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Theoretical and experimental insights into the origin of the catalytic activity of subnanometric gold clusters: attempts to predict reactivity with clusters and nanoparticles of gold

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Theoretical and experimental insights into the origin of the catalytic activity of subnanometric gold clusters: attempts to predict reactivity with clusters and nanoparticles of gold

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Boronat Zaragoza, M.; Leyva Perez, A.; Corma Canós, A. (2014). Theoretical and experimental insights into the origin of the catalytic activity of subnanometric gold clusters: attempts to predict reactivity with clusters and nanoparticles of gold. Accounts of Chemical Research. 47(3):834-844. https://doi.org/10.1021/ar400068w

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/55540

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Title: Theoretical and experimental insights into the origin of the catalytic activity of subnanometric gold clusters: attempts to predict reactivity with clusters and nanoparticles of gold
Author: Boronat Zaragoza, Mercedes Leyva Perez, Antonio Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] Particle size is one of the key parameters determining the unexpected catalytic activity of gold, with reactivity improving as the particle gets smaller. While this is valid In the 1-5 nm range, chemists are now ...[+]
Subjects: Aerobic oxidation , Co oxidation , AU Clusters , Propene epoxidation , Temperature , Selectivity , Nanoclusters , Iodobenzene , Adsorption , Propylene
Copyrigths: Cerrado
Source:
Accounts of Chemical Research. (issn: 0001-4842 )
DOI: 10.1021/ar400068w
Publisher:
American Chemical Society
Publisher version: http://dx.doi.org/10.1021/ar400068w
Project ID:
info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/
info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/
info:eu-repo/grantAgreement/MICINN//MAT2011-28009/ES/CATALIZADORES MONO- Y MULTIFUNCIONALES BASADOS EN NANOPARTICULAS METALICAS DIRIGIDOS A TRANSFORMACIONES SECUENCIALES O REACCIONES EN CASCADA/
Thanks:
Financial support from the Spanish Science and Innovation Ministry (Consolider Ingenio 2010-MULTICAT CSD2009-00050, Subprograma de apoyo a Centros y Universidades de Excelencia Sever Ochoa SEV 2012 0267, MAT2011-28009 ...[+]
Type: Artículo

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