydrogenation Processes. Journal of Catalysis, 200(2), 259-269. doi:10.1006/jcat.2001.3219

Prieto, G., Martínez, A., Concepción, P., & Moreno-Tost, R. (2009). Cobalt particle size effects in Fischer–Tropsch synthesis: structural and in situ spectroscopic characterisation on reverse micelle-synthesised Co/ITQ-2 model catalysts. Journal of Catalysis, 266(1), 129-144. doi:10.1016/j.jcat.2009.06.001

MARTINEZ, A., & PRIETO, G. (2007). Breaking the dispersion-reducibility dependence in oxide-supported cobalt nanoparticles. Journal of Catalysis, 245(2), 470-476. doi:10.1016/j.jcat.2006.11.002

Concepción, P., López, C., Martínez, A., & Puntes, V. F. (2004). Characterization and catalytic properties of cobalt supported on delaminated ITQ-6 and ITQ-2 zeolites for the Fischer–Tropsch synthesis reaction. Journal of Catalysis, 228(2), 321-332. doi:10.1016/j.jcat.2004.09.011

Martínez, A., Valencia, S., Murciano, R., Cerqueira, H. S., Costa, A. F., & S.-Aguiar, E. F. (2008). Catalytic behavior of hybrid Co/SiO2-(medium-pore) zeolite catalysts during the one-stage conversion of syngas to gasoline. Applied Catalysis A: General, 346(1-2), 117-125. doi:10.1016/j.apcata.2008.05.015

Martínez, A., Peris, E., & Sastre, G. (2005). Dehydroaromatization of methane under non-oxidative conditions over bifunctional Mo/ITQ-2 catalysts. Catalysis Today, 107-108, 676-684. doi:10.1016/j.cattod.2005.07.051

Chica, A., & Sayas, S. (2009). Effective and stable bioethanol steam reforming catalyst based on Ni and Co supported on all-silica delaminated ITQ-2 zeolite. Catalysis Today, 146(1-2), 37-43. doi:10.1016/j.cattod.2008.12.024

RODRIGUEZ, I., CLIMENT, M., IBORRA, S., FORNES, V., & CORMA, A. (2000). Use of delaminated zeolites (ITQ-2) and mesoporous molecular sieves in the production of fine chemicals: Preparation of dimethylacetals and tetrahydropyranylation of alcohols and phenols. Journal of Catalysis, 192(2), 441-447. doi:10.1006/jcat.2000.2861

Aquino, C. C., Pastore, H. O., Masters, A. F., & Maschmeyer, T. (2011). An ITQ-2/TUD-1 Micro-/Mesoporous Composite: In Situ Delamination as a Tool for the Preparation of Innovative Materials. ChemCatChem, 3(11), 1759-1762. doi:10.1002/cctc.201100077

Climent, M. J., Corma, A., & Velty, A. (2004). Synthesis of hyacinth, vanilla, and blossom orange fragrances: the benefit of using zeolites and delaminated zeolites as catalysts. Applied Catalysis A: General, 263(2), 155-161. doi:10.1016/j.apcata.2003.12.007

CLIMENT, M., CORMA, A., & IBORRA, S. (2005). Synthesis of nonsteroidal drugs with anti-inflammatory and analgesic activities with zeolites and mesoporous molecular sieve catalysts. Journal of Catalysis, 233(2), 308-316. doi:10.1016/j.jcat.2005.05.003

BOTELLA, P., CORMA, A., IBORRA, S., MONTON, R., RODRIGUEZ, I., & COSTA, V. (2007). Nanosized and delayered zeolitic materials for the liquid-phase Beckmann rearrangement of cyclododecanone oxime. Journal of Catalysis, 250(1), 161-170. doi:10.1016/j.jcat.2007.05.020

GOMEZ, M., CANTIN, A., CORMA, A., & DELAHOZ, A. (2005). Use of different microporous and mesoporous materials as catalyst in the Diels–Alder and retro-Diels–Alder reaction between cyclopentadiene and p-benzoquinoneActivity of Al-, Ti- and Sn-doped silica. Journal of Molecular Catalysis A: Chemical, 240(1-2), 16-21. doi:10.1016/j.molcata.2005.06.030

Wang, J., Jaenicke, S., Chuah, G. K., Hua, W., Yue, Y., & Gao, Z. (2011). Acidity and porosity modulation of MWW type zeolites for Nopol production by Prins condensation. Catalysis Communications, 12(12), 1131-1135. doi:10.1016/j.catcom.2011.03.034

Antunes, M. M., Lima, S., Fernandes, A., Pillinger, M., Ribeiro, M. F., & Valente, A. A. (2012). Aqueous-phase dehydration of xylose to furfural in the presence of MCM-22 and ITQ-2 solid acid catalysts. Applied Catalysis A: General, 417-418, 243-252. doi:10.1016/j.apcata.2011.12.046

Fuerte, A., Corma, A., Iglesias, M., Morales, E., & Sánchez, F. (2006). Approaches to the synthesis of heterogenised metalloporphyrins. Journal of Molecular Catalysis A: Chemical, 246(1-2), 109-117. doi:10.1016/j.molcata.2005.10.031

Baleizão, C., Gigante, B., Sabater, M. J., Garcia, H., & Corma, A. (2002). On the activity of chiral chromium salen complexes covalently bound to solid silicates for the enantioselective epoxide ring opening. Applied Catalysis A: General, 228(1-2), 279-288. doi:10.1016/s0926-860x(01)00979-6

Ayala, V., Corma, A., Iglesias, M., Rincón, J. A., & Sánchez, F. (2004). Hybrid organic—inorganic catalysts: a cooperative effect between support, and palladium and nickel salen complexes on catalytic hydrogenation of imines. Journal of Catalysis, 224(1), 170-177. doi:10.1016/j.jcat.2004.02.017

González-Arellano, C., Corma, A., Iglesias, M., & Sánchez, F. (2004). Improved Palladium and Nickel Catalysts Heterogenised on Oxidic Supports (Silica, MCM-41, ITQ-2, ITQ-6). Advanced Synthesis & Catalysis, 346(11), 1316-1328. doi:10.1002/adsc.200404029

González-Arellano, C., Corma, A., Iglesias, M., & Sánchez, F. (2004). Pd(II)-Schiff Base Complexes Heterogenised on MCM-41 and Delaminated Zeolites as Efficient and Recyclable Catalysts for the Heck Reaction. Advanced Synthesis & Catalysis, 346(13-15), 1758-1764. doi:10.1002/adsc.200404119

DOMINGUEZ, I., FORNES, V., & SABATER, M. (2004). Chiral manganese(III) salen catalysts immobilized on MCM-41 and delaminated zeolites ITQ-2 and ITQ-6 through new axial coordinating linkers. Journal of Catalysis, 228(1), 92-99. doi:10.1016/j.jcat.2004.08.021

Baleizão, C. (2003). Chiral vanadyl Schiff base complex anchored on silicas as solid enantioselective catalysts for formation of cyanohydrins: optimization of the asymmetric induction by support modification. Journal of Catalysis, 215(2), 199-207. doi:10.1016/s0021-9517(03)00007-1

Fuerte, A., Corma, A., & Sánchez, F. (2005). Heterogenised chiral amines as environmentally friendly base catalysts for enantioselective Michael addition. Catalysis Today, 107-108, 404-409. doi:10.1016/j.cattod.2005.07.095

Corma, A., Gutiérrez-Puebla, E., Iglesias, M., Monge, A., Pérez-Ferreras, S., & Sánchez, F. (2006). New Heterogenized Gold(I)-Heterocyclic Carbene Complexes as Reusable Catalysts in Hydrogenation and Cross-Coupling Reactions. Advanced Synthesis & Catalysis, 348(14), 1899-1907. doi:10.1002/adsc.200606163

Corma, A., González-Arellano, C., Iglesias, M., Pérez-Ferreras, S., & Sánchez, F. (2007). Heterogenized Gold(I), Gold(III), and Palladium(II) Complexes for C-C Bond Reactions. Synlett, 2007(11), 1771-1774. doi:10.1055/s-2007-984500

Macario, A., Katovic, A., Giordano, G., Forni, L., Carloni, F., Filippini, A., & Setti, L. (2005). Immobilization of Lipase on microporous and mesoporous materials: studies of the support surfaces. Studies in Surface Science and Catalysis, 381-394. doi:10.1016/s0167-2991(05)80166-1

Corma, A., Forne´s, V., Sales Galletero, M., García, H., & Gómez-García, C. J. (2001). Prevalence of the external surface over the internal pores in the spontaneous generation of tetrathiafulvalene radical cation incorporated in the novel delaminated ITQ-2 zeolite. Physical Chemistry Chemical Physics, 3(7), 1218-1222. doi:10.1039/b009304l

