Dhakshinamoorthy, A.; Asiri, AM.; García Gómez, H. (2014). Catalysis by metal organic frameworks in water. Chemical Communications. 50(85):12800-12814. https://doi.org/10.1039/C4CC04387A
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/57293
Title:
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Catalysis by metal organic frameworks in water
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Author:
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Dhakshinamoorthy, Amarajothi
Asiri, Abdullah M.
García Gómez, Hermenegildo
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UPV Unit:
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Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
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Issued date:
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Abstract:
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[EN] Metal–organic frameworks (MOFs) having a large surface area and porosity as well as a high density of transition metals are increasingly used as heterogeneous catalysts for organic reactions. However, one of the main ...[+]
[EN] Metal–organic frameworks (MOFs) having a large surface area and porosity as well as a high density of transition metals are increasingly used as heterogeneous catalysts for organic reactions. However, one of the main limitations of various MOFs has been their lack of structural stability that led to an assumption that MOFs are unstable materials, particularly in water or polar solvents. However, since a few years ago the hydrothermal stability of several MOFs such as MIL-101(Cr), MIL-53(Al) and ZIF-8 has been demonstrated and, hence, they can be used as solid catalysts in the aqueous phase. The present review is aimed at showing that there are a sufficiently large number of reports proving that certain MOFs can be used as reusable catalysts in water as the solvent. The use of water as the solvent has considerable advantages from the environmental point of view and affordability. Water can be the solvent of choice for hydrolytic processes, but MOFs have been reported as catalysts in water even for esterifications and C–C couplings. Considering that the synthesis of new MOFs is an active area of research and the flexibility in the selection of transition metals and organic linkers, these materials can be prepared with the required hydrophilicity/hydrophobicity to adapt specifically for catalysis in aqueous phase.
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Subjects:
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Mesoporous Mcm-41 Aluminosilicates
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Monodisperse Nickel Nanoparticles
,
Porous Coordination Polymers
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Aqueous Ammonia-Borane
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Lewis-Acid Catalysts
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Hydrogen Generation
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Heat Transformation
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Coupling Reactions
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Hydrolytic Dehydrogenation
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Heterogeneous Catalysis
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Copyrigths:
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Cerrado |
Source:
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Chemical Communications. (issn:
1359-7345
) (eissn:
1364-548X
)
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DOI:
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10.1039/C4CC04387A
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Publisher:
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Royal Society of Chemistry
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Publisher version:
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http://dx.doi.org/10.1039/C4CC04387A
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Project ID:
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info:eu-repo/grantAgreement/EC/FP7/228862/EU/MOFs as Catalysts and Adsorbents: Discovery and Engineering of Materials for Industrial Applications/
info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/
info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F014/
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Thanks:
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A.D.M. thanks University Grants Commission (UGC), New Delhi, for the award of Assistant Professorship under its Faculty Recharge
Programme. Financial support by the Spanish Ministry of Economy and Competitiveness ...[+]
A.D.M. thanks University Grants Commission (UGC), New Delhi, for the award of Assistant Professorship under its Faculty Recharge
Programme. Financial support by the Spanish Ministry of Economy and Competitiveness (CTQ-2012-32315 and Severo Ochoa) and
Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged. The research leading to these results has received partial
funding from the European Community’s Seventh Framework Programme (FP7/2007–2013) under grant agreement no. 228862
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Type:
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Artículo
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