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dc.contributor.author | Climent Olmedo, María José | es_ES |
dc.contributor.author | Iborra Chornet, Sara | es_ES |
dc.contributor.author | Sabater Picot, Mª José | es_ES |
dc.contributor.author | Vidal Castro, Juan Diego | |
dc.date.accessioned | 2015-11-06T08:08:44Z | |
dc.date.available | 2015-11-06T08:08:44Z | |
dc.date.issued | 2014-07-05 | |
dc.identifier.issn | 0926-860X | |
dc.identifier.uri | http://hdl.handle.net/10251/57107 | |
dc.description.abstract | A bifunctional organocatalyst with ionic liquid properties and with an optimized distance between the acid and basic sites efficiently activates electron deficient olefins for 1,4 conjugated addition, which can be incorporated in different one-pot transformations for the preparation of cyclic and acyclic compounds of biological and synthetic interest. More specifically, the catalyst can be successfully applied for different carbon–carbon (Csingle bondC) and carbon–heteroatom (Csingle bondN, Csingle bondO, Csingle bondS) bond forming reactions integrated in a cascade sequence. The activity of the organocatalyst has been compared with that of structurally related monofunctional and bifunctional catalysts. The most attractive features of this procedure are the high atom economy and the use of inexpensive starting materials as well as the use of an environmentally friendly catalyst that can be easily recovered due to its ionic liquid properties. | es_ES |
dc.description.sponsorship | Financial support by Consolider-Ingenio 2010 (project MULTICAT), Spanish MICINN (Projects MAT2011-28009 and CTQ-201127550) and Program Severo Ochoa are gratefully acknowledged. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | Applied Catalysis A: General | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Organocatalysis | es_ES |
dc.subject | Bifunctional | es_ES |
dc.subject | Acid–base | es_ES |
dc.subject | One-pot | es_ES |
dc.subject | Michael addition | es_ES |
dc.subject | Condensation | es_ES |
dc.subject | Fine chemicals | es_ES |
dc.subject | Chromenes | es_ES |
dc.subject | Quinolines | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.subject.classification | QUIMICA ANALITICA | es_ES |
dc.title | Bifunctional acid-base ionic liquid for the one-pot synthesis of fine chemicals: thioethers, 2H-chromenes and 2H-quinoline derivatives | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.apcata.2014.05.004 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ / | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CTQ2011-27550/ES/TRANSFORMACION CATALITICA DE BIOMASA EN DIESEL Y EN PRODUCTOS QUIMICOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//MAT2011-28009/ES/CATALIZADORES MONO- Y MULTIFUNCIONALES BASADOS EN NANOPARTICULAS METALICAS DIRIGIDOS A TRANSFORMACIONES SECUENCIALES O REACCIONES EN CASCADA/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Climent Olmedo, MJ.; Iborra Chornet, S.; Sabater Picot, MJ.; Vidal Castro, JD. (2014). Bifunctional acid-base ionic liquid for the one-pot synthesis of fine chemicals: thioethers, 2H-chromenes and 2H-quinoline derivatives. Applied Catalysis A: General. 481:27-38. https://doi.org/10.1016/j.apcata.2014.05.004 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.apcata.2014.05.004 | es_ES |
dc.description.upvformatpinicio | 27 | es_ES |
dc.description.upvformatpfin | 38 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 481 | es_ES |
dc.relation.senia | 283496 | |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |