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Enantioselective Synthesis of Tertiary Alcohols through a Zirconium-Catalized Friedel-Crafts Alkylation of Pyrroles with alpha-Ketoesters

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Enantioselective Synthesis of Tertiary Alcohols through a Zirconium-Catalized Friedel-Crafts Alkylation of Pyrroles with alpha-Ketoesters

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Blay, G.; Fernández, I.; Muñoz Roca, MDC.; Pedro, J.; Recuenco, A.; Vila, C. (2011). Enantioselective Synthesis of Tertiary Alcohols through a Zirconium-Catalized Friedel-Crafts Alkylation of Pyrroles with alpha-Ketoesters. Journal of Organic Chemistry. 76:6286-6294. https://doi.org/10.1021/jo2010704

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Title: Enantioselective Synthesis of Tertiary Alcohols through a Zirconium-Catalized Friedel-Crafts Alkylation of Pyrroles with alpha-Ketoesters
Author: Blay, G. Fernández, I. Muñoz Roca, María del Carmen Pedro, J.R. Recuenco, A. Vila, C.
UPV Unit: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Issued date:
Abstract:
Chiral complexes of 1,10-bi-2-naphthol-based ligands with zirconium tert-butoxide catalyze the Friedel Crafts alkylation of pyrroles with R-ketoesters to afford tertiary alcohols in good yields and ee up to 98%. The ...[+]
Copyrigths: Cerrado
Source:
Journal of Organic Chemistry. (issn: 0022-3263 )
DOI: 10.1021/jo2010704
Publisher:
American Chemical Society
Publisher version: http://dx.doi.org/10.1021/jo2010704
Project ID:
info:eu-repo/grantAgreement/MICINN//CTQ2009-13083/ES/Desarrollo de nuevos procesos enantioselectivos de formación de enlaces C-C mediante catálisis asimétrica/
info:eu-repo/grantAgreement/GVA//ACOMP%2F2011%2F267/
Thanks:
We thank the Ministerio de Ciencia e Innovacion and FEDER (Grant CTQ2009-13083) and the Generalitat Valenciana (Grant ACOMP/2011/267) for financial support. C.V. thanks the Generalitat Valenciana for a predoctoral grant.
Type: Artículo

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