Galletero, M. S., Corma, A., Ferrer, B., Fornés, V., & García, H. (2003). Confinement Effects at the External Surface of Delaminated Zeolites (ITQ-2):  An Inorganic Mimic of Cyclodextrins. The Journal of Physical Chemistry B, 107(5), 1135-1141. doi:10.1021/jp0210531

Corma, A., Fornés, V., Galletero, M. S., García, H., & Scaiano, J. C. (2002). Evidence for through-framework electron transfer in intrazeolite photochemistry. Case of Ru(bpy)32+ and methylviologen in novel delaminated ITQ-2 zeolite. Chemical Communications, (4), 334-335. doi:10.1039/b110440c

Corma, A., Díaz, U., Ferrer, B., Fornés, V., Galletero, M. S., & García, H. (2004). Controlling the Emission of Blue-Emitting Complexes by Encapsulation within Zeolite Cavities. Chemistry of Materials, 16(7), 1170-1176. doi:10.1021/cm0347640

Atienzar, P., Corma, A., García, H., & Scaiano, J. C. (2004). Diffuse Reflectance Laser Flash Photolysis Study of Titanium-Containing Zeolites. Chemistry of Materials, 16(6), 982-987. doi:10.1021/cm049941r

Corma, A., Galletero, M. S., García, H., Palomares, E., & Rey, F. (2002). Pyrene covalently anchored on a large external surface area zeolite as a selective heterogeneous sensor for iodide. Chemical Communications, (10), 1100-1101. doi:10.1039/b201523b

Dathe, H., Sedlmair, C., Jentys, A., & Lercher, J. A. (2004). Adsorption of SO2 on different metal impregnated zeolites. Recent Advances in the Science and Technology of Zeolites and Related Materials, Proceedings of the 14th International Zeolite Conference, 3003-3009. doi:10.1016/s0167-2991(04)80584-6

Yang, S.-T., Kim, J.-Y., Kim, J., & Ahn, W.-S. (2012). CO2 capture over amine-functionalized MCM-22, MCM-36 and ITQ-2. Fuel, 97, 435-442. doi:10.1016/j.fuel.2012.03.034

Pawlesa, J., Zukal, A., & Čejka, J. (2007). Synthesis and adsorption investigations of zeolites MCM-22 and MCM-49 modified by alkali metal cations. Adsorption, 13(3-4), 257-265. doi:10.1007/s10450-007-9023-7

Domínguez, I., Pawlesa, J., Zukal, A., & Čejka, J. (2008). Ferrierite and MCM-22 for the CO2 adsorption. Studies in Surface Science and Catalysis, 603-606. doi:10.1016/s0167-2991(08)80272-8

Zukal, A., Pawlesa, J., & Čejka, J. (2009). Isosteric heats of adsorption of carbon dioxide on zeolite MCM-22 modified by alkali metal cations. Adsorption, 15(3), 264-270. doi:10.1007/s10450-009-9178-5

Zukal, A., Dominguez, I., Mayerová, J., & Čejka, J. (2009). Functionalization of Delaminated Zeolite ITQ-6 for the Adsorption of Carbon Dioxide. Langmuir, 25(17), 10314-10321. doi:10.1021/la901156z

Corma, A., Fornés, V., & Díaz, U. (2001). Chemical Communications, (24), 2642-2643. doi:10.1039/b108777k

Corma, A., Diaz, U., Domine, M. E., & Fornés, V. (2000). New Aluminosilicate and Titanosilicate Delaminated Materials Active for Acid Catalysis, and Oxidation Reactions Using H2O2. Journal of the American Chemical Society, 122(12), 2804-2809. doi:10.1021/ja9938130

Corma, A., Diaz, U., Domine, M. E., & Fornés, V. (2000). Ti-ferrierite and TiITQ-6: synthesis and catalytic activity for the epoxidation of olefins with H2O2. Chemical Communications, (2), 137-138. doi:10.1039/a908748f

Corma, A., Fornés, V., Jordá, J. L., Rey, F., Fernandez-Lafuente, R., Guisan, J. M., & Mateo, C. (2001). Electrostatic and covalent immobilisation of enzymes on ITQ-6 delaminated zeolitic materials. Chemical Communications, (5), 419-420. doi:10.1039/b009232k

Corma, A., Fornes, V., & Rey, F. (2002). Delaminated Zeolites: An Efficient Support for Enzymes. Advanced Materials, 14(1), 71-74. doi:10.1002/1521-4095(20020104)14:1<71::aid-adma71>3.0.co;2-w

Dumitriu, E., Secundo, F., Patarin, J., & Fechete, I. (2003). Preparation and properties of lipase immobilized on MCM-36 support. Journal of Molecular Catalysis B: Enzymatic, 22(3-4), 119-133. doi:10.1016/s1381-1177(03)00015-8

Solsona, B., Lopez Nieto, J. M., & Díaz, U. (2006). Siliceous ITQ-6: A new support for vanadia in the oxidative dehydrogenation of propane. Microporous and Mesoporous Materials, 94(1-3), 339-347. doi:10.1016/j.micromeso.2006.04.007

Eilertsen, E. A., Ogino, I., Hwang, S.-J., Rea, T., Yeh, S., Zones, S. I., & Katz, A. (2011). Nonaqueous Fluoride/Chloride Anion-Promoted Delamination of Layered Zeolite Precursors: Synthesis and Characterization of UCB-2. Chemistry of Materials, 23(24), 5404-5408. doi:10.1021/cm202364q

Choi, M., Na, K., Kim, J., Sakamoto, Y., Terasaki, O., & Ryoo, R. (2009). Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts. Nature, 461(7261), 246-249. doi:10.1038/nature08288

Park, W., Yu, D., Na, K., Jelfs, K. E., Slater, B., Sakamoto, Y., & Ryoo, R. (2011). Hierarchically Structure-Directing Effect of Multi-Ammonium Surfactants for the Generation of MFI Zeolite Nanosheets. Chemistry of Materials, 23(23), 5131-5137. doi:10.1021/cm201709q

Jung, J., Jo, C., Cho, K., & Ryoo, R. (2012). Zeolite nanosheet of a single-pore thickness generated by a zeolite-structure-directing surfactant. Journal of Materials Chemistry, 22(11), 4637. doi:10.1039/c2jm16539b

Na, K., Choi, M., Park, W., Sakamoto, Y., Terasaki, O., & Ryoo, R. (2010). Pillared MFI Zeolite Nanosheets of a Single-Unit-Cell Thickness. Journal of the American Chemical Society, 132(12), 4169-4177. doi:10.1021/ja908382n

Na, K., Park, W., Seo, Y., & Ryoo, R. (2011). Disordered Assembly of MFI Zeolite Nanosheets with a Large Volume of Intersheet Mesopores. Chemistry of Materials, 23(5), 1273-1279. doi:10.1021/cm103245m

Corma, A., Fornés, V., Forni, L., Márquez, F., Martı́nez-Triguero, J., & Moscotti, D. (1998). 2,6-Di-Tert-Butyl-Pyridine as a Probe Molecule to Measure External Acidity of Zeolites. Journal of Catalysis, 179(2), 451-458. doi:10.1006/jcat.1998.2233

Kim, K., Ryoo, R., Jang, H.-D., & Choi, M. (2012). Spatial distribution, strength, and dealumination behavior of acid sites in nanocrystalline MFI zeolites and their catalytic consequences. Journal of Catalysis, 288, 115-123. doi:10.1016/j.jcat.2012.01.009

Seo, Y., Cho, K., Jung, Y., & Ryoo, R. (2013). Characterization of the Surface Acidity of MFI Zeolite Nanosheets by 31P NMR of Adsorbed Phosphine Oxides and Catalytic Cracking of Decalin. ACS Catalysis, 3(4), 713-720. doi:10.1021/cs300824e

Kim, J., Park, W., & Ryoo, R. (2011). Surfactant-Directed Zeolite Nanosheets: A High-Performance Catalyst for Gas-Phase Beckmann Rearrangement. ACS Catalysis, 1(4), 337-341. doi:10.1021/cs100160g

Jo, C., Ryoo, R., Žilková, N., Vitvarová, D., & Čejka, J. (2013). The effect of MFI zeolite lamellar and related mesostructures on toluene disproportionation and alkylation. Catalysis Science & Technology, 3(8), 2119. doi:10.1039/c3cy00146f

Koekkoek, A. J. J., Kim, W., Degirmenci, V., Xin, H., Ryoo, R., & Hensen, E. J. M. (2013). Catalytic performance of sheet-like Fe/ZSM-5 zeolites for the selective oxidation of benzene with nitrous oxide. Journal of Catalysis, 299, 81-89. doi:10.1016/j.jcat.2012.12.002

Verheyen, E., Jo, C., Kurttepeli, M., Vanbutsele, G., Gobechiya, E., Korányi, T. I., … Martens, J. A. (2013). Molecular shape-selectivity of MFI zeolite nanosheets in n-decane isomerization and hydrocracking. Journal of Catalysis, 300, 70-80. doi:10.1016/j.jcat.2012.12.017

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