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Zirconium Materials from Mixed Dicarboxylate Linkers: Enhancing the Stability for Catalytic Applications

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Zirconium Materials from Mixed Dicarboxylate Linkers: Enhancing the Stability for Catalytic Applications

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dc.contributor.author Rasero-Almansa, Antonia M. es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author Iglesias, Marta es_ES
dc.contributor.author Sanchez, Felix es_ES
dc.date.accessioned 2015-11-19T09:28:56Z
dc.date.issued 2014-12
dc.identifier.issn 1867-3880
dc.identifier.uri http://hdl.handle.net/10251/57727
dc.description.abstract [EN] We report the synthesis of two series of zirconium-based metal-organic frameworks from solutions composed of a mixed-ligand system (naphthalene dicarboxylic acid/4-amino-2,6-naphthalenedicarboxylic acid or [1,1'-biphenyl]-4,4'-dicarboxylic acid (BPDC)/2-amino-[1,1'-biphenyl]-4,4'-dicarboxylic acid). Materials synthesized with low loadings of functionalized linkers exhibit higher long-term chemical stability and similarly high thermal stability relative to those with 100% amino linkers. These materials and their corresponding rhodium derivatives prove excellent catalysts in one-pot reactions. Moreover, the recycling experiments demonstrate an interesting prospect for the long-term reusability of these catalysts. es_ES
dc.description.sponsorship This work was supported by MINECO of Spain (Project MAT2011-29020-C02-02, Consolider-Ingenio 2010-CSD-0050-MULTICAT). A.M.R.A. thanks MINECO for the FPI program.
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation info:eu-repo/grantAgreement/MICINN//MAT2011-29020-C02-02/ES/MATERIALES HIBRIDOS ORGANO-INORGANICOS COMO CATALIZADORES SELECTIVOS RECICLABLES/ es_ES
dc.relation MINECO/CSD-0050-MULTICAT es_ES
dc.relation.ispartof ChemCatChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Metal-organic frameworks es_ES
dc.subject Multicomponent reactions es_ES
dc.subject N ligands es_ES
dc.subject Zirconium es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Zirconium Materials from Mixed Dicarboxylate Linkers: Enhancing the Stability for Catalytic Applications es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/cctc.201402546
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Rasero-Almansa, AM.; Corma Canós, A.; Iglesias, M.; Sanchez, F. (2014). Zirconium Materials from Mixed Dicarboxylate Linkers: Enhancing the Stability for Catalytic Applications. ChemCatChem. 6(12):3426-3433. https://doi.org/10.1002/cctc.201402546 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/cctc.201402546 es_ES
dc.description.upvformatpinicio 3426 es_ES
dc.description.upvformatpfin 3433 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 6 es_ES
dc.description.issue 12 es_ES
dc.relation.senia 286156 es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación


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