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Superior Performance of Fe(BTC) With Respect to Other Metal-Containing Solids in the N-Hydroxyphthalimide-Promoted Heterogeneous Aerobic Oxidation of Cycloalkanes

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Superior Performance of Fe(BTC) With Respect to Other Metal-Containing Solids in the N-Hydroxyphthalimide-Promoted Heterogeneous Aerobic Oxidation of Cycloalkanes

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dc.contributor.author Mikami, Yusuke es_ES
dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2015-11-18T14:00:15Z
dc.date.issued 2013-07
dc.identifier.issn 1867-3880
dc.identifier.uri http://hdl.handle.net/10251/57696
dc.description.abstract A series of heterogeneous catalysts incorporating N-hydroxyphthalimide (NHPI) and contg. transition-metal ion as promoter (Fe3+ or Co2+) on a support such as Fe(BTC) (BTC=1,3,5-benzenetricarboxylate), zeolites Y and Beta, mesoporous Al-MCM-41 aluminosilicate, and nonporous silica have been prepd. and tested for the aerobic oxidn. of cyclooctane. It was found that NHPI/Fe(BTC) as catalyst exhibits the best performance in the series with the highest selectivity to the -ol/-one mixt. at identical conversions. These results have been interpreted as being due to the appropriate combination between reaction cavity dimensions and confinement of the autoxidn. chain reaction. The catalytic activity for cyclohexane using NHPI/Fe(BTC) under similar reaction conditions is also reported. es_ES
dc.description.sponsorship Financial support by the Spanish MINECOM (CTQ-2009-11586) is gratefully acknowledged. ADM thanks the University Grants Commission (UGC), New Delhi, for the award of Faculty Recharge Programme. en_EN
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof ChemCatChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject cycloalkanes es_ES
dc.subject metal-organic frameworks es_ES
dc.subject oxidation es_ES
dc.subject zeolites es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Superior Performance of Fe(BTC) With Respect to Other Metal-Containing Solids in the N-Hydroxyphthalimide-Promoted Heterogeneous Aerobic Oxidation of Cycloalkanes es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/cctc.201200854
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CTQ2009-11583/ES/Ruptura Fotocaliftica del Agua con Luz Solar/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Mikami, Y.; Dhakshinamoorthy, A.; Alvaro Rodríguez, MM.; García Gómez, H. (2013). Superior Performance of Fe(BTC) With Respect to Other Metal-Containing Solids in the N-Hydroxyphthalimide-Promoted Heterogeneous Aerobic Oxidation of Cycloalkanes. ChemCatChem. 5(7):1964-1970. https://doi.org/10.1002/cctc.201200854 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/cctc.201200854 es_ES
dc.description.upvformatpinicio 1964 es_ES
dc.description.upvformatpfin 1970 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 5 es_ES
dc.description.issue 7 es_ES
dc.relation.senia 259372 es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder University Grants Commission, India es_ES
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