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dc.contributor.author | Verde-Sesto, Ester | es_ES |
dc.contributor.author | Pintado-Sierra, Mercedes | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.contributor.author | Maya, Eva M. | es_ES |
dc.contributor.author | de la Campa, Jose G. | es_ES |
dc.contributor.author | Iglesias, Marta | es_ES |
dc.contributor.author | Sanchez, Felix | es_ES |
dc.date.accessioned | 2016-01-21T10:45:19Z | |
dc.date.issued | 2014-04-22 | |
dc.identifier.issn | 0947-6539 | |
dc.identifier.uri | http://hdl.handle.net/10251/60102 | |
dc.description.abstract | [EN] Starting from mononitrotetrakis(iodophenyl)methane as monomer, we report the preparation of the first pre-functionalised porous aromatic frameworks (PAFs) and their application as supports for organometallic catalysts. Neutral coordinate imino-pyridine Schiff base (PAF-NPy) or chiral bis-amino (PAF-NPro) ligands were obtained by postsynthetic treatment of PAF-NH2 and treated with copper(I) or rhodium(I) to yield the corresponding supported transition- metal catalysts. The as-prepared PAF-NN-M catalysts exhibited activity and selectivity similar to that of the corresponding homogeneous catalysts and were easily removed from reaction media and recycled without loss of activity or selectivity. | es_ES |
dc.description.sponsorship | We acknowledge the Direccion General de Investigacion Cientifica y Tecnica (MINECO) Spain (Projects MAT2011-29020-C02-02 and Consolider-Ingenio 2010-CSD-0050-MULTICAT) for financial support. | |
dc.language | Inglés | es_ES |
dc.publisher | Wiley-VCH Verlag | es_ES |
dc.relation.ispartof | Chemistry - A European Journal | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Cyclopropanation | es_ES |
dc.subject | Heterogeneous catalysts | es_ES |
dc.subject | Porous aromatic frameworks | es_ES |
dc.subject | Recyclability | es_ES |
dc.subject | Supported catalysts | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | First pre-functionalized polymeric aromatic framework from nononitrotetrakis(iodophenyl)methane and its applications | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1002/chem.201304163 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//MAT2011-29020-C02-02/ES/MATERIALES HIBRIDOS ORGANO-INORGANICOS COMO CATALIZADORES SELECTIVOS RECICLABLES/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ / | |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Verde-Sesto, E.; Pintado-Sierra, M.; Corma Canós, A.; Maya, EM.; De La Campa, JG.; Iglesias, M.; Sanchez, F. (2014). First pre-functionalized polymeric aromatic framework from nononitrotetrakis(iodophenyl)methane and its applications. Chemistry - A European Journal. 20(17):5111-5120. https://doi.org/10.1002/chem.201304163 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1002/chem.201304163 | es_ES |
dc.description.upvformatpinicio | 5111 | es_ES |
dc.description.upvformatpfin | 5120 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 20 | es_ES |
dc.description.issue | 17 | es_ES |
dc.relation.senia | 281666 | es_ES |
dc.identifier.eissn | 1521-3765 | |
dc.identifier.pmid | 24623578 | |
dc.contributor.funder | Ministerio de Ciencia e Innovación |