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NMR Spectrocopic Characterization and DFT Calculations of Zirconium(IV)-3,3 -Br-2-BINOLate and Related Complexes Used in an Enantioselective Friedel Crafts Alkylation of Indoles with alpha, beta-Unsaturated Ketones

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NMR Spectrocopic Characterization and DFT Calculations of Zirconium(IV)-3,3 -Br-2-BINOLate and Related Complexes Used in an Enantioselective Friedel Crafts Alkylation of Indoles with alpha, beta-Unsaturated Ketones

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Blay, G.; Cano, J.; Cardona, L.; Fernandez, I.; Muñoz Roca, MDC.; Pedro, J.; Vila, C. (2012). NMR Spectrocopic Characterization and DFT Calculations of Zirconium(IV)-3,3 -Br-2-BINOLate and Related Complexes Used in an Enantioselective Friedel Crafts Alkylation of Indoles with alpha, beta-Unsaturated Ketones. Journal of Organic Chemistry. 77(23):10545-10556. doi:10.1021/jo3013594

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/59125

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Title: NMR Spectrocopic Characterization and DFT Calculations of Zirconium(IV)-3,3 -Br-2-BINOLate and Related Complexes Used in an Enantioselective Friedel Crafts Alkylation of Indoles with alpha, beta-Unsaturated Ketones
Author: Blay, G. Cano, J. Cardona, L. Fernandez, I. Muñoz Roca, María del Carmen Pedro, J.R. Vila, C.
UPV Unit: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Issued date:
Abstract:
Experimental and theoretical studies on the structure of several complexes based on (R)-3,3'-Br-2-BINOL ligand and group (IV) metals used as catalysts in an enantioselective Friedel-Crafts alkylation of indoles with ...[+]
Copyrigths: Cerrado
Source:
Journal of Organic Chemistry. (issn: 0022-3263 )
DOI: 10.1021/jo3013594
Publisher:
American Chemical Society
Publisher version: http://dx.doi.org/10.1021/jo3013594
Project ID:
Ministerio de Ciencia e Innovacion
Gobierno de Espana
FEDER
European Union (Grant CTQ 2009-13083)
Generalitat Valenciana (Grants ACOMP/2012/212 and ISIC 2012/001)
Thanks:
Financial support from the Ministerio de Ciencia e Innovacion, Gobierno de Espana and FEDER, European Union (Grant CTQ 2009-13083) and the Generalitat Valenciana (Grants ACOMP/2012/212 and ISIC 2012/001) is acknowledged. ...[+]
Type: Artículo

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