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MOFs as Multifunctional catalysts: Synthesis of secondary arylamines, quinolines, pyrroles and arylpyrrolidines over bifunctional MIL-101

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MOFs as Multifunctional catalysts: Synthesis of secondary arylamines, quinolines, pyrroles and arylpyrrolidines over bifunctional MIL-101

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dc.contributor.author García Cirujano, Francisco es_ES
dc.contributor.author Leyva Perez, Antonio es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author Llabrés i Xamena, Francesc Xavier es_ES
dc.date.accessioned 2015-11-18T12:59:19Z
dc.date.issued 2013-02
dc.identifier.issn 1867-3880
dc.identifier.uri http://hdl.handle.net/10251/57687
dc.description.abstract Bifunctional MIL-101 MOFs containing Lewis acid Cr3+ sites and Pd or Pt hydrogenation/reduction centers, either as isolated metal complexes or in the form of encapsulated metal nanoparticles, have shown to be highly active catalysts for the one-pot nitroarene reduction and reductive amination of carbonyl compounds. This preparation procedure has been successfully applied to the synthesis of secondary arylamines, quinolines, pyrrols, and 3-arylpyrrolidines. In all the cases, the MOFs have shown superior performances with respect to commercially available Pd and Pt metal catalysts under the same conditions. es_ES
dc.description.sponsorship Financial support by Ministerio de Educacion y Ciencia e Innovacion (Project MAT2011-29020-C02-01, and CSD2009-00050 PROGRAMA CONSOLIDER. INGENIO 2009), Ministerio de Economia y Competitividad (Subprograma de apoyo a Centros y Universidades de Excelencia Severo Ochoa, Project SEV 2012 0267) and the CSIC (Proyectos Intramurales Especiales 201080I020) is gratefully acknowledged. en_EN
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof ChemCatChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Amination es_ES
dc.subject Carbonyl compounds es_ES
dc.subject Heterocycle synthesis es_ES
dc.subject Hydrogenation es_ES
dc.subject Metalorganic frameworks es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title MOFs as Multifunctional catalysts: Synthesis of secondary arylamines, quinolines, pyrroles and arylpyrrolidines over bifunctional MIL-101 es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/cctc.201200878
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CSIC//201080I020/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2011-29020-C02-01/ES/CATALIZADORES HIBRIDOS MULTIFUNCIONALES BASADOS EN UNIDADES ESTRUCTURALES ORGANICAS-INORGANICAS UTILIZADOS EN REACCIONES CASCADA/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation García Cirujano, F.; Leyva Perez, A.; Corma Canós, A.; Llabrés I Xamena, FX. (2013). MOFs as Multifunctional catalysts: Synthesis of secondary arylamines, quinolines, pyrroles and arylpyrrolidines over bifunctional MIL-101. ChemCatChem. 5(2):538-549. https://doi.org/10.1002/cctc.201200878 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/cctc.201200878 es_ES
dc.description.upvformatpinicio 538 es_ES
dc.description.upvformatpfin 549 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 5 es_ES
dc.description.issue 2 es_ES
dc.relation.senia 244275 es_ES
dc.contributor.funder Consejo Superior de Investigaciones Científicas es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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