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Low-cost inorganic cation exchange membrane for electrodialysis: optimum processing temperature for the cation exchanger

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Low-cost inorganic cation exchange membrane for electrodialysis: optimum processing temperature for the cation exchanger

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dc.contributor.author Mestre, S. es_ES
dc.contributor.author Sales, S. es_ES
dc.contributor.author Palacios, M.D. es_ES
dc.contributor.author Lorente, M.M. es_ES
dc.contributor.author Mallol, G. es_ES
dc.contributor.author Pérez-Herranz, Valentín es_ES
dc.date.accessioned 2015-10-19T11:49:27Z
dc.date.available 2015-10-19T11:49:27Z
dc.date.issued 2013-04
dc.identifier.issn 1944-3994
dc.identifier.uri http://hdl.handle.net/10251/56208
dc.description.abstract The optimum temperature for fixing zirconium phosphate, obtained by precipitation, on a low-cost ceramic support was determined in order to obtain an inorganic cation exchange membrane for electrodialysis. Zirconium phosphate ion exchange capacity maximised between 450 and 550°C, thus it was considered the optimum processing temperature. The origin of this maximum was investigated by means of X-ray diffraction and termogravimetry and evolved gas analysis. Zirconium phosphate formation by precipitation in the porous network of the support was verified by scanning electron microscopy and energy dispersive X-ray analysis and mercury intrusion porosimetry. The membrane obtained after thermal treatment at 450°C displayed selectivity to the cations present in the spent rinse water of the chromium plating process. This property allows the recovery of chromium by removing the cations through the cation exchange ceramic membrane. es_ES
dc.description.sponsorship The authors wish to express their gratitude to the Spanish Ministry of Science and Innovation for the support given to the research study (National Basic Research Programme, Ref. CTQ2008-06750-C02-02), as well as for the FPU student grant awarded to one of the authors (Ref.: AP2009-4409). en_EN
dc.language Inglés es_ES
dc.publisher Taylor & Francis es_ES
dc.relation.ispartof Desalination and Water Treatment es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Alpha-Zirconium Phosphate es_ES
dc.subject Chromium plating baths es_ES
dc.subject Crystalline zirconium es_ES
dc.subject Transport properties es_ES
dc.subject Composite membranes es_ES
dc.subject Titanium Phosphate es_ES
dc.subject Ceramic membranes es_ES
dc.subject Acid es_ES
dc.subject Salts es_ES
dc.subject Regeneration es_ES
dc.subject Zirconium phosphate es_ES
dc.subject Ion exchange capacity es_ES
dc.subject Cationic membrane es_ES
dc.subject Electrodialysis es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Low-cost inorganic cation exchange membrane for electrodialysis: optimum processing temperature for the cation exchanger es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1080/19443994.2012.749177
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2008-06750-C02-02/ES/DESARROLLO DE MEMBRANAS CERAMICAS POROSAS NANOESTRUCTURADAS CONDUCTORAS DE IONES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/ME//AP2009-4409/ES/AP2009-4409/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Mestre, S.; Sales, S.; Palacios, M.; Lorente, M.; Mallol, G.; Pérez-Herranz, V. (2013). Low-cost inorganic cation exchange membrane for electrodialysis: optimum processing temperature for the cation exchanger. Desalination and Water Treatment. 51(16-18):3317-3324. https://doi.org/10.1080/19443994.2012.749177 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1080/19443994.2012.749177 es_ES
dc.description.upvformatpinicio 3317 es_ES
dc.description.upvformatpfin 3324 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 51 es_ES
dc.description.issue 16-18 es_ES
dc.relation.senia 248516 es_ES
dc.identifier.eissn 1944-3986
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Ministerio de Educación es_ES
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