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dc.contributor.author | Muñoz Roca, María del Carmen | es_ES |
dc.date.accessioned | 2015-10-19T11:52:56Z | |
dc.date.available | 2015-10-19T11:52:56Z | |
dc.date.issued | 2014-11 | |
dc.identifier.issn | 1600-5368 | |
dc.identifier.uri | http://hdl.handle.net/10251/56209 | |
dc.description.abstract | [EN] The title complex, poly[dodeca--cyanido-diiron(III)triplatinum(II)], [FeIII2{PtII(CN)4}3], has a three-dimensional polymeric structure. It is built-up from square-planar [PtII(CN)4] 2 anions (point group symmetry 2/m) bridging cationic [FeIIIPtII(CN)4] + 1 layers extending in the bc plane. The FeII atoms of the layers are located on inversion centres and exhibit an octahedral coordination sphere defined by six N atoms of cyanide ligands, while the PtII atoms are located on twofold rotation axes and are surrounded by four C atoms of the cyanide ligands in a square-planar coordination. The geometrical preferences of the two cations for octahedral and square-planar coordination, respectively, lead to a corrugated organisation of the layers. The distance between neighbouring [FeIIIPtII(CN)4] + 1 layers corresponds to the length a/2 = 8.0070 (3) A˚ , and the separation between two neighbouring PtII atoms of the bridging [PtII(CN)4] 2 groups corresponds to the length of the c axis [7.5720 (2) A˚ ]. The structure is porous with accessible voids of 390 A˚ 3 per unit cell. | es_ES |
dc.description.sponsorship | This study was supported by the Spanish Ministerio de Economı´a y Competitividad (MINECO) and FEDER funds (CTQ2013–46275-P) and Generalitat Valenciana (PROMETEO/2012/049). MS thanks the EU for a Marie Curie fellowship (IIF-253254) | |
dc.language | Inglés | es_ES |
dc.publisher | International Union of Crystallography | es_ES |
dc.relation.ispartof | Acta Crystallographica Section E: Structure Reports Online | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Polycyanidometalate | es_ES |
dc.subject | Crystal structure | es_ES |
dc.subject | Spin-crossover | es_ES |
dc.subject.classification | FISICA APLICADA | es_ES |
dc.title | Crystal structure of the coordination polymer [FeIII2{PtII(CN)4}3] | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1107/S2056989014026188 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2013-46275-P/ES/SENSORES Y MEMORIAS BASADOS EN MATERIALES BIESTABLES CON TRANSICION DE ESPIN/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/253254/EU/Tailoring crossover properties by electric field in nano-structural and liquid crystalline molecular based magnetic materials/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F049/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada | es_ES |
dc.description.bibliographicCitation | Muñoz Roca, MDC. (2014). Crystal structure of the coordination polymer [FeIII2{PtII(CN)4}3]. Acta Crystallographica Section E: Structure Reports Online. E71:i1-i2. https://doi.org/10.1107/S2056989014026188 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://doi.org/10.1107/S2056989014026188 | es_ES |
dc.description.upvformatpinicio | i1 | es_ES |
dc.description.upvformatpfin | i2 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | E71 | es_ES |
dc.relation.senia | 293028 | es_ES |
dc.identifier.pmid | 25705468 | |
dc.identifier.pmcid | PMC4331858 | |
dc.contributor.funder | Ministerio de Economía y Competitividad | |
dc.contributor.funder | European Commission | |
dc.contributor.funder | Generalitat Valenciana |