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Cationic Copper(I) complexes as highly efficient catalysts for single and double A(3)-coupling mannich reactions of terminal alkynes: Mechanistic insights and comparative studies with analogous Gold (I) complexes

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Cationic Copper(I) complexes as highly efficient catalysts for single and double A(3)-coupling mannich reactions of terminal alkynes: Mechanistic insights and comparative studies with analogous Gold (I) complexes

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Grirrane, A.; Alvarez, E.; García Gómez, H.; Corma Canós, A. (2014). Cationic Copper(I) complexes as highly efficient catalysts for single and double A(3)-coupling mannich reactions of terminal alkynes: Mechanistic insights and comparative studies with analogous Gold (I) complexes. Chemistry - A European Journal. 20(44):14317-14328. https://doi.org/10.1002/chem.201403927

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Title: Cationic Copper(I) complexes as highly efficient catalysts for single and double A(3)-coupling mannich reactions of terminal alkynes: Mechanistic insights and comparative studies with analogous Gold (I) complexes
Author: Grirrane, Abdessamad Alvarez, Eleuterio García Gómez, Hermenegildo Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] Cationic Cu L complexes (L=Buchwald-type phosphane) with N co-ligands have been characterised by structural and spectroscopic properties. These copper(I) complexes are extremely active catalysts, far more active than ...[+]
Subjects: Coordination chemistry , Copper , Homogeneous catalysis , Reaction mechanisms , Solvent effects
Copyrigths: Cerrado
Source:
Chemistry - A European Journal. (issn: 0947-6539 ) (eissn: 1521-3765 )
DOI: 10.1002/chem.201403927
Publisher:
Wiley-VCH Verlag
Publisher version: http://dx.doi.org/10.1002/chem.201403927
Project ID:
info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/
info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F014/
Thanks:
Financial support by the Spanish ministry of Economy and Competitiveness (Severo Ochoa and CTQ2012-32315) and Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged. We also thank Dr. J. A. Vidal-Moya (ITQ) ...[+]
Type: Artículo

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