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MOF catalysis in relation to their homogeneous counterparts and conventional solid catalysts

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MOF catalysis in relation to their homogeneous counterparts and conventional solid catalysts

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dc.contributor.author García García, Pilar es_ES
dc.contributor.author Müller, Maike es_ES
dc.contributor.author Corma Canós, Avelino
dc.date.accessioned 2015-11-10T13:30:50Z
dc.date.available 2015-11-10T13:30:50Z
dc.date.issued 2014
dc.identifier.issn 2041-6520
dc.identifier.uri http://hdl.handle.net/10251/57295
dc.description.abstract Metal-organic frameworks have recently attracted attention as heterogeneous catalysts due to their high content of metal centres and large surface area and pore volume, along with their impressive topological richness. Therefore, many studies describing the use of MOFs as heterogeneous Lewis acid catalysts have been published. In this regard, these efforts have been directed towards probing the catalytic activity. Further information is required in terms of kinetic parameters and comparison of performance with their homogeneous counterparts, or other conventional heterogeneous catalysts. Here we have attempted to put MOFs into perspective with respect to their homogeneous counterparts and more conventional heterogeneous catalysts to show their advantages and limitations. We have exemplified a number of reactions reported in the literature wherein MOFs have been used as catalysts, and we have carried them out using homogeneous counterparts, i.e. benzoates and acetates, and other well defined conventional solid catalysts. The activities and selectivities of the catalysts are compared and then put into perspective on the basis of kinetic parameters, such as turnover numbers and turnover frequencies. Additionally, we illustrate using selected examples what the potential advantages of MOF catalysts could be, and how they may outperform the potential of other solid catalysts. es_ES
dc.description.sponsorship This work was supported by the Spanish Government (Consolider Ingenio 2010-MULTICAT (CSD2009-00050) and MAT2011-29020-C02-01). P.G.-G. thanks ITQ for a contract. M.M. thanks the Alexander von Humboldt Foundation for a Feodor Lynen Postdoctoral Scholarship. The Severo Ochoa program is gratefully acknowledged. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation Spanish Government (Consolider Ingenio 2010-MULTICAT) CSD2009-00050 es_ES
dc.relation Spanish Government (Consolider Ingenio 2010-MULTICAT) MAT2011-29020-C02-01 es_ES
dc.relation Alexander von Humboldt Foundation es_ES
dc.relation.ispartof Chemical Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Metal-Organic Frameworks es_ES
dc.subject Friedel-Crafts Alkylation es_ES
dc.subject Heterogeneous Asymmetric Catalysis es_ES
dc.subject Electron-Deficient Olefins es_ES
dc.subject Light-Driven Photocatalyst es_ES
dc.subject Enantioselective Catalyst es_ES
dc.subject Chemoselective Reduction es_ES
dc.subject Aerobic Hydrogenation es_ES
dc.subject Coordination Polymer es_ES
dc.subject Oxidative Amidation es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title MOF catalysis in relation to their homogeneous counterparts and conventional solid catalysts es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c4sc00265b
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation García García, P.; Müller, M.; Corma Canós, A. (2014). MOF catalysis in relation to their homogeneous counterparts and conventional solid catalysts. Chemical Science. 5(8):2979-3007. doi:10.1039/c4sc00265b es_ES
dc.description.accrualMethod Senia es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c4sc00265b es_ES
dc.description.upvformatpinicio 2979 es_ES
dc.description.upvformatpfin 3007 es_ES
dc.type.version info:eu repo/semantics/publishedVersion es_ES
dc.description.volume 5 es_ES
dc.description.issue 8 es_ES
dc.relation.senia 282358 es_ES


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