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Hydroxyl radical as an unlikely key intermediate in the photodegradation of emerging pollutants

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Hydroxyl radical as an unlikely key intermediate in the photodegradation of emerging pollutants

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Nombre: PandP 2014, 90 (6), ...
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dc.contributor.author Rodríguez Muñiz, Gemma María es_ES
dc.contributor.author Gomis Vicens, Juan es_ES
dc.contributor.author Arques Sanz, Antonio es_ES
dc.contributor.author Amat Payá, Ana María es_ES
dc.contributor.author Marín García, Mª Luisa es_ES
dc.contributor.author Miranda Alonso, Miguel Ángel es_ES
dc.date.accessioned 2015-11-23T10:00:23Z
dc.date.available 2015-11-23T10:00:23Z
dc.date.issued 2014-11
dc.identifier.issn 0031-8655
dc.identifier.uri http://hdl.handle.net/10251/57876
dc.description This is the accepted version of the following article: Rodriguez-Muñiz, G. M., Gomis, J., Arques, A., Amat, A. M., Marin, M. L. and Miranda, M. A. (2014), Hydroxyl Radical as an Unlikely Key Intermediate in the Photodegradation of Emerging Pollutants. Photochemistry and Photobiology, 90: 1467–1469, which has been published in final form at http://dx.doi.org/10.1111/php.12325. es_ES
dc.description.abstract In this work, a kinetic model, in combination with time-resolved experiments, is applied to assess the involvement of OH in the photodegradation of emerging pollutants (EPs) by means of advanced oxidation processes. In contrast with the general assumption, quenching of the short-lived OH in the real waters by the (highly diluted) EPs must be very inefficient, so removal of EPs cannot purely rely on the generation and reaction of OH. This suggests that more complex pathways have to be considered to explain the photodegradation of EPs actually achieved under the employed oxidative conditions, possibly involving other reactive species with longer lifetimes or chain degradation processes. es_ES
dc.description.sponsorship This work was supported by the Spanish Government (Projects CTQ2012-38754-C03-03 and CTQ2012-38754-C03-02) and Technical University of Valencia (Predoctoral fellowship for J. Gomis). en_EN
dc.language Inglés es_ES
dc.publisher Wiley-Blackwell es_ES
dc.relation.ispartof Photochemistry and Photobiology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Laser Flash-Photolysis es_ES
dc.subject Photochemical fate es_ES
dc.subject Organic-Matter es_ES
dc.subject Oxidation es_ES
dc.subject Water es_ES
dc.subject Acid es_ES
dc.subject Pharmaceuticals es_ES
dc.subject Degradation es_ES
dc.subject Environment es_ES
dc.subject Reactivity es_ES
dc.subject.classification INGENIERIA TEXTIL Y PAPELERA es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.subject.classification QUIMICA FISICA es_ES
dc.title Hydroxyl radical as an unlikely key intermediate in the photodegradation of emerging pollutants es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1111/php.12325
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2012-38754-C03-02/ES/DESARROLLO DE NUEVAS ESTRATEGIAS BASADAS EN LA INTEGRACION DE PROCESOS FOTOQUIMICOS SOLARES CON OTRAS TECNICAS AVANZADAS PARA EL TRATAMIENTO DE AGUAS RESIDUALES COMPLEJAS./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2012-38754-C03-03/ES/CTQ2012-38754-C03-03/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Rodríguez Muñiz, GM.; Gomis Vicens, J.; Arqués Sanz, A.; Amat Payá, AM.; Marín García, ML.; Miranda Alonso, MÁ. (2014). Hydroxyl radical as an unlikely key intermediate in the photodegradation of emerging pollutants. Photochemistry and Photobiology. 90(6):1467-1469. doi:10.1111/php.12325 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1111/php.12325 es_ES
dc.description.upvformatpinicio 1467 es_ES
dc.description.upvformatpfin 1469 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 90 es_ES
dc.description.issue 6 es_ES
dc.relation.senia 279831 es_ES
dc.identifier.eissn 1751-1097
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
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