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Crystal structure of the coordination polymer [FeIII2{PtII(CN)4}3]

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Crystal structure of the coordination polymer [FeIII2{PtII(CN)4}3]

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dc.contributor.author Muñoz Roca, María del Carmen es_ES
dc.date.accessioned 2015-10-19T11:52:56Z
dc.date.available 2015-10-19T11:52:56Z
dc.date.issued 2014-11
dc.identifier.issn 1600-5368
dc.identifier.uri http://hdl.handle.net/10251/56209
dc.description.abstract [EN] The title complex, poly[dodeca--cyanido-diiron(III)triplatinum(II)], [FeIII2{PtII(CN)4}3], has a three-dimensional polymeric structure. It is built-up from square-planar [PtII(CN)4] 2 anions (point group symmetry 2/m) bridging cationic [FeIIIPtII(CN)4] + 1 layers extending in the bc plane. The FeII atoms of the layers are located on inversion centres and exhibit an octahedral coordination sphere defined by six N atoms of cyanide ligands, while the PtII atoms are located on twofold rotation axes and are surrounded by four C atoms of the cyanide ligands in a square-planar coordination. The geometrical preferences of the two cations for octahedral and square-planar coordination, respectively, lead to a corrugated organisation of the layers. The distance between neighbouring [FeIIIPtII(CN)4] + 1 layers corresponds to the length a/2 = 8.0070 (3) A˚ , and the separation between two neighbouring PtII atoms of the bridging [PtII(CN)4] 2 groups corresponds to the length of the c axis [7.5720 (2) A˚ ]. The structure is porous with accessible voids of 390 A˚ 3 per unit cell. es_ES
dc.description.sponsorship This study was supported by the Spanish Ministerio de Economı´a y Competitividad (MINECO) and FEDER funds (CTQ2013–46275-P) and Generalitat Valenciana (PROMETEO/2012/049). MS thanks the EU for a Marie Curie fellowship (IIF-253254)
dc.language Inglés es_ES
dc.publisher International Union of Crystallography es_ES
dc.relation MINECO/CTQ2013–46275-P es_ES
dc.relation GV/PROMETEO/2012/049 es_ES
dc.relation.ispartof Acta Crystallographica Section E: Structure Reports Online es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Polycyanidometalate es_ES
dc.subject Crystal structure es_ES
dc.subject Spin-crossover es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Crystal structure of the coordination polymer [FeIII2{PtII(CN)4}3] es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1107/S2056989014026188
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/253254/EU
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Muñoz Roca, MDC. (2014). Crystal structure of the coordination polymer [FeIII2{PtII(CN)4}3]. Acta Crystallographica Section E: Structure Reports Online. E71:i1-i2. http://hdl.handle.net/10251/56209 es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://doi.org/10.1107/S2056989014026188 es_ES
dc.description.upvformatpinicio i1 es_ES
dc.description.upvformatpfin i2 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume E71 es_ES
dc.relation.senia 293028 es_ES
dc.identifier.pmid 25705468
dc.identifier.pmcid PMC4331858
dc.contributor.funder Ministerio de Economía y Competitividad (MINECO)
dc.contributor.funder European Commission
dc.contributor.funder Generalitat Valenciana


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