Blay, G.; Fernández, I.; Muñoz Roca, MDC.; Pedro, J.; Recuenco, A.; Vila, C. (2011). Enantioselective Synthesis of Tertiary Alcohols through a Zirconium-Catalized Friedel-Crafts Alkylation of Pyrroles with alpha-Ketoesters. Journal of Organic Chemistry. 76:6286-6294. https://doi.org/10.1021/jo2010704
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/57368
Title: | Enantioselective Synthesis of Tertiary Alcohols through a Zirconium-Catalized Friedel-Crafts Alkylation of Pyrroles with alpha-Ketoesters | |
Author: | Blay, G. Fernández, I. Muñoz Roca, María del Carmen Pedro, J.R. Recuenco, A. Vila, C. | |
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Chiral complexes of 1,10-bi-2-naphthol-based ligands with
zirconium tert-butoxide catalyze the Friedel Crafts alkylation of pyrroles
with R-ketoesters to afford tertiary alcohols in good yields and ee up to 98%.
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Publisher version: | http://dx.doi.org/10.1021/jo2010704 | |
